Multi-zone mirrors

• US 9,274,394 B2
• Filed: 01/15/2014
• Issued: 03/01/2016
• Est. Priority Date: 03/05/2007
• Status: Active Grant

• Current Assignee: Gentex Corporation
• Original Assignee: Gentex Corporation
• Inventors: Neuman, George A., Luten, Henry A., Anderson, John S., Forgette, Jeffrey A., Williams, Jeffrey N., Perron, Lansen M.
• Primary Examiner(s): Martinez, Joseph P
• Application Number:
  US14/155,659
• Publication Number:
  US 20140126036A1
• Time in Patent Office: 776 Days
• US Class Current: 1/1
• CPC Class Codes: B60R 1/088 using a cell of electrically changeable optical characteristic, e.g. liquid-crystal or electrochromic mirrors
• CPC Class Codes: B60R 1/12 Mirror assemblies combined with other articles, e.g. clocks
• CPC Class Codes: B60R 2001/1253 with cameras, video cameras or video screens
• CPC Class Codes: C03C 17/36 at least one coating being a metal
• CPC Class Codes: C03C 17/3618 Coatings of type glass/inorganic compound/other inorganic layers, at least one layer being metallic
• CPC Class Codes: C03C 17/3639 Multilayers containing at least two functional metal layers
• CPC Class Codes: C03C 17/3663 specially adapted for use as mirrors
• CPC Class Codes: G02B 27/14 operating by reflection only
• CPC Class Codes: G02B 5/0875 the reflecting layers comprising two or more metallic layers
• CPC Class Codes: G02F 1/157 Structural association of cells with optical devices, e.g. reflectors or illuminating devices

Abstract

A multi-zone reflector having an opaque zone and a transflective zone. The reflector includes a supporting base, a lower reflecting layer disposed adjacent the supporting base, and an upper reflecting layer extending over the opacifying layer and the transflective zone of the reflector. The lower reflecting layer substantially completely covers the transflective zone, and the opacifying layer is disposed substantially outside the transflective zone adjacent to the lower reflecting layer. Over at least a portion of the transflective zone, the upper and lower reflecting layers have a common surface.

Claims

1. An electrochromic mirror element comprising

a first substrate comprising:

a first surface; and

a second surface;

a second substrate substantially parallel to said first substrate comprising;

a third surface; and

a fourth surface;

an electro-optic medium in a cavity defined by said first substrate and said second substrate;

wherein said third surface carries a transflective coating;

wherein said fourth surface carries a graded opacifying layer;

wherein said opacifying layer defines at least two zones;

wherein a first zone is a transflective zone; and

wherein a second zone is an opacifying zone.

2. An electrochromic mirror element according to claim 1, wherein the transflective coating includes a layer containing silver.

3. An electrochromic mirror element according to claim 2, wherein the layer containing silver includes a silver-gold alloy.

4. An electrochromic mirror element according to claim 2, wherein the layer containing silver is a graded layer.

5. An electrochromic mirror element according to claim 2, further comprising a quarter-wave-thick dielectric stack under the layer containing silver.

6. An electrochromic mirror element according to claim 2, further comprising a layer of transparent conductive oxide disposed over the layer containing silver.

7. An electrochromic mirror element according to claim 1, further comprising a flash layer of material interposed between the layer containing silver and a quarter-wave-thick dielectric stack.

8. An electrochromic mirror element according to claim 1, wherein the at least two zones include an opaque zone and a transflective zone, the electrochromic mirror element having a gradually changing, across the electrochromic mirror element, reflectance value measured in light from a CIE Standard Illuminant D₆₅ incident onto the first surface.

9. An electrochromic mirror element according to claim 1, wherein the at least two zones include an opaque zone and a transflective zone, the electrochromic mirror element having a substantially constant, across the electrochromic mirror element, reflectance value measured in light from CIE Standard Illuminant D₆₅ incident onto the first surface.

10. An electrochromic mirror element according to claim 1, further comprising an additional opacifying layer on the third surface under the silver.

11. An electrochromic mirror element according to claim 1, further comprising a silver layer disposed under said additional opacifying layer.

12. An electrochromic mirror element according to claim 1, further comprising a layer of transparent electrode on the second surface.

13. An electrochromic mirror element according to claim 12, wherein said layer of transparent electrode on the second surface includes one or more of TCO, ITO, AZO, IZO, fluorine doped tin oxide, aluminum doped zinc oxide, and niobium doped titania.

14. An electrochromic mirror element according to claim 1, wherein the opavifying layer includes at least one of chromium, stainless steel, silicon, titanium, nickel, molybdenum, Inconel, indium, palladium osmium, tungsten, rhenium, iridium, rhodium, ruthenium, tantalum, copper, gold, and platinum.

15. An electrochromic mirror element according to claim 1, wherein the at least two zones include an opaque zone and a transflective zone, the opaque zone having transmittance not exceeding 5 percent.

16. An electrochromic mirror element according to claim 1, wherein the at least two zones include an opaque zone and a transflective zone, the opaque zone having transmittance not exceeding 2.5 percent.

17. An electro-optic mirror element comprising

a first substrate comprising:

a first surface; and

a second surface;

a second substrate substantially parallel to said first substrate comprising;

a third surface; and

a fourth surface;

an electro-optic medium in a cavity defined by said first substrate and said second substrate;

wherein said third surface carries a transflective coating; and

wherein said fourth surface carries an opacifying layer, and the transflective coating includes a graded layer containing silver.

18. A mirror element comprising:

a first substrate comprising;

a first surface; and

a second surface;

wherein said first surface carries a transflective coating;

a second substrate substantially parallel to said first substrate comprising;

a third surface, wherein said third surface carries a graded transflective coating; and

a fourth surface;

an electro-optic medium in a cavity defined by said first substrate and said second substrate.

19. An electro-optic mirror element comprising:

a first substrate comprising;

a first substrate; and

a second surface;

a second substrate substantially parallel to said first substrate comprising;

a third surface; and

a fourth surface;

an electro-optic medium in a cavity defined by said first substrate and said second substrate;

wherein one of said third surface and said fourth surface carries a transflective coating;

wherein one of said third surface and said fourth surface carries a graded opacifying layer;

wherein said opacifying layer defines at least two zones;

wherein a first zone is a transflective zone; and

wherein a second zone is an opacifying zone.