Methods of producing sugars from biomass feedstocks

• US 9,238,845 B2
• Filed: 03/14/2013
• Issued: 01/19/2016
• Est. Priority Date: 08/24/2012
• Status: Active Grant

• Current Assignee: DSM Nutritional Products Incorporated (DSM-Firmenich AG)
• Original Assignee: Midori Usa, Inc. (DSM-Firmenich AG)
• Inventors: Baynes, Brian M., Geremia, John M., Andoh, Joseph, Dhawan, Ashish
• Primary Examiner(s): Mayes, Melvin C
• Assistant Examiner(s): CALL, DOUGLAS BRYANT
• Application Number:
  US13/831,495
• Publication Number:
  US 20140060522A1
• Time in Patent Office: 1,041 Days
• Field of Search: None
• US Class Current: 1/1
• CPC Class Codes: C12P 2203/00 Fermentation products obtained from optionally pretreated or hydrolyzed cellulosic or lignocellulosic material as the carbon source ethanol C12P7/10
• CPC Class Codes: C12P 7/10 substrate containing cellulosic material
• CPC Class Codes: C13K 1/02 obtained by saccharification of cellulosic materials manufacture of fodder A23K10/32
• CPC Class Codes: C13K 13/002 Xylose
• CPC Class Codes: C13K 13/007 Separation of sugars provided for in subclass C13K C13K3/00 takes precedence
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel

Abstract

Provided herein are catalysts useful in non-enzymatic saccharification processes. The catalysts can be polymeric catalysts or solid-supported catalysts with acidic and ionic moieties. Provided are also methods for hydrolyzing cellulosic materials into monosaccharides and/or oligosaccharides using the catalysts described herein.

Claims

1. A method of producing one or more sugars from feedstock, comprising:

combining feedstock and a polymeric catalyst to form a reaction mixture,

wherein the feedstock is selected from the group consisting of softwood, hardwood, sugarbeet pulp, food waste, enzymatic digestion residuals, and beer bottoms, or any combination thereof, and

wherein the polymeric catalyst comprises acidic monomers and ionic monomers connected to form a polymeric backbone, wherein a plurality of acidic monomers independently comprises at least one Bronsted-Lowry acid, and wherein a plurality of ionic monomers independently comprises at least one nitrogen-containing cationic group, at least one phosphorous-containing cationic group, or a combination thereof; and

degrading the feedstock in the reaction mixture to produce a liquid phase and a solid phase, wherein the liquid phase comprises one or more sugars, and the solid phase comprises residual feedstock.

2. The method of claim 1, wherein the feedstock and the polymeric catalyst are further combined with a solvent to form the reaction mixture.

3. The method of claim 1, wherein the one or more sugars are selected from one or more monosaccharides, one or more oligosaccharides, or a combination thereof.

4. The method of claim 1, further comprising pretreating the feedstock before combining the feedstock with the polymeric catalyst.

5. The method of claim 1, further comprising

d) isolating at least a portion of the liquid phase from the solid phase;

and

e) recovering the one or more sugars from the isolated liquid phase.

6. The method of claim 2, wherein isolating the at least a portion of the liquid phase from the solid phase in step (d) produces a residual feedstock mixture, and the method further comprises:

i) providing additional feedstock;

ii) combining the additional feedstock with the residual feedstock mixture;

iii) degrading the additional feedstock and the residual feedstock mixture to produce a second liquid phase and a second solid phase, wherein the second liquid phase comprises one or more additional sugars, and wherein the second solid phase comprises additional residual feedstock;

iv) isolating at least a portion of the second liquid phase from the second solid phase; and

v) recovering the one or more additional sugars from the isolated second liquid phase.

7. The method of claim 6, wherein the feedstock and the additional feedstock are the same type of feedstock.

8. The method of claim 6, wherein the one or more additional sugars are selected from one or more monosaccharides, one or more oligosaccharides, or a combination thereof.

9. The method of claim 6, further comprising pretreating the additional feedstock before combining the additional feedstock with the residual feedstock mixture.

10. A method of producing one or more sugars from feedstock, comprising:

combining feedstock and a solid-supported catalyst to form a reaction mixture,

wherein the feedstock is selected from the group consisting of softwood, hardwood, cassava, bagasse, sugarbeet pulp, straw, paper sludge, oil palm, corn stover, food waste, enzymatic digestion residuals, and beer bottoms, or any combination thereof, and

wherein the solid-supported catalyst comprises a solid support, acidic moieties attached to the solid support, and ionic moieties attached to the solid support,

wherein the solid support is selected from the group consisting of biochar, amorphous carbon, activated carbon, silica, silica gel, alumina, magnesia, titania, zirconia, clay, magnesium silicate, silicon carbide, zeolite, ceramic, and any combinations thereof,

wherein a plurality of acidic moieties independently comprises at least one Bronsted-Lowry acid, and wherein a plurality of ionic moieties independently comprises at least one nitrogen-containing cationic group, at least one phosphorous-containing cationic group, or a combination thereof, and

wherein at least a portion of the acidic moieties are directly attached to the solid support, or at least a portion of the acidic moieties are attached to the solid support by a linker, or a combination thereof, and

wherein at least a portion of the ionic moieties are directly attached to the solid support, or at least a portion of the ionic moieties are attached to the solid support by a linker, or a combination thereof; and

degrading the feedstock in the reaction mixture to produce a liquid phase and a solid phase, wherein the liquid phase comprises one or more sugars, and the solid phase comprises residual feedstock.

11. The method of claim 10, wherein the feedstock and the solid-supported catalyst are further combined with a solvent to form the reaction mixture.

12. The method of claim 10, wherein the one or more sugars are selected from one or more monosaccharides, one or more oligosaccharides, or a combination thereof.

13. The method of claim 10, further comprising pretreating the feedstock before combining the feedstock with the solid-supported catalyst.

14. The method of claim 10, further comprising

d) isolating at least a portion of the liquid phase from the solid phase;

and

e) recovering the one or more sugars from the isolated liquid phase.

15. The method of claim 14, wherein isolating the at least a portion of the liquid phase from the solid phase in step (d) produces a residual feedstock mixture, and the method further comprises:

i) providing additional feedstock;

ii) combining the additional feedstock with the residual feedstock mixture;

iii) degrading the additional feedstock and the residual feedstock mixture to produce a second liquid phase and a second solid phase, wherein the second liquid phase comprises one or more additional sugars, and wherein the second solid phase comprises additional residual feedstock;

iv) isolating at least a portion of the second liquid phase from the second solid phase; and

v) recovering the one or more additional sugars from the isolated second liquid phase.

16. The method of claim 15, wherein the feedstock and the additional feedstock are the same type of feedstock.

17. The method of claim 15, wherein the one or more additional sugars are selected from one or more monosaccharides, one or more oligosaccharides, or a combination thereof.

18. The method of claim 15, further comprising pretreating the additional feedstock before combining the additional feedstock with the residual feedstock mixture.