Method for purifying lithium bicarbonate

• US 9,284,626 B2
• Filed: 03/01/2010
• Issued: 03/15/2016
• Est. Priority Date: 03/11/2009
• Status: Active Grant

• Current Assignee: Metso Outotec Finland OY (Metso Outotec Oyj)
• Original Assignee: Outotec Oyj (Metso Outotec Oyj)
• Inventors: Tiihonen, Marika
• Primary Examiner(s): Savage, Matthew O
• Application Number:
  US13/255,099
• Publication Number:
  US 20110318253A1
• Time in Patent Office: 2,206 Days
• Field of Search: 210/670, 210/673, 210/677, 210/681, 210/687, 423/179.5, 423/181, 423/422
• US Class Current: 1/1
• CPC Class Codes: B01J 39/04 Processes using organic exchangers
• CPC Class Codes: B01J 39/07 in the weakly acidic form
• CPC Class Codes: B01J 49/53 for cationic exchangers
• CPC Class Codes: B01J 49/60 Cleaning or rinsing ion-exchange beds
• CPC Class Codes: C22B 26/12 Obtaining lithium
• CPC Class Codes: C22B 3/20 Treatment or purification of solutions, e.g. obtained by leaching C22B3/18 takes precedence
• CPC Class Codes: C22B 3/42 by ion-exchange extraction
• CPC Class Codes: Y02P 10/20 Recycling

Abstract

The invention relates to a method for purifying impure lithium bicarbonate by means of a cation exchange resin. In addition to solution purification by ion exchange, the treatment stages include the regeneration of impurity metals bound to the resin. Regeneration consists of washing the resin with water, elution with acid solution, washing with water, neutralization with alkali solution and washing with water. It is characteristic of the method that neutralization is performed with sodium hydroxide solution.

Claims

1. A method for purifying an impure aqueous solution of lithium bicarbonate containing divalent metal cations the method comprising the steps of:

a) providing a bed of an organic weak acid cation exchange resin that is substantially free of multivalent cations and has been neutralized with sodium ions, wherein the resin has a selectivity for cations in the sequence of Li⁺<

Na⁺<

multivalent metal cations<

H⁺;

b) passing the impure aqueous solution of lithium bicarbonate through the bed provided by step a) to remove the divalent metal cations from the impure aqueous solution;

c) collecting a solution containing sodium ions from the bed at a beginning of step b);

d) collecting a purified aqueous solution of lithium bicarbonate from the bed during step b) and following step c);

e) passing the solution collected in step c) through the bed to displace lithium ions from the bed to produce a solution containing lithium ions following step d);

f) collecting the solution containing lithium ions during step e);

g) passing water through the bed following step e) to rinse the bed;

h) passing an aqueous solution containing an acid through the bed following step g) to elute the divalent metal cations from the cation exchange resin;

i) passing water through the bed following step h) to rinse the bed;

j) passing an aqueous solution containing sodium hydroxide through the bed following step i) to neutralize the cation exchange resin thereby providing the bed recited in step a).

2. A method according to claim 1, wherein the acid recited in step h) is sulfuric acid.

3. A method according to claim 1, wherein the acid recited in step h) is hydrochloric acid.

4. A method according to claim 1, wherein a concentration of sodium hydroxide in the aqueous solution recited in step j) is 0.5-2 mol/l.

5. A method according to claim 1, wherein a concentration of the acid in the aqueous solution recited in step h) is 0.5-2 mol/l.

6. A method according to claim 1, wherein the bed of cation exchange resin has a volume, and wherein a volume of the solution collected in step c) is equal to about two times the volume of the bed in size.