Processing of α+β titanium alloys

• US 9,255,316 B2
• Filed: 07/19/2010
• Issued: 02/09/2016
• Est. Priority Date: 07/19/2010
• Status: Active Grant

• Current Assignee: ATI Properties LLC
• Original Assignee: ATI Properties Incorporated (Allegheny Technologies Incorporated)
• Inventors: Bryan, David J.
• Primary Examiner(s): LEE, REBECCA Y
• Application Number:
  US12/838,674
• Publication Number:
  US 20120012233A1
• Time in Patent Office: 2,031 Days
• Field of Search: 148/407, 148/421, 148/671, 420/418, 420/420
• US Class Current: 1/1
• CPC Class Codes: C21D 1/26 Methods of annealing
• CPC Class Codes: C22C 14/00 Alloys based on titanium
• CPC Class Codes: C22F 1/18 High-melting or refractory metals or alloys based thereon
• CPC Class Codes: C22F 1/183 of titanium or alloys based thereon

Abstract

Processes for forming an article from an α+β titanium alloy are disclosed. The α+β titanium alloy includes, in weight percentages, from 2.90 to 5.00 aluminum, from 2.00 to 3.00 vanadium, from 0.40 to 2.00 iron, and from 0.10 to 0.30 oxygen. The α+β titanium alloy is cold worked at a temperature in the range of ambient temperature to 500° F., and then aged at a temperature in the range of 700° F. to 1200° F.

Claims

1. A process for forming an article from an α

+β

titanium alloy comprising;

cold working the α

+β

titanium alloy at a temperature in the range of ambient temperature to 500°

F.; and

direct aging the cold-worked α

+β

titanium alloy at a temperature in the range of 700°

F. to 1200°

F.;

the α

+β

titanium alloy comprising, in weight percentages, from 2.90 to 5.00 aluminum, from 2.00 to 3.00 vanadium, from 0.40 to 2.00 iron, from 0.10 to 0.30 oxygen, titanium, and incidental impurities; and

wherein the cold working and direct aging forms an α

+β

titanium alloy article having an ultimate tensile strength in the range of 155 ksi to 200 ksi and an elongation in the range of 8% to 20%, at ambient temperature.

2. The process of claim 1, wherein the cold working and aging forms an α

+β

titanium alloy article having an ultimate tensile strength in the range of 165 ksi to 180 ksi and an elongation in the range of 8% to 17%, at ambient temperature.

3. The process of claim 1, wherein the cold working and aging forms an α

+β

titanium alloy article having a yield strength in the range of 140 ksi to 165 ksi and an elongation in the range of 8% to 20%, at ambient temperature.

4. The process of claim 1, wherein the cold working and aging forms an α

+β

titanium alloy article having a yield strength in the range of 155 ksi to 165 ksi and an elongation in the range of 8% to 15%, at ambient temperature.

5. The process of claim 1, wherein the cold working and aging forms an α

+β

titanium alloy article having an ultimate tensile strength, a yield strength, and an elongation, at ambient temperature, that are at least as great as an ultimate tensile strength, a yield strength, and an elongation, at ambient temperature, of an otherwise identical article consisting of a Ti-6Al-4V alloy in a solution treated and aged condition.

6. The process of claim 1, comprising cold working the α

+β

titanium alloy to a 20% to 60% reduction in area.

7. The process of claim 1, comprising cold working the α

+β

titanium alloy to a 20% to 40% reduction in area.

8. The process of claim 1, wherein the cold working of the α

+β

titanium alloy comprises at least two deformation cycles, wherein each cycle comprises cold working the α

+β

titanium alloy to an at least 10% reduction in area.

9. The process of claim 1, wherein the cold working of the α

+β

titanium alloy comprises at least two deformation cycles, wherein each cycle comprises cold working the α

+β

titanium alloy to an at least 20% reduction in area.

10. The process of claim 1, comprising cold working the α

+β

titanium alloy at a temperature in the range of ambient temperature to 400°

F.

11. The process of claim 1, comprising cold working the α

+β

titanium alloy at ambient temperature.

12. The process of claim 1, comprising aging the α

+β

titanium alloy at a temperature in the range of 800°

F. to 1150°

F. after the cold working.

13. The process of claim 1, comprising aging the α

+β

titanium alloy at a temperature in the range of 850°

F. to 1100°

F. after the cold working.

14. The process of claim 1, comprising aging the α

+β

titanium alloy for up to 50 hours.

