Polymer-bound UV absorbers in personal care compositions

• US 9,289,631 B2
• Filed: 06/01/2015
• Issued: 03/22/2016
• Est. Priority Date: 01/27/2009
• Status: Active Grant

• Current Assignee: Isp Investments LLC (Ashland Global Holdings, Inc.)
• Original Assignee: ISP Investments, Inc. (Ashland Global Holdings, Inc.)
• Inventors: Musa, Osama M., Shih, Jenn S.
• Primary Examiner(s): FALKOWITZ, ANNA R
• Application Number:
  US14/727,558
• Publication Number:
  US 20150265522A1
• Time in Patent Office: 295 Days
• US Class Current: 1/1
• CPC Class Codes: A61K 2800/57 Compounds covalently linked to a(n inert) carrier molecule, e.g. conjugates, pro-fragrances
• CPC Class Codes: A61K 8/8164 Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers, e.g. poly (methyl vinyl ether-co-maleic anhydride)
• CPC Class Codes: A61Q 17/04 Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
• CPC Class Codes: C08F 222/06 Maleic anhydride
• CPC Class Codes: C08F 8/30 Introducing nitrogen atoms or nitrogen-containing groups

Abstract

Personal care compositions comprising a polymer-bound UV absorber are described that provide enhanced properties, including customizable UV spectrum protection, broad-spectrum UV spectrum protection, water resistance, and labile UV stabilization. The polymer comprises anhydride functionality, such as maleic anhydride or a derivative thereof, and the UV absorber contains at least one hydroxyl, primary amine, or secondary amine group.

The personal care compositions may be used to treat and/or protect against burns, cancers, erythema, lentigo (“liver spots”), keratotic lesions, wrinkles, and cellular changes of the skin; and/or color changes, embrittlement, lack of luster, tangles, split ends, and/or unmanageability of the hair.

Claims

1. A personal care composition comprising at least one cosmetic or pharmaceutical ingredient selected from the group comprising:

actives, anti-oxidants, colorants, defoamers, emollients, fragrances, humectants, labile UV absorbers, lower monoalcohols, lower polyols, oils, pigments, preservatives, propellants, surfactants, thickeners, UV absorbers, waxes, and blends thereof and in the form of an aerosol, conditioner, cream, dispersion, emulsion, foundation, gel, lotion, mist, moisturizer, mousse, paste, powder, roll-on, shampoo, stick, spray, suspension, or wipe and from 0.01% to about 100% of a polymer-bound UV absorber comprising at least one unit having the structure;

2. The personal care composition of claim 1 wherein said UV-absorbing polymer comprises at least one unit having the structure:

3. The composition of claim 1 or 2 wherein said unit having the structure:

4. The composition of claim 3 wherein said polymer backbone is derived from a polymer selected from the group consisting of:

homopolymers and non-homopolymers of polybutadienes and polyisoprenes.

5. The composition of claim 1 wherein said unit having the structure:

6. The composition of claim 5 wherein said polymer backbone is derived from a polymer selected from the group consisting of:

homopolymer, copolymers, and non-homopolymers of;

maleic anhydride, and halogenated analogues thereof.

7. The composition of claim 6 wherein said copolymers comprise repeating units selected from the group consisting of:

alkylacrylamides including acrylamide and methacrylamide, acrylates, allyl derivatives, benzoxanes, cinnamyls, epoxides, fumarates, maleates, maleimides, oxazolines, oxetanes, styrenes, vinyl acetates, vinyl acrylamides, vinyl carbonates, vinyl ethers, vinyl imidazoles, vinyl triazoles, vinyl lactams, vinyl pyridines, vinyl silanes, vinyl sulfones, and mixtures thereof.

8. The composition of claim 1 or 2 wherein said polymer-bound UV absorber has a molecular weight from about 200 amu to about 5,000,000 amu.

9. The composition of claim 1 or 2 wherein said polymer-bound UV absorber comprises a UV absorber selected from the group consisting of:

aminobenzoic acid;

2-aminobenzophenone;

amyl dimethyl PABA;

bemotrizinol;

benzophenone-3;

benzophenone-4;

benzophenone-9;

2-(2H-benzotriazole-2-yl)-4,6-di-tert-pentylphenol;

2-(2H-benzotriazole-2-yl)-4-methylphenol;

2-(2H-benzotriazole-2-yl)-4,6-bis(1-methyl-1-phenylethyl)phenol;

bis-benzoxazoyl phenyl ethylhexyl amino triazine;

3-benzylidene camphor sulfonic acid;

CAS number 152261-33-1;

N,N′

-bisformyl-N,N′

-bis-(2,2,6,6-tetramethyl-4-piperidinyl)-hexamethylendiamine;

bisoctrizole;

2-[(p-(tert-butylamido)-anilino]-4,6,-bis[(p-(2′

-ethylhexyl-1′

-oxycarbonyl)-anilino]-1,3,5-triazine;

6-tert-butyl-2-(5-chloro-2H-benzotriazole-2-yl)-4-methylphenol;

2,4-di-tert-butyl-6-(5-chloro-2H-benzotriazole-2-yl)-phenol;

camphor benzalkonium methosulfate;

diethanolamine p-methoxycinnamate;

diethylaminohydroxybenzoylhexylbenzoate;

diethylhexyl butamido triazone;

digalloyl trioleate;

dioxybenzone;

disodium phenyl dibenzimidazole tetrasulfonate;

drometrizole trisiloxane;

ecamsule;

ensulizole;

ethyl 4-bis(hydroxypropyl)aminobenzoate;

ethylhexyl p-methoxycinnamate;

2-ethylhexyl salicylate;

ethylhexyl triazone;

beta-2-glucopyranoxypropylhydroxybenzophenone;

glyceryl aminobenzoate;

homomenthyl salicylate;

[2-hydroxy-4-(octyloxy)phenyl](phenyl)methanone;

2-[bis(2-hydroxyethyl)amino]ethyl salicylate;

(E)-3-(4-hydroxy-3-methoxyphenyl)prop-2-enoic acid;

lawsone with dihydroxyacetone;

meradimate;

methoxycinnamido propyl hydroxy sultaine menthyl anthranilate;

meradimate;

methyl-2-aminobenzoate;

oxybenzone;

2-phenylbenzimidazole-5-sulfonic acid (and its potassium, sodium and triethanolamine salts);

sulisobenzone;

bis-(2,2,6,6-tetramethyl-4-piperidyl)-sebacate;

sterically hindered oligomeric amine, triethanolamine salicylate, and blends thereof.

10. The composition of claim 9 wherein said polymer-bound UV absorber comprises more than one UV absorber.

11. The personal care composition of claim 1 that is water resistant or water-proof.