Method and system to reclaim functional sites on a sorbent contaminated by heat stable salts

• US 9,278,314 B2
• Filed: 09/19/2013
• Issued: 03/08/2016
• Est. Priority Date: 04/11/2012
• Status: Active Grant

• Current Assignee: ADA-ES, Inc. (Advanced Emissions Solutions, Inc.)
• Original Assignee: ADA-ES, Inc. (Advanced Emissions Solutions, Inc.)
• Inventors: Krutka, Holly, Sjostrom, Sharon, Morris, William J.
• Primary Examiner(s): Vanoy, Timothy
• Application Number:
  US14/032,030
• Publication Number:
  US 20140079612A1
• Time in Patent Office: 901 Days
• US Class Current: 1/1
• CPC Class Codes: B01D 2252/204 Amines
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 2258/0283 Flue gases
• CPC Class Codes: B01D 53/62 Carbon oxides
• CPC Class Codes: B01D 53/83 with moving reactants
• CPC Class Codes: B01D 53/96 Regeneration, reactivation or recycling of reactants
• CPC Class Codes: Y02A 50/20 Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

The objective of this invention is to develop a method to reclaim functional sites on a CO₂ sorbent that have reacted with an acid gas (other than CO₂) to form heat stable salts (HSS). HSS are a significant concern for dry sorbent based CO₂ capture because over time the buildup of HSS will reduce the overall functionality of the CO₂ sorbent. A chemical treatment can remove the non-CO₂ acid gas and reclaim functional sites that can then be used for further CO₂ adsorption.

Claims

1. A method, comprising:

receiving a gas stream, the gas stream comprising a target gas component and at least one acid gas, the at least one acid gas being different from the target gas component;

contacting the gas stream with a sorbent to remove at least a portion of the target gas component to form a purified gas stream and a loaded sorbent comprising the removed target gas component, the sorbent also removing and the loaded sorbent also comprising a portion of the at least one acid gas;

removing at least most of the removed target gas component from the loaded sorbent to form a lean sorbent comprising at least most of the removed portion of the at least one acid gas and/or a salt thereof; and

contacting the lean sorbent with a regeneration solution to remove at least most of the removed portion of the at least one acid gas and/or a salt thereof and form for recycle to the gas stream contacting step the sorbent,

wherein the target gas component is a carbon oxide, wherein the at least one acid gas is one or more of a sulfur oxide, a nitrogen oxide and hydrogen sulfide, wherein the sorbent is an amine-base sorbent, and wherein the regeneration solution has a pH of at least pH 10.

2. The method of claim 1, wherein the acid gas comprises SO₂, wherein the target gas component is CO₂, wherein the regeneration solution comprises a base, wherein at least most of the CO₂ in the received gas stream is removed by the sorbent, wherein CO₂ is removed from the loaded sorbent by one or more of a pressure swing, temperature swing, and combination thereof, and wherein the sorbent is in the form of a solid.

3. A method comprising:

receiving a gas stream, the gas stream comprising a target gas component and at least one acid gas, the at least one acid gas being different from the target gas component;

contacting the gas stream with a sorbent to remove at least a portion of the target gas component to form a purified gas stream and a loaded sorbent comprising the removed target gas component, the sorbent also removing and the loaded sorbet also comprising a portion of the at least one acid gas;

removing at least most of the removed target gas component from the loaded sorbent to form a lean sorbent comprising at least most of the removed portion of the at least one acid gas and/or a salt thereof; and

contacting the lean sorbent with a regeneration solution to remove at least most of the removed portion of the at least one acid gas and/or a salt thereof and form for recycle to the gas stream contacting step the sorbent,

wherein bonds between adjacent sorbent components and between the sorbent components and an adjacent sorbent substrate are stronger than bonds between the sorbent component and the target gas component and between the sorbent component and the at least one acid gas and/or salt thereof.

4. The method of claim 3, wherein the regeneration solution does not significantly impact the strengths of the bonds between the between adjacent sorbent components and between the sorbent components and an adjacent sorbent substrate.

5. The method of claim 4, wherein the regeneration solution comprises a base that is at least one of an alkali or alkaline earth metal carbonate, at least one of an alkali or alkaline earth metal hydroxide, an alkoxide, a metal oxide, ammonia, a metal amine, a carboxylate, a phosphine, an ether, a ketone, an alkene, and CH₃⁻

.

6. A method, comprising:

receiving a gas stream, the gas stream comprising a target gas component and at least one acid gas, the at least one acid gas being different from the target gas component;

contacting the gas stream with a sorbent to remove at least a portion of the target gas component to form a purified gas stream and a loaded sorbent comprising the removed target gas component, the sorbent also removing and the loaded sorbent also comprising a portion of the at least one acid gas;

removing at least most of the removed target gas component from the loaded sorbent to form a lean sorbent comprising at least most of the removed portion of the at least one acid gas and/or a salt thereof;

contacting the lean sorbent with a regeneration solution to remove at least most of the removed portion of the at least one acid gas and/or a salt thereof and form for recycle to the gas stream contacting step the sorbent; and

after contact of the lean sorbent with the regeneration solution, contacting the sorbent with a wash solution to remove any deposit on the sorbent after contact with the regeneration solution.

7. A system, comprising:

a gas component separator configured to (a) receive a gas stream, the gas stream comprising a target gas component and at least one acid gas, the at least one acid gas being different from the target gas component, and (b) contact the gas stream with a sorbent to remove at least a portion of the target gas component and a portion of the at least one acid gas to form a purified gas stream and a loaded sorbent comprising the removed target gas and the removed acid gas;

a sorbent regenerator configured to remove at least most of the removed target gas component from the loaded sorbent to form a lean sorbent comprising at least most of the removed acid gas and/or a salt thereof; and

a regeneration vessel configured to contact the lean sorbent with a regeneration solution to remove at least most of the removed acid gas and/or a salt thereof and form for recycle to the gas component separator the sorbent,

wherein the target gas component is a carbon oxide, wherein the at least one acid gas is one or more of a sulfur oxide, a nitrogen oxide and hydrogen sulfide, wherein the sorbent is an a mine-base sorbent, and wherein the regeneration solution has a pH of at least about pH 10.

