Proton exchange membrane fuel cell

• US 9,293,778 B2
• Filed: 06/11/2007
• Issued: 03/22/2016
• Est. Priority Date: 06/11/2007
• Status: Active Grant

• Current Assignee: Emergent Power Inc. (Plug Power Inc.)
• Original Assignee: Emergent Power Inc. (Plug Power Inc.)
• Inventors: Spink, Scott A., Lott, David R., Wright, Matthew M., Yemul, Dinesh S., Fuglevand, William A., Duan, Runrun, Bai, Lijun, Bayuuk, Shiblihanna I.
• Primary Examiner(s): Eggerding, Alix
• Application Number:
  US11/811,624
• Publication Number:
  US 20080305378A1
• Time in Patent Office: 3,207 Days
• Field of Search: None
• US Class Current: 1/1
• CPC Class Codes: H01M 4/8807 Gas diffusion layers
• CPC Class Codes: H01M 8/0236 Glass; Ceramics; Cermets
• CPC Class Codes: H01M 8/0245 in the form of layered or coated products
• CPC Class Codes: H01M 8/1004 characterised by membrane-electrode assemblies [MEA] H01M8/12 takes precedence
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A proton exchange membrane fuel cell is described and which includes a proton exchange membrane having at least one gas diffusion layer which is juxtaposed relative thereto, and which is fabricated, at least in part, of a porous, electrically conductive, inorganic material which is selected from the group comprising metal diborides, metal disilicides, metal nitrides, metal carbides, and composites, laminates and solid solutions thereof.

Claims

1. A proton exchange membrane fuel cell, comprising:

a copolymer proton exchange membrane having at least one gas diffusion layer which is juxtaposed relative thereto, the at least one gas diffusion layer fabricated solely of a porous, electrically conductive, inorganic material which is selected from the group comprising metal diborides, metal disilicides, metal nitrides, metal carbides, and composites, laminates and solid solutions thereof,

wherein the proton exchange membrane fuel cell is configured to operate with an intake ambient air temperature range of about 42 to about 58 degrees Celsius and generates water as a byproduct during operation, and

wherein the porous, electrically conductive, inorganic material forming the at least one gas diffusion layer retains an operationally effective amount of liquid water during operation so as to render the proton exchange membrane fuel cell substantially self-humidifying.

2. A proton exchange membrane fuel cell as claimed in claim 1, and wherein the metal is selected from the group comprising group IV to group VI transition metals.

3. A proton exchange membrane fuel cell as claimed in claim 2, and wherein the transition metal is selected from the group comprising titanium, zirconium, vanadium, niobium, tungsten