Apparatus and method for limiting and analyzing stress corrosion cracking in pressurized water reactors

• US 9,280,688 B2
• Filed: 06/28/2013
• Issued: 03/08/2016
• Est. Priority Date: 02/28/2005
• Status: Expired due to Fees

• Current Assignee: AREVA Inc.
• Original Assignee: AREVA Inc.
• Inventors: Lockamon, Brian Glenn, Allmon, William Edward, Fyfitch, Stephen, Griffith, John Carroll
• Primary Examiner(s): Keith, Jack W
• Assistant Examiner(s): Davis, Sharon M
• Application Number:
  US13/930,632
• Publication Number:
  US 20140010339A1
• Time in Patent Office: 984 Days
• Field of Search: None
• US Class Current: 1/1
• CPC Class Codes: G06G 7/54 for nuclear physics, e.g. nuclear reactors, radioactive fall processing of scintigraphic or other radio-isotope data G01T1/1647, G01T1/2992
• CPC Class Codes: G21C 17/00 Monitoring; Testing measuring in general G01; Maintaining
• CPC Class Codes: G21C 17/022 for monitoring liquid coolants or moderators
• CPC Class Codes: G21C 17/0225 Chemical surface treatment, e.g. corrosion corrosion prevention in presence of water from scale removal or by modification of the properties of the liquid C02F5/00; inhibiting corrosion by adding corrosion inhibitors C23F11/00
• CPC Class Codes: Y02E 30/30 Nuclear fission reactors

Abstract

A method to assess and predict pressurized water stress corrosion cracking in operational nuclear power plants and the effect of adding zinc compounds into a reactor coolant system of the nuclear power plant.

Claims

1. A method to evaluate an effect of applying a zinc compound to a reactor coolant system of a pressurized water reactor, comprising:

quantitatively assessing a pressurized water reactor stress corrosion cracking initiation rate of a candidate reactor coolant system through analysis of operational eddy current testing data and pressurized water stress corrosion cracking failure history using empirical relationships;

determining an extent of damage to the candidate system;

quantitatively assessing pressurized water stress corrosion cracking initiation benefit for high-concentration (>

10 ppb) and low-concentration (<

10 ppb) zinc addition programs;

calculating a pressurized water stress corrosion cracking initiation benefit from zinc addition at low concentrations (<

10 ppb) in the candidate system;

approximating a time T when zinc addition at low concentrations (<

10 ppb) in the candidate system is needed for pressurized water stress corrosion cracking mitigation; and

applying zinc acetate to the reactor coolant system at the time T at concentrations of approximately between 1 to 10 parts per billion for pressurized water stress corrosion cracking mitigation,

wherein zinc has not previously been applied to the candidate system and wherein the applying zinc acetate to the reactor coolant system at the time T at concentrations of approximately between 1 and 10 ppb for pressurized water stress corrosion cracking mitigation is not performed until after there are pressurized water stress corrosion cracking indications in the reactor coolant system.

2. The method according to claim 1, further comprising:

applying a temperature scaling factor adjustment to the data to normalize differences between different locations within the reactor coolant system and between the reactor coolant system and reactor coolant systems of other pressurized water reactors.

3. The method according to claim 1, further comprising:

developing a database of degradation rates, the database being adjusted to a common reference temperature.

4. The method according to claim 3, wherein the database is adjusted to effective full power years of operation of the pressurized water reactor.

5. The method according to claim 4, further comprising:

developing a probabilistic predictive tool to trend and predict degradation in the reactor coolant system, the probabilistic predictive tool correlating the effective full power years of reactor operation and the normalized degradation rate.

6. The method according to claim 5, wherein the probabilistic predictive tool is developed from a change in a Weibull slope of pressurized water stress corrosion cracking initiation plotted data before and after zinc addition.

7. The method according to claim 1, further comprising:

calculating a magnitude of pressurized water stress corrosion cracking mitigation due to zinc injection at nuclear power plants as a function of a mass of zinc incorporated into surface oxides of the reactor coolant system.

8. The method according to claim 1 wherein the applying zinc acetate to the reactor coolant system at the time T is performed at concentrations of approximately between 1 to 10 parts per billion that minimize a removal of zinc from the reactor coolant system.

9. The method according to claim 1 wherein the applying zinc acetate to the reactor coolant system at the time T at concentrations of approximately between 1 to 10 parts per billion for pressurized water stress corrosion cracking mitigation includes maintaining the zinc concentration in the reactor coolant system above the solubility of zinc chromite in the reactor coolant system.

10. A method to evaluate an effect of applying a zinc compound to a reactor coolant system of a pressurized water reactor, comprising:

quantitatively assessing a pressurized water reactor stress corrosion cracking initiation rate of a candidate reactor coolant system through analysis of operational eddy current testing data and pressurized water stress corrosion cracking failure history using empirical relationships;

determining an extent of damage to the candidate system;

quantitatively assessing pressurized water stress corrosion cracking initiation benefit for high-concentration (>

10 ppb) and low-concentration (<

10 ppb) zinc addition programs;

calculating a pressurized water stress corrosion cracking initiation benefit from zinc addition at low concentrations (<

10 ppb) in the candidate system;

approximating a time T when zinc addition at low concentrations (<

10ppb) in the candidate system is needed for pressurized water stress corrosion cracking mitigation; and

applying zinc acetate to the reactor coolant system at the time T at concentrations of approximately between 1 to 10 parts per billion for pressurized water stress corrosion cracking mitigation,

wherein zinc has not previously been applied to the candidate system and wherein the step of quantitatively assessing a pressurized water stress corrosion cracking initiation rate of a candidate system through analysis of operational eddy current testing data and pressurized water stress corrosion cracking failure history using empirical relationships comprises calculating a normalized degradation rate define as a number of tubes with new pressurized water stress corrosion cracking indications divided by a number of rotating coil examinations in a region of the number of tubes.