Nano-antenna based infrared molecular taggants

• US 9,291,607 B2
• Filed: 08/14/2012
• Issued: 03/22/2016
• Est. Priority Date: 08/14/2012
• Status: Active Grant

• Current Assignee: Empire Technology Development LLC (Allied Inventors Management, LLC)
• Original Assignee: Empire Technology Development LLC (Allied Inventors Management, LLC)
• Inventors: Chen, Sung-Wei, Rothfuss, Christopher J.
• Primary Examiner(s): Le, Thien M
• Application Number:
  US13/879,751
• Publication Number:
  US 20140205749A1
• Time in Patent Office: 1,316 Days
• Field of Search: 235/454, 235/486, 235/487, 235/492, 235/488
• US Class Current: 1/1
• CPC Class Codes: G01N 33/00 Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
• CPC Class Codes: G01N 33/587 Nanoparticles
• CPC Class Codes: H01Q 1/2225 used in active tags, i.e. provided with its own power source or in passive tags, i.e. deriving power from RF signal
• CPC Class Codes: Y10T 436/13 Tracers or tags

Abstract

A detectable taggant is described. The detectable taggant may include at least one nano-antenna having a resonant frequency of about 300 GHz to about 800 THz. The nano-antenna is adapted to be physically or chemically associated with an article of manufacture.

Claims

1. A detectable taggant comprising:

at least one nano-antenna having a resonant frequency of about 300 GHz to about 800 THz (far infrared to optical),

wherein the nano-antenna is adapted to be physically or chemically associated with a radio frequency tag by a thiol-containing moiety.

2. The detectable taggant of claim 1, wherein an architecture of the nano-antenna comprises a dipole, a monopole, a linear model, Yagi-Uda type, a log-periodic array, a collinear array, an extra short dipole, or a combination thereof.

3. The detectable taggant of claim 1, wherein the nano-antenna is chemically conjugated to the radio frequency tag by non-covalent, covalent, or ionic bonding.

4. The detectable taggant of claim 1, wherein the nano-antenna comprises a metal, a semi-metal, a conductor, a dielectric, a conducting polymer, a semiconductor, a carbon allotrope, a DNA molecule, a biomolecule, or a combination thereof.

5. The detectable taggant of claim 1, wherein the nano-antenna comprises a metal nanowire.

6. The detectable taggant of claim 5, wherein the nanowire has a diameter of about 1 nm to about 500 nm.

7. The detectable taggant of claim 5, wherein the nanowire has a length of about 100 nm to about 10 μ

m.

8. The detectable taggant of claim 5, wherein the metal nanowire comprises one or more of gold, silver, platinum, palladium, copper, titanium, aluminum, cobalt, zinc, manganese, nickel, tantalum, iron, tungsten, chromium, molybdenum, niobium, cadmium, gallium, indium, lead, tin, and alloys thereof.

9. The detectable taggant of claim 1, wherein the nano-antenna is adapted to be conjugated to a carrier particle.

10. The detectable taggant of claim 9, wherein the carrier particle is used as a support material or as a linker to conjugate the nano-antenna to the radio frequency tag.

11. The detectable taggant of claim 9, wherein the carrier particle is a dendrimer.

12. A method of labeling a radio frequency tag with a detectable taggant, the method comprising:

providing a detectable taggant comprising a nano-antenna, wherein the nano-antenna has a resonant frequency of about 300 GHz to about 800 THz; and

disposing the taggant on or in the radio frequency tag, wherein the nano-antenna is adapted to be associated with the radio frequency tag by a thiol-containing moiety.

13. The method of claim 12, wherein disposing the taggant comprises physically or chemically associating the nano-antenna with the radio frequency tag.

14. The method of claim 12, further comprising mixing the nano-antenna in a precursor solution from which the radio frequency tag is manufactured.

15. The method of claim 12, further comprising chemically conjugating the nano-antenna to the radio frequency tag by non-covalent, covalent, or ionic bonding.

16. The method of claim 12, wherein providing the detectable taggant comprises the nano-antenna selected from a metal, a semi-metal, a conductor, a dielectric, a conducting polymer, a semiconductor, a carbon allotrope, a DNA, a biomolecule, and a combination thereof.

17. The method of claim 12, wherein providing the detectable taggant comprises synthesizing the nano-antenna by electrodeposition assisted by a template.

18. The method of claim 12, further comprising conjugating the nano-antenna to a carrier particle prior to disposing the taggant.

19. The method of claim 18, further comprising conjugating the nano-antenna to the radio frequency tag by using the carrier particle as a support material or as a linker.

20. A method of encoding information on or in a radio frequency tag, the method comprising:

selecting at least one nano-antenna to encode the information, wherein the nano-antenna has a resonant frequency of about 300 GHz to about 800 THz;

providing the nano-antenna; and

disposing the nano-antenna on or in the radio frequency tag, wherein the nano-antenna is adapted to be associated with the radio frequency tag by a thiol-containing moiety.

21. The method of claim 20, wherein disposing the nano-antenna comprises physically or chemically associating the nano-antenna with the radio frequency tag.

22. The method of claim 20, wherein selecting at least one nano-antenna comprises the information is encoded as a function of the properties the nano-antenna selected from spatial location, resonance frequency, frequency response, gain, polarization, and any combination thereof.

23. The method of claim 20, further comprising retrieving the information by irradiating the radio frequency tag with radiation of at least one frequency from about 300 GHz to about 800 THz.

24. The method of claim 20, further comprising using the information for tracking the radio frequency tag, authenticating the radio frequency tag, or recycling the radio frequency tag.

25. The method of claim 20, further comprising encoding the information using binary combinatorial binning.

26. The method of claim 20, further comprising encoding the information using specific spatial patterns.

27. The method of claim 20, further comprising encoding the information using directional patterns or polarization patterns.

28. A system of detecting a radio frequency tag comprising:

a detectable taggant comprising a plurality of nano-antennas having a resonance frequency of about 300 GHz to about 800 THz on the radio frequency tag,

wherein information is encoded on the detectable taggant using at least one property of the plurality of nano-antennas;

disposing the detectable taggant on the radio frequency tag, wherein the nano-antenna is adapted to be associated with the radio frequency tag by a thiol-containing moiety; and

retrieving the information encoded on the detectable taggant.