Phase immersion emulsification process and apparatus

• US 9,291,925 B2
• Filed: 03/08/2013
• Issued: 03/22/2016
• Est. Priority Date: 03/08/2013
• Status: Active Grant

• Current Assignee: Xerox Corporation (Xerox Holdings Corp.)
• Original Assignee: Xerox Corporation (Xerox Holdings Corp.)
• Inventors: Liu, Yu, Wang, Yulin, Lee, Frank Ping-Hay, Zhou, Ke
• Primary Examiner(s): Dote, Janis L
• Application Number:
  US13/790,290
• Publication Number:
  US 20140255842A1
• Time in Patent Office: 1,110 Days
• Field of Search: 430/137.14, 523/326, 523/328, 524/356
• US Class Current: 1/1
• CPC Class Codes: C08J 3/07 from polymer solutions
• CPC Class Codes: C08K 5/05 Alcohols; Metal alcoholates
• CPC Class Codes: C08K 5/07 Aldehydes; Ketones
• CPC Class Codes: G03G 9/0804 whereby the components are brought together in a liquid dispersing medium

Abstract

A method for preparing a latex or dispersion, the method comprising contacting at least one resin with an organic solvent to form a resin mixture; neutralizing the resin mixture with a neutralizing agent; and subjecting the resin mixture flow to steam flow in a continuous manner to form a dispersion. A method for forming toner, the method comprising: contacting a resin to an organic solvent and a neutralizing agent to form a resin mixture; subjecting the resin mixture flow to a steam flow in a continuous manner to form a dispersion; aggregating particles from a pre-toner mixture, the pre-toner mixture comprising the dispersion, an optional colorant, and an optional wax; and coalescing the aggregated particles to form toner particles. An apparatus that can perform the methods.

Claims

1. A method for preparing a latex or dispersion, the method comprising:

contacting at least one resin with an organic solvent to form a resin mixture;

neutralizing the resin mixture with a basic neutralizing agent;

subjecting the resin mixture to steam flow in a continuous manner to form a dispersion by continually pumping the resin mixture and the steam flow into a mixing zone thereby forming a latex where the resin mixture and steam flow contact within the mixing zone; and

removing the latex from the mixing zone;

wherein the latex formation in the mixing zone requires no mechanical mixing.

2. The method according to claim 1, wherein the organic solvent is selected from the group consisting of a ketone, an alcohol, an ester, a nitrile, a sulfone, a sulfoxide, a phosphoramide, a benzene, an amine, and combinations thereof.

3. The method according to claim 1, wherein the steam introduced to the resin mixture is from about 80°

C. to about 150°

C.

4. The method according to claim 1, wherein the basic neutralizing agent is selected from the group consisting of ammonium hydroxide, sodium carbonate, potassium hydroxide, sodium hydroxide, sodium bicarbonate, lithium hydroxide, potassium carbonate, triethyl amine, triethanolamine, pyridine, diphenylamine, poly(ethylene amine), amine bases, piperazine, and mixtures thereof.

5. The method according to claim 1, wherein the organic solvent evaporates spontaneously upon introducing the steam in contact with the resin mixture.

6. The method according to claim 1, wherein the resin is selected from the group consisting of amorphous resins, crystalline resins, and mixtures thereof.

7. The method according to claim 1, wherein the dispersion has a particle size from about 5 nm to about 1000 nm.

8. The method according to claim 1, wherein the steam injection is sufficiently turbulent to induce global turbulent mixing.

13. The method according to claim 1, wherein the dispersion has a particle size from about 5 nm to about 1,000 nm.

14. The method according to claim 1, wherein the steam introduced to the resin mixture is from about 80°

C. to about 150°

C.

9. A method for forming toner, the method comprising:

contacting a resin with an organic solvent and a basic neutralizing agent to form a resin mixture;

subjecting the resin mixture to a steam flow in a continuous manner to form a dispersion by continually pumping the resin mixture and the steam flow into a mixing zone thereby forming a latex where the resin mixture and steam flow contact within the mixing zone;

removing the latex from the mixing zone;

wherein latex formation in the mixing zone requires no mechanical mixing;

aggregating particles from a pre-toner mixture, the pre-toner mixture comprising the dispersion, an optional colorant, and an optional wax; and

coalescing the aggregated particles to form toner particles.

10. The method according to claim 9, wherein the resin is selected from the group consisting of amorphous resins, crystalline resins, and mixtures thereof.

11. The method according to claim 9, wherein the organic solvent is selected from the group consisting of a ketone, an alcohol, an ester, a nitrile, a sulfone, a sulfoxide, a phosphoramide, a benzene, an amine, and combinations thereof.

12. The method according to claim 9, wherein the basic neutralizing agent is selected from the group consisting of ammonium hydroxide, sodium carbonate, potassium hydroxide, sodium hydroxide, sodium bicarbonate, lithium hydroxide, potassium carbonate, triethyl amine, triethanolamine, pyridine, diphenylamine, poly(ethylene amine), amine bases, piperazine, and mixtures thereof.