Treating biomass to produce materials useful for biofuels

• US 9,290,821 B2
• Filed: 11/03/2011
• Issued: 03/22/2016
• Est. Priority Date: 11/05/2010
• Status: Active Grant

• Current Assignee: Shell USA Incorporated (Shell Plc)
• Original Assignee: Shell Oil Company (Shell Plc)
• Inventors: Blackbourn, Robert Lawrence, Weider, Paul Richard
• Primary Examiner(s): Carlson, Karen Cochrane
• Assistant Examiner(s): Tichy, Jennifer M. H.
• Application Number:
  US13/288,687
• Publication Number:
  US 20120122152A1
• Time in Patent Office: 1,601 Days
• Field of Search: None
• US Class Current: 1/1
• CPC Class Codes: C08H 8/00 Macromolecular compounds derived from lignocellulosic materials pretreatment thereof B27N
• CPC Class Codes: C13K 1/02 obtained by saccharification of cellulosic materials manufacture of fodder A23K10/32
• CPC Class Codes: C13K 1/04 Purifying
• CPC Class Codes: C13K 13/002 Xylose
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel

Abstract

Fermentable sugar useful for the production of biofuels can be produced from biomass by contacting the biomass with a solution containing at least one α-hydroxysulfonic acid. The α-hydroxysulfonic acid can be easily removed from the product and recycled.

Claims

1. A method comprising:

a) providing a biomass containing polysaccharides; and

b) contacting the biomass with a solution containing at least one α

-hydroxysulfonic acid thereby hydrolyzing the biomass to produce at least one fermentable sugar containing product.

2. The method of claim 1 wherein further comprising (c) removing the α

-hydroxysulfonic acid in its component form from the product by heating and/or reducing pressure to produce an acid-removed product containing at least one fermentable sugar substantially free of the α

-hydroxysulfonic acid.

3. The method of claim 1 wherein the α

-hydroxysulfonic acid is present in an amount of from about 1% wt. to about 55% wt., based on the solution.

4. The method of claim 1 wherein the α

-hydroxysulfonic acid is produced from (a) a carbonyl compound or a precursor to a carbonyl compound with (b) sulfur dioxide or a precursor to sulfur dioxide and (c) water.

5. The method of claim 1 wherein the α

-hydroxysulfonic acid is in-situ generated.

6. The method of claim 3 wherein step (b) is carried out at a temperature within the range of about 50°

C. to about 150°

C. and a pressure within the range of 1 barg to about 10 barg.

7. The method of claim 2 wherein the α

-hydroxysulfonic acid is present in an amount of from about 1% wt. to about 55% wt., based on the solution.

8. The method of claim 2 wherein the α

-hydroxysulfonic acid is produced from (a) a carbonyl compound or a precursor to a carbonyl compound with (b) sulfur dioxide or a precursor to sulfur dioxide and (c) water.

9. The method of claim 2 wherein the α

-hydroxysulfonic acid is in-situ generated.

10. The method of claim 7 wherein step (b) is carried out at a temperature within the range of about 50°

C. to about 150°

C. and a pressure within the range of 1 barg to about 10 barg.

11. The method of claim 1 wherein the at least one fermentable sugar comprises a pentose.

12. The method of claim 1 wherein the at least one fermentable sugar comprises a hexose.

13. The method of claim 1 wherein in step (b) at least one pentose and at least one hexose is produced.

14. The method of claim 1 further comprising (d) separating a liquid stream containing said fermentable sugar and a wet solid stream containing remaining biomass from the acid-removed product.

15. The method of claim 2 further comprising (d) separating a liquid stream containing said fermentable sugar and a wet solid stream containing remaining biomass from the acid-removed product.

16. The method of claim 15 further comprising (e) hydrolyzing the wet solid stream thereby producing a sugar stream.

17. The method of claim 16 further comprising (f) fermenting the sugar stream thereby producing fermented products.

18. The method of claim 2 further comprising hydrolyzing and fermenting the stream containing fermentable sugar thereby producing fermented products.

19. The method of claim 15 further comprising fermenting the liquid stream containing fermentable sugar.

20. The method of claim 2 wherein the α

-hydroxysulfonic acid removed in step (c) is recycled to step (b) as components and/or in its recombined form.

21. The method of claim 7 wherein the α

-hydroxysulfonic acid removed in step (c) is recycled to step (b) as components and/or in its recombined form.

22. The method of claim 9 wherein the α

-hydroxysulfonic removed in step (c) is recycled to step (b) as components and/or in its recombined form.

23. The method of claim 10 wherein the α

-hydroxysulfonic acid removed in step (c) is recycled to step (b) as components and/or in its recombined form.

24. The method of claim 6 wherein the α

-hydroxysulfonic acid is present in an amount of from about 1% wt. to about 40% wt., based on the solution.

25. The process of claim 6 wherein the biomass is contacted with the α

-hydroxysulfonic acid at a temperature of 120°

C. or less.

26. The method of claim 2 wherein no more than about 2 wt % of the α

-hydroxysulfonic acid is present in the acid-removed product.

27. The method of claim 4 wherein the carbonyl compound is an aldehyde.

28. The method of claim 1 wherein further comprising (c) removing at least a portion of the α

-hydroxysulfonic acid in its component form from the product by heating and/or reducing pressure to produce an acid-removed product containing at least one fermentable sugar.

29. The method of claim 28 wherein no more than about 2 wt % of the α

-hydroxysulfonic acid is present in the acid-removed product.

30. The method of claim 28 wherein the α

-hydroxysulfonic acid is produced from (a) a carbonyl compound or a precursor to a carbonyl compound with (b) sulfur dioxide or a precursor to sulfur dioxide and (c) water.

31. The method of claim 28 wherein the α

-hydroxysulfonic acid is present in an amount of from about 1% wt. to about 55% wt., based on the solution.

32. The method of claim 31 wherein step (b) is carried out at a temperature within the range of about 50°

C. to about 150°

C. and a pressure within the range of 1 barg to about 10 barg.

33. The method of claim 30 wherein the carbonyl compound is an aldehyde.

34. A method comprising:

(a) providing a biomass containing polysaccharides;

(b) contacting the biomass with a solution containing at least one α

-hydroxysulfonic acid in an amount of from about 1% wt. to about 55% wt., based on the solution, at a temperature within the range of about 50°

C. to about 150°

C. and a pressure within the range of 1 barg to about 10 barg thereby hydrolyzing the biomass to produce at least one fermentable sugar containing product;

(c) removing at least a portion of the α

-hydroxysulfonic acid in its component form from the product by heating and/or reducing pressure to produce an acid-removed product containing at least one fermentable sugar; and

(d) recycling the α

-hydroxysulfonic acid removed in step (c) to step (b) as components and/or in its recombined form.

35. The method of claim 34 wherein no more than about 2 wt % of the α

-hydroxysulfonic acid is present in the acid-removed product.