Methods and apparatus for authenticating articles with luminescent phosphor compounds

• US 9,239,262 B2
• Filed: 06/29/2012
• Issued: 01/19/2016
• Est. Priority Date: 07/15/2011
• Status: Active Grant

• Current Assignee: Honeywell International Inc.
• Original Assignee: Honeywell International Inc.
• Inventors: Rapoport, William Ross, Kane, James, Lau, Carsten
• Primary Examiner(s): Porta, David
• Assistant Examiner(s): SAHU, MEENAKSHI S
• Application Number:
  US13/537,414
• Publication Number:
  US 20130015369A1
• Time in Patent Office: 1,299 Days
• Field of Search: 250/459.1, 250/458.1, 250/461.1, 250/214.R
• US Class Current: 1/1
• CPC Class Codes: G01J 3/427 Dual wavelengths spectrometry
• CPC Class Codes: G01N 2021/6421 Measuring at two or more wavelengths
• CPC Class Codes: G01N 21/64 Fluorescence; Phosphorescence
• CPC Class Codes: G07D 7/1205 Testing spectral properties

Abstract

Methods and apparatus for article authentication include an exciting radiation generator that exposes an area of the article to exciting radiation, and at least two radiation detectors that detect emitted radiation from the area in a first band and in a second band that does not overlap the first band. The first band corresponds with a first emission sub-band of an emitting ion, and the second band corresponds with a second emission sub-band of the same emitting ion. A processing system calculates a comparison value that represents a mathematical relationship (e.g., a ratio) between a first intensity of the emitted radiation in the first band with a second intensity of the emitted radiation in the second band, and determines whether the comparison value compares favorably with an authentication parameter. When the comparison value compares favorably with the authentication parameter, the article is identified as being authentic.

Claims

1. A method for authenticating an article, the method comprising the steps of:

exposing an area of the article to exciting radiation, wherein the area of the article includes a phosphor compound that emits detectable radiation at a plurality of wavelengths and wherein the phosphor compound comprises an emitting ion and a host crystal lattice material;

detecting emitted radiation from the area of the article in a first band and in a second band that does not overlap the first band, wherein the first band corresponds with a first emission sub-band of the emitting ion within the phosphor compound, and the second band corresponds with a second emission sub-band of the emitting ion within the phosphor compound;

calculating a comparison value that represents a mathematical relationship between a first intensity of the emitted radiation in the first band with a second intensity of the emitted radiation in the second band; and

determining whether the comparison value compares favorably with an authentication parameter.

2. The method of claim 1, wherein the first intensity is a first integrated intensity in the first band, and the second intensity is a second integrated intensity in the second band.

3. The method of claim 1, further comprising, after the exposing step:

discontinuing provision of the exciting radiation at a first time, wherein detecting the emitted radiation is performed after discontinuing the provision of the exciting radiation.

4. The method of claim 3, wherein the first intensity is a first absolute intensity measured at a pre-determined time after the first time, and the second intensity is a second absolute intensity measured at the pre-determined time after the first time.

5. The method of claim 1, wherein the first band and the second band correspond to emission bands of a single ion of an element selected from a group of elements consisting of chromium, manganese, cobalt, nickel, cerium, praseodymium, neodymium, samarium, europium, terbium, dysprosium, holmium, erbium, thulium, and ytterbium.

6. The method of claim 1, wherein the first band and the second band correspond to emission bands of a single ion after substitution into the host crystal lattice material, wherein the host crystal lattice material is selected from a group consisting of an oxide, a fluoride, an oxysulfide, a halide, a borate, a silicate, a gallate, a phosphate, a vanadate, an oxyhalide, an aluminate, a molybdate, a tungstate, a garnet, and a niobate.

7. The method of claim 1, wherein the first band and the second band correspond to emission bands of a single ion after substitution into the host crystal lattice material, wherein the host crystal lattice material is selected from a group consisting of yttrium oxysulfide, a yttrium aluminum garnet, and a gadolinium gallium garnet.

8. The method of claim 1, wherein detecting the emitted radiation comprises the steps of:

separating the emitted radiation into a first beam that includes light within the first band and a second beam that includes light within the second band;

detecting the first intensity from the first beam; and

detecting the second intensity from the second beam.

9. The method of claim 1, wherein detecting the emitted radiation comprises the steps of:

separating the emitted radiation into a first beam that includes light within the first band and a second beam that includes light within the second band;

filtering the first beam with a first filter to produce a first filtered beam;

filtering the second beam with a second filter to produce a second filtered beam;

detecting the first intensity from the first filtered beam; and

detecting the second intensity from the second filtered beam.

10. The method of claim 1, wherein calculating the comparison value comprises the step of:

calculating a ratio between the first intensity and the second intensity, wherein the comparison value is the ratio.

11. The method of claim 1, wherein determining whether the comparison value compares favorably with an authentication parameter comprises the steps of:

determining whether the comparison value falls within a range defined by a lower limit and an upper limit;

when the comparison value falls within the range, determining that the comparison value compares favorably with the authentication parameter, wherein the method further comprises identifying the article as being authentic; and

when the comparison value falls outside the range, determining that the comparison value does not compare favorably with the authentication parameter, wherein the method further comprises identifying the article as being unauthentic.

12. The method of claim 1, further comprising the steps of:

determining whether a decay time of the emitted radiation compares favorably with a decay time parameter; and

when the decay time does not compare favorably with the decay time parameter, identifying the article as being unauthentic.

13. The method of claim 1, further comprising the step of:

when the comparison value does not compare favorably with the authentication parameter, identifying the article as being unauthentic.