Silicon anode for a rechargeable battery

• US 9,252,426 B2
• Filed: 05/09/2008
• Issued: 02/02/2016
• Est. Priority Date: 05/11/2007
• Status: Active Grant

• Current Assignee: Nexeon Limited
• Original Assignee: Nexeon Limited
• Inventors: Green, Mino
• Primary Examiner(s): Ruddock, Ula C
• Assistant Examiner(s): AMPONSAH, OSEI K
• Application Number:
  US12/599,034
• Publication Number:
  US 20100190061A1
• Time in Patent Office: 2,825 Days
• Field of Search: 429/231.95
• US Class Current: 1/1
• CPC Class Codes: H01M 10/052 Li-accumulators
• CPC Class Codes: H01M 10/0525 Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
• CPC Class Codes: H01M 2004/021 Physical characteristics, e.g. porosity, surface area
• CPC Class Codes: H01M 2004/027 Negative electrodes
• CPC Class Codes: H01M 2004/028 Positive electrodes
• CPC Class Codes: H01M 4/131 Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
• CPC Class Codes: H01M 4/134 Electrodes based on metals, Si or alloys
• CPC Class Codes: H01M 4/1395 of electrodes based on metals, Si or alloys
• CPC Class Codes: H01M 4/38 of elements or alloys
• CPC Class Codes: H01M 4/386 Silicon or alloys based on silicon
• CPC Class Codes: H01M 4/485 of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy H01M4/505, H01M4/525 take precedence
• CPC Class Codes: H01M 4/525 of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

An electrode and electrode assembly, for example for use as an anode in a lithium-ion rechargeable cell that uses silicon or silicon-based elements of specific dimensions and geometry as its active material, is provided, as well as methods for manufacturing the same. The active silicon or silicon-based material may include fibers, sheets, flakes, tubes or ribbons, for example.

Claims

1. An electrochemical cell anode comprising

a porous composite film containing a plurality of discrete silicon or silicon-based elements as an active material, each having a first dimension in the range of 0.08 μ

m to 0.3 μ

m and a second dimension of at least five times as large as the first dimension, the composite film having a mass of silicon or silicon-based elements between 70 and 95 percent,

wherein the silicon or silicon-based elements form an interconnected array,

wherein the silicon or silicon-based elements are capable of lithium insertion and removal, and

wherein the silicon or silicon-based elements are selected from the group consisting of hollow tubes, ribbons and flakes.

2. An electrochemical cell anode as claimed in claim 1, in which the silicon or silicon-based elements are elongate.

3. An electrochemical cell anode as claimed in claim 1 further comprising a copper current collector.

4. An electrochemical cell containing an electrochemical cell anode as claimed in claim 1.

5. An electrochemical cell as claimed in claim 4 in which a cathode of the electrochemical cell comprises lithium-based compound as its active material.

6. An electrochemical cell as claimed in claim 5 in which the cathode comprises lithium-based metal oxide as its active material.

7. A device powered by an electrochemical cell as claimed in claim 4.

8. An electrochemical cell anode as claimed in claim 1 wherein the elements have a third dimension oriented transverse to each of the first and second dimensions, the third dimension being at least ten times as large as the first dimension.

9. An electrochemical cell anode as claimed in claim 1 wherein the elements have a third dimension oriented transverse to each of the first and second dimensions, the third dimension being at least 100 times as large as the first dimension.

10. An electrochemical cell anode as claimed in claim 1 wherein members of the interconnected array form multiple connections therebetween.

11. An electrochemical cell anode as claimed in claim 1 wherein members of the interconnected array criss-cross one another.

12. An electrochemical cell anode as claimed in claim 1 wherein the first dimension is in the range of 0.2 μ

m to 0.3 μ

m.

13. An electrochemical cell anode as claimed in claim 1 wherein the silicon or silicon-based elements are hollow tubes.

14. An electrochemical cell anode as claimed in claim 1 wherein the silicon or silicon-based elements are ribbons.

15. An electrochemical cell anode as claimed in claim 1 wherein the silicon or silicon-based elements are flakes.

16. An electrochemical cell anode as claimed in claim 1 wherein the second dimension is at least 10 times as large as the first dimension.

17. An electrochemical cell anode as claimed in claim 1 wherein the elements further comprise a third dimension that is at least 10 times as large as the first dimension.

18. An electrochemical cell anode as claimed in claim 4 further comprising an electrolyte saturating the available electrode pore volume.

19. A lithium-ion rechargeable battery cell containing an electrochemical cell anode as claimed in claim 1.

20. An electrochemical anode as claimed in claim 1, wherein the composite film has a pore volume between 10% and 30%.

21. An electrochemical cell as claimed in claim 6, wherein the active material of the cathode comprises LiCoO₂.

22. An electrochemical anode as claimed in claim 1, wherein the elements have a largest dimension that is no larger than 500 μ

m.