Herbicidal concentrate compositions containing glyphosate and dicamba salts

• US 9,288,984 B2
• Filed: 06/24/2010
• Issued: 03/22/2016
• Est. Priority Date: 06/25/2009
• Status: Active Grant

• Current Assignee: Corteva Agriscience LLC (Corteva, Inc.)
• Original Assignee: Dow Agrosciences LLC (Corteva, Inc.)
• Inventors: Zhang, Hong, Tank, Holger, Li, Mei, Liu, Lei, Wilson, Stephen L., Qin, Kuide, Ouse, David G.
• Primary Examiner(s): Wax, Robert A
• Assistant Examiner(s): NIELSEN, THOR B
• Application Number:
  US12/822,373
• Publication Number:
  US 20100331182A1
• Time in Patent Office: 2,098 Days
• Field of Search: None
• US Class Current: 1/1
• CPC Class Codes: A01N 2300/00 Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
• CPC Class Codes: A01N 25/02 containing liquids as carriers, diluents or solvents
• CPC Class Codes: A01N 37/10 Aromatic or araliphatic carboxylic acids, or thio analogues thereof; Derivatives thereof
• CPC Class Codes: A01N 37/40 having at least one carboxylic group or a thio analogue, or a derivative thereof, and one oxygen or sulfur atom attached to the same aromatic ring system
• CPC Class Codes: A01N 57/20 containing acyclic or cycloaliphatic radicals

Abstract

The mixture of potassium or certain amine salts of glyphosate and dicamba allows the preparation of high-strength liquid compositions containing greater than 300 gae/L of total active ingredient loading if the pH is adjusted between about 6.0 and about 8.0. Compositions are particularly well-suited for herbicidal applications on crops that are resistant or tolerant to both glyphosate and dicamba.

Claims

1. A homogeneous, stable, high-strength aqueous herbicidal concentrate composition comprising:

(a) water,

(b) a glyphosate potassium or amine salt, and

(c) a dicamba potassium or amine salt,

in which (i) the glyphosate salt is potassium or a secondary, tertiary or quaternary alkylamine or a primary, secondary, tertiary or quaternary alkanolamine, alkylalkanolamine or alkoxyalkanolamine salt, wherein the alkyl and alkanol groups are saturated and contain from C₁-C₄ carbon atoms individually, (ii) the dicamba salt is potassium or a secondary, tertiary or quaternary alkylamine or a primary, secondary, tertiary or quaternary alkanolamine, alkylalkanolamine or alkoxyalkanolamine salt, wherein the alkyl and alkanol groups are saturated and contain from C₁-C₄ carbon atoms individually, (iii) the composition contains a total active ingredient loading of at least 300 g ae/L of the glyphosate potassium or amine salt and the dicamba potassium or amine salt, (iv) the acid equivalent weight ratio of the glyphosate potassium or amine salt to the dicamba potassium or amine salt is from about 1;

1 to about 3;

1, and (v) the pH is from about 6.0 to about 8.0.

2. A composition of claim 1 which contains a total active ingredient loading of greater than about 450 grams of acid equivalent of the glyphosate potassium or amine salt and the dicamba potassium or amine salt.

3. A composition of claim 1 in which the acid equivalent weight ratio of the glyphosate potassium or amine salt to the dicamba potassium or amine salt is about 1.5:

1 to about 3;

1.

4. A composition of claim 1 in which the pH is from about 6.5 to about 7.5.

5. A composition of claim 1 in which the glyphosate salt is potassium or a monoethanolamine, dimethylethanolamine, dimethylamine, diglycolamine or choline salt.

6. A composition of claim 1 in which the dicamba salt is potassium or a dimethylamine, monoethanolamine, dimethylethanolamine, choline or diglycolamine salt.

7. A method of controlling undesirable vegetation in crops that are resistant or tolerant to both glyphosate and dicamba which comprises applying to the undesirable vegetation and the crops that are resistant or tolerant to both glyphosate and dicamba a water-diluted composition of claim 1.

8. A composition of claim 1 in which the glyphosate salt is a monoethanolamine, dimethylethanolamine, diglycolamine, or choline salt.

9. A composition of claim 1 in which the dicamba salt is a monoethanolamine, dimethylethanolamine, diglycolamine, or choline salt.

10. A composition of claim 1 wherein the glyphosate salt is a dimethylamine salt and the dicamba salt is a diglycolamine, dimethylamine, dimethylethanolamine, choline, monoethanolamine, or potassium salt.

11. A composition of claim 1 wherein the glyphosate salt is a monoethanolamine salt and the dicamba salt is a diglycolamine, dimethylamine, dimethylethanolamine, choline, or monoethanolamine salt.

12. A composition of claim 1 wherein the glyphosate salt is a dimethylethanolamine salt and the dicamba salt is a diglycolamine, dimethylamine, dimethylethanolamine, choline, monoethanolamine, or potassium salt.

13. A composition of claim 1 wherein the glyphosate salt is a diglycolamine salt and the dicamba salt is a diglycolamine, dimethylamine, dimethylethanolamine, choline, monoethanolamine, or potassium salt.

14. A composition of claim 1 wherein the glyphosate salt is a choline salt and the dicamba salt is a diglycolamine, dimethylamine, dimethylethanolamine, choline, monoethanolamine, or potassium salt.

15. A composition of claim 1 wherein the glyphosate salt is a potassium salt and the dicamba salt is a diglycolamine, dimethylamine, dimethylethanolamine, choline, or monoethanolamine salt.

16. A composition of claim 1 wherein the dicamba salt is a dimethylamine salt and the glyphosate salt is a diglycolamine, dimethylamine, dimethylethanolamine, choline, monoethanolamine, or potassium salt.

17. A composition of claim 1 wherein the dicamba salt is a monoethanol amine salt and the glyphosate salt is a diglycolamine, dimethylamine, dimethylethanolamine, choline, monoethanolamine, or potassium salt.

18. A composition of claim 1 wherein the dicamba salt is a dimethylethanolamine salt and the glyphosate salt is a diglycolamine, dimethylamine, dimethylethanolamine, choline, monoethanolamine, or potassium salt.

19. A composition of claim 1 wherein the dicamba salt is a diglycolamine salt and the glyphosate salt is a diglycolamine, dimethylamine, dimethylethanolamine, choline, monoethanolamine, or potassium salt.

20. A composition of claim 1 wherein the dicamba salt is a choline salt and the glyphosate salt is a diglycolamine, dimethylamine, dimethylethanolamine, choline, monoethanolamine, or potassium salt.

21. A composition of claim 1 wherein the dicamba salt is a potassium salt and the glyphosate salt is a diglycolamine, dimethylamine, dimethylethanolamine, choline, or monoethanolamine salt.