15. The process of claim 14, comprising aging the α

+β

titanium alloy for 0.5 to 10 hours.

16. The process of claim 1, further comprising hot working the α

+β

titanium alloy at a temperature in the range of 300°

F. to 25°

F. below the β

-transus temperature of the α

+β

titanium alloy, wherein the hot working is performed before the cold working.

17. The process of claim 16, further comprising annealing the α

+β

titanium alloy at a temperature in the range of 1200°

F. to 1500°

F., wherein the annealing is performed between the hot working and the cold working.

18. The process of claim 16, comprising hot working the α

+β

titanium alloy at a temperature in the range of 1500°

F. to 1775°

F.

19. The process of claim 1, wherein the α

+β

titanium alloy consists of, in weight percentages, from 2.90 to 5.00 aluminum, from 2.00 to 3.00 vanadium, from 0.40 to 2.00 iron, from 0.10 to 0.30 oxygen, incidental impurities, and titanium.

20. The process of claim 1, wherein the α

+β

titanium alloy consists essentially of, in weight percentages, from 3.50 to 4.50 aluminum, from 2.00 to 3.00 vanadium, from 1.00 to 2.00 iron, from 0.10 to 0.30 oxygen, and titanium.

21. The process of claim 1, wherein the α

+β

titanium alloy consists essentially of, in weight percentages, from 3.70 to 4.30 aluminum, from 2.20 to 2.80 vanadium, from 1.20 to 1.80 iron, from 0.22 to 0.28 oxygen, and titanium.

22. The process of claim 1, wherein cold working the α

+β

titanium alloy comprises cold working by at least one operation selected from the group consisting of rolling, forging, extruding, pilgering, rocking, and drawing.

23. The process of claim 1, wherein cold working the α

+β

titanium alloy comprises cold drawing the α

+β

titanium alloy.

24. A process for forming an article from an α

+β

titanium alloy comprising;

hot working the α

+β

titanium alloy at a temperature in the range of 300°

F. to 25°

F. below the β

-transus temperature of the α

+β

titanium alloy;

annealing the α

+β

titanium alloy at a temperature in the range of 1200°

F. to 1500°

F., wherein the annealing is performed after the hot working;

cold working the α

+β

titanium alloy at a temperature in the range of ambient temperature to 500°

F., wherein the cold working is performed after the annealing; and

direct aging the cold worked α

+β

titanium alloy at a temperature in the range of 700°

F. to 1200°

F.;

the α

+β

titanium alloy comprising, in weight percentages, from 2.90 to 5.00 aluminum, from 2.00 to 3.00 vanadium, from 0.40 to 2.00 iron, from 0.10 to 0.30 oxygen, titanium, and incidental impurities;

wherein the cold working and direct aging forms an α

+β

titanium alloy article having an ultimate tensile strength in the range of 155 ksi to 200 ksi and an elongation in the range of 8% to 20%, at ambient temperature.

26. The process of claim 24, comprising hot working the α

+β

titanium alloy at a temperature in the range of 1500°

F. to 1775°

F.

25. A process for forming an article from an α

+β

titanium alloy comprising;

drawing an α

+β

titanium alloy bar at a temperature in the range of ambient temperature to 500°

F. to reduce the cross-sectional area of the bar; and

direct aging the drawn α

+β

titanium alloy bar at a temperature in the range of 700°

F. to 1200°

F.;

the α

+β

titanium alloy comprising, in weight percentages, from 2.90 to 5.00 aluminum, from 2.00 to 3.00 vanadium, from 0.40 to 2.00 iron, from 0.10 to 0.30 oxygen, titanium, and incidental impurities;

wherein the drawing and direct aging forms an α

+β

titanium alloy article having an ultimate tensile strength in the range of 155 ksi to 200 ksi and an elongation in the range of 8% to 20%, at ambient temperature.

27. The process of claim 25, further comprising forming the α

+β

titanium alloy bar by hot working the α

+β

titanium alloy at a temperature in the range of 300°

F. to 25°

F. below the β

-transus temperature of the α

+β

titanium alloy.

28. The process of claim 27, further comprising annealing the α

+β

titanium alloy at a temperature in the range of 1200°

F. to 1500°

F., wherein the annealing is performed between the hot working and the drawing.