8. The system of claim 7, wherein the acid gas comprises SO₂, wherein the target gas component is CO₂, wherein the regeneration solution comprises a base, wherein at least most of the CO₂ in the received gas stream is removed by the sorbent, wherein in the sorbent regenerator CO₂ is removed from the loaded sorbent by one or more of a pressure swing, temperature swing, and combination thereof, and wherein the sorbent is in the form of a solid.

9. The system of claim 8, wherein bonds between the between adjacent sorbent components and between the sorbent and an adjacent sorbent substrate are stronger than bonds between the sorbent and the target gas and between the sorbent and the at least one acid gas and/or salt thereof and wherein the regeneration solution does not significantly impact the strengths of the bonds between the between adjacent sorbent components and between the sorbent and the adjacent sorbent substrate.

10. The system of claim 9, wherein the regeneration vessel is further configured, after contact of the lean sorbent with the regeneration solution, to contact the sorbent with a wash solution to remove any deposit on the sorbent after contact with the regeneration solution.

11. A system, comprising:

a gas component separator configured to (a) receive a gas stream, the gas stream comprising a target gas component and at least one acid gas, the at least one acid gas being different from the target gas component, and (b) contact the gas stream with a sorbent to remove at least a portion of the target gas component and a portion of the at least one acid gas to form a purified gas stream and a loaded sorbent comprising the removed target gas and the removed acid gas;

a sorbent regenerator configured to remove at least most of the removed target gas component from the loaded sorbent to form a lean sorbent comprising at least most of the removed one acid gas and/or a salt thereof;

a regeneration vessel configured to contact the lean sorbent with a regeneration solution to remove at least most of the removed acid gas and/or a salt thereof and form, for recycle to the gas component separator, the sorbent; and

a controller comprising microprocessor readable and executable instructions stored on a non-transient and tangible computer readable medium that, when executed, determine a concentration of the target gas component and/or at least one acid gas in the received gas stream and/or purified gas stream and, when a determined relationship involving the determined concentration of the target gas component and/or at least one acid gas in the received gas stream and/or purified gas stream is deemed to exist, initiate regeneration of the loaded sorbent.

12. In a system to remove a target gas component from a gas stream, the gas stream comprising the target gas component and at least one acid gas and the at least one acid gas being different from the target gas component, by contacting the gas stream with a sorbent to remove at least a portion of the target gas component to form a purified gas stream and a target gas component loaded sorbent, the sorbent also removing a portion of the at least one acid gas, a tangible and non-transient computer readable medium comprising microprocessor readable and executable instructions that, when executed, perform operations comprising:

determine a concentration of a target gas component and/or at least one acid gas in at least one of the gas stream and the purified gas stream and, when a determined relationship involving the determined concentration of the target gas component and/or at least one acid gas in the at least one of the gas stream and the purified gas stream is deemed to exist, cause the following sub-operations to be performed;

removing at least most of the removed at least a portion of the target gas component from the loaded sorbent to form a lean sorbent, the lean sorbent comprising at least most of the removed portion of the at least one acid gas and/or a salt thereof; and

contacting the lean sorbent with a regeneration solution to remove at least most of the removed portion of the at least one acid gas and/or a salt thereof and form a fully treated sorbent for recycle.

13. The computer readable medium of claim 12, wherein the instructions, when executed, select between first and second operating modes of the system based on whether the determined relationship is deemed to exist, wherein in the first operating mode, the gas stream passes through a first gas component separator but not a second gas component separator, a first sorbent used by the first gas component separator is not regenerated, and a second sorbent used by the second gas component separator is undergoing regeneration and wherein in the second operating mode, the gas stream passes through the second gas component separator but not the first gas component separator, the second sorbent used by the second gas component separator is not regenerated, and the first sorbent used by the first gas component separator is undergoing regeneration.

14. The computer readable medium of claim 12, wherein the determined relationship estimates at least one of an in-use and unused sorption capacity of the sorbent.

15. The computer readable medium of claim 12, wherein the target gas component is a carbon oxide, wherein the at least one acid gas is one or more of a sulfur oxide, a nitrogen oxide and hydrogen sulfide, wherein the sorbent is an amine-base sorbent, and wherein the regeneration solution has a pH of at least about pH 10.

16. The computer readable medium of claim 15, wherein the acid gas comprises SO₂, wherein the target gas component is CO₂, wherein the regeneration solution comprises a base, wherein at least most of the CO₂ in the received gas stream is removed by the sorbent, wherein in a sorbent regenerator CO₂ is removed from the loaded sorbent by one or more of a pressure swing, temperature swing, and combination thereof, and wherein the sorbent is in the form of a solid.

17. The computer readable medium of claim 16, wherein bonds between the between adjacent sorbent components and between the sorbent component and an adjacent sorbent substrate are stronger than bonds between the sorbent component and the target gas component and between the sorbent component and the at least one acid gas and/or salt thereof and wherein the regeneration solution do not significantly impact the strengths of the bonds between the between adjacent sorbent components and between the sorbent component and an adjacent sorbent substrate.

18. The computer readable medium of claim 17, wherein the regeneration solution is contacted with the lean sorbent in a regeneration vessel, wherein the regeneration vessel is further configured, after contact of the lean sorbent with the regeneration solution, to contact the sorbent with a wash solution to remove any deposit on the sorbent after contact with the regeneration solution.