Method for optimizing in-situ bioconversion of carbon-bearing formations

• US 9,255,472 B2
• Filed: 05/08/2013
• Issued: 02/09/2016
• Est. Priority Date: 07/02/2008
• Status: Expired due to Fees

• Current Assignee: Ciris Energy, Inc.
• Original Assignee: Ciris Energy, Inc.
• Inventors: Downey, Robert A.
• Primary Examiner(s): Bates, Zakiya W
• Application Number:
  US13/889,754
• Publication Number:
  US 20140151027A1
• Time in Patent Office: 1,007 Days
• US Class Current: 1/1
• CPC Class Codes: B09C 1/10 microbiologically, biologically or by using enzymes
• CPC Class Codes: C02F 1/001 Processes for the treatment of water whereby the filtration technique is of importance C02F1/44 takes precedence; construction of filters in general B01D24/00 - B01D41/00
• CPC Class Codes: C09K 8/582 characterised by the use of bacteria
• CPC Class Codes: C12M 21/04 for producing gas, e.g. biogas digesters for manure with production of biogas A01C3/028, biological treatment of water, waste water or sewage C02F3/00, C02F11/02, preparation of natural gas or syngas C10L3/06, C10L3/10
• CPC Class Codes: C12M 23/18 Open ponds; Greenhouse type or underground installations
• CPC Class Codes: C12P 5/023 Methane
• CPC Class Codes: E21B 43/006 Production of coal-bed methane E21B43/243 takes precedence
• CPC Class Codes: E21B 43/16 Enhanced recovery methods for obtaining hydrocarbons
• CPC Class Codes: E21B 43/295 Gasification of minerals, e.g. for producing mixtures of combustible gases E21B43/243 takes precedence
• CPC Class Codes: Y02E 50/30 Fuel from waste, e.g. synthetic alcohol or diesel

Abstract

A process for bioconverting a subterranean carbon-bearing subterranean formation deposit include the steps of injecting a fluid into the carbon bearing deposit with at least one injection well and removing injected fluid and product from the deposit through at least one production well, controlling fluid pressure within at least a portion of the deposit by use of the injected fluid such that the pressure causes a net effective stress decrease for the portion of the deposit and an increase in permeability of the deposit, bioconverting at least a portion of carbonaceous materials in the carbon bearing deposit to methane by a microbial consortium, and withdrawing the injected fluid and methane from the carbon bearing deposit. Cetane or butane may also be produced by the microbial consortium.

Claims

1. A process for bioconverting a subterranean carbon-bearing deposit selected from coal seams, coal deposits and shale deposits comprising the steps of:

injecting a fluid into the carbon bearing deposit with at least one injection well and removing injected fluid and product from the deposit through at least one production well;

controlling fluid pressure within at least a portion of the deposit by use of said injected fluid, said pressure being controlled such that a net effective stress for said portion of the deposit is decreased and a permeability of said deposit is increased, and such that the fluid pressure within at least a portion of the deposit exceeds the fluid pressure that normally exists in that portion;

bioconverting at least a portion of carbonaceous materials in the carbon bearing deposit to methane by a microbial consortium including at least one methanogen; and

withdrawing the injected fluid and methane from said carbon bearing deposit.

2. The process of claim 1 wherein the net effective stress is reduced during production of methane from said deposit.

3. The process of claim 2 wherein the pressure is controlled by increasing the pressure of introduction of said fluid.

4. The process of claim 2 wherein the pressure is controlled by controlling the flow of fluid removed from the at least one production well.

5. The process of claim 1 wherein the injected fluid includes nutrients for bacteria that bioconvert the carbonaceous materials to methane.

6. The process of claim 5 wherein the injected fluid flows from the at least one injection well to a plurality of production wells and the distribution of fluid flow from the injection well to the production wells is controlled by controlling the pressure difference between the at least one injection well and the production wells.

7. The process of claim 6 wherein the flow distribution is controlled to increase the total production of methane.

8. The process of claim 1 wherein the deposit is a coal deposit.

9. The process of claim 1 wherein the deposit is shale deposit.

10. The process of claim 1, wherein said injected fluid contains a microbial consortium that is capable of bioconverting at least portion of the carbonaceous materials in the carbon bearing deposit.

11. The process of claim 1, wherein said injected fluid contains nutrients and a microbial consortium that is capable of bioconverting at least portion of the carbonaceous materials in the carbon bearing deposit.

12. The process of claim 1, wherein the pressure is controlled for achieving a desired distribution of the injected fluid through the carbon bearing deposit by controlling pressure at said at least one injection well.

13. The process of claim 12, wherein the method of controlling the pressure at said at least one injection well is selected from a group consisting of pumping, capping, increasing input, decreasing output, decreasing input and increasing output.

14. The process of claim 1, wherein the pressure is controlled for achieving a desired distribution of the injected fluid through said carbon bearing deposit by controlling a pressure at said at least one production well.

15. The process of claim 14, wherein the method of controlling the pressure at said at least one production well is selected from a group consisting of pumping, capping, increasing input, decreasing output, decreasing input and increasing output.

16. The process of claim 1, wherein the increased permeability enables increasing fluid flow through said carbon-bearing deposit to increase a flow of materials introduced with the injected fluid and a flow of products produced in the bioconverting step.

17. The process of claim 1, wherein said permeability is increased by at least 5%.

18. The process of claim 1, wherein said permeability is increased by at least 10%.

19. The process of claim 1, wherein said permeability is increased by at least 15%.

20. The process of claim 1, wherein the bioconverting step additionally produces cetane or butane.