Process and apparatus to remove and destroy volatile organic compounds by atomizing water in ozone atmosphere

• US 9,272,924 B2
• Filed: 10/25/2012
• Issued: 03/01/2016
• Est. Priority Date: 10/25/2012
• Status: Active Grant

• Current Assignee: ABC Soils Incorporated
• Original Assignee: ABC Soils Incorporated
• Inventors: Berger, Marcia Jada, Anderson, Isaac Wayne
• Primary Examiner(s): STELLING, LUCAS A
• Application Number:
  US13/661,023
• Publication Number:
  US 20140120018A1
• Time in Patent Office: 1,223 Days
• US Class Current: 1/1
• CPC Class Codes: B01D 1/16 by spraying B01D1/22 takes precedence
• CPC Class Codes: B01D 19/0005 with one or more auxiliary substances
• CPC Class Codes: B01D 19/0047 Atomizing, spraying, trickling
• CPC Class Codes: B01D 2251/104 Ozone
• CPC Class Codes: B01D 2253/102 Carbon
• CPC Class Codes: B01D 2257/7027 Aromatic hydrocarbons
• CPC Class Codes: B01D 2257/708 Volatile organic compounds V.O.C.'s
• CPC Class Codes: B01D 3/346 the gas being used for removing vapours, e.g. transport gas
• CPC Class Codes: B01D 53/44 Organic components
• CPC Class Codes: B01D 53/70 Organic halogen compounds
• CPC Class Codes: C02F 1/001 Processes for the treatment of water whereby the filtration technique is of importance C02F1/44 takes precedence; construction of filters in general B01D24/00 - B01D41/00
• CPC Class Codes: C02F 1/20 by degassing, i.e. liberation of dissolved gases degasification of liquids in general B01D19/00; arrangement of degassing apparatus in boiler feed supply F22D
• CPC Class Codes: C02F 1/78 with ozone C02F1/4672 takes precedence
• CPC Class Codes: C02F 2101/322 Volatile compounds, e.g. benzene
• CPC Class Codes: C02F 2209/005 Processes using a programmable logic controller [PLC]
• CPC Class Codes: C02F 2209/235 in the gas phase

Abstract

A process and apparatus to remove and breakdown volatile organic compounds from drinking water, groundwater, wastewater, frack water and air exhaust. The process entails filling a tank, chamber, pipe, or column with ozone-containing gas, introducing into this ozone-containing gas-filled tank, chamber, pipe or column, very small droplets of water, contaminated with volatile organic compounds which then volatilize out from the water and break down in the ozone gas thereby improving the water quality and associated air quality. The current invention has been shown to achieve more than 99% combined removal efficiency. The process can also be used to treat air streams containing volatile organic compounds. To increase efficiency, ozone is introduced where the atomized particles are smallest. Three configurations utilizing said process include upward and downward spray of contaminated water into ozone and pumping through openings in an enclosure to a reaction chamber filled with ozone-containing gas.

Claims

1. An apparatus for water treatment based on the use of ozone gas to remove and break down organic compounds that are volatilized from atomized water droplets, comprising:

a vessel having a top and a bottom and inner and outer chambers,

a multiport sprayer having spray nozzles connected to an influent pipe to atomize the incoming fluid in the vessel,

an ozone inlet provided at the top of the inner chamber and fluidly connected to a source of ozone and to provide ozone into the inner chamber,

a series of baffles located at the top of the inner chamber and covering the ozone inlet to prevent atomized water in the inner chamber from entering the ozone inlet,

an effluent pipe located at the bottom of the inner chamber,

at least one vent located on the inner chamber to allow exhaust gas to exit the inner chamber to the outer chamber, and

at least one drip edge and overflow port located below the location of the at least one vent in the inner chamber,

whereby water to be treated is pressurized and sprayed through the spray nozzles of the multiport sprayer to atomize the water into the inner chamber containing a relatively lower pressure and ozone gas to remove and break down organic compounds in the atomized water.

2. The apparatus of claim 1, wherein water is treated in a continuous flow mode of operation.

3. The apparatus of claim 2, wherein the inner chamber is continuously replenished with ozone-containing gas while treated water drains from the reaction chamber and continues along the effluent pipe.

4. The apparatus of claim 2, wherein the nozzles of the multiport sprayer are directed upward in the inner chamber.

5. The apparatus of claim 1, wherein water is treated in a batch treatment mode.

6. The apparatus of claim 5, wherein the inner chamber is continuously replenished with ozone-containing gas while treated water drains from the reaction chamber and continues along the effluent pipe.

7. The apparatus of claim 5, wherein the nozzles of the multiport sprayer are directed upward in the inner chamber.

8. A water treatment process based on the use of ozone gas to remove and break down organic compounds, comprising:

providing a treatment apparatus comprising;

a vessel having a top and a bottom and inner and outer chambers,

a multiport sprayer having spray nozzles connected to an influent pipe to atomize the incoming fluid in the vessel,

an ozone inlet provided at the top of the inner chamber and fluidly connected to a source of ozone and to provide ozone into the inner chamber,

a series of baffles located at the top of the inner chamber and covering the ozone inlet to prevent atomized water in the inner chamber from entering the ozone inlet,

an effluent pipe located at the bottom of the inner chamber,

at least one vent located on the inner chamber to allow exhaust gas to exit the inner chamber to the outer chamber, and

at least one drip edge and overflow port located below the location of the at least one vent in the inner chamber,

pressurizing water to be treated in the influent pipe providing a pressurized water,

providing ozone to the ozone inlet to fill the inner chamber with an ozone gas at a relatively lower pressure than the pressurized water,

spraying the pressurized water to be treated through the nozzles of the multiport sprayer atomizing the water to be treated, and

removing and breaking down organic compounds in the atomized water.

9. The method of claim 8, wherein the method is performed as a continuous process.

10. The method of claim 9, further comprising:

detecting the ozone concentration and organic compound concentrations and adjusting ozone flow rate and concentration and influent flow rate to increase efficiency of ozone usage and percentage of organic compounds destroyed.

11. The method of claim 9, further comprising:

pre-filtering the water to be treated with a pre-filter to remove solids from the water to be treated and periodically channeling ozone to said pre-filter.

12. The method of claim 8, wherein the method is performed as a batch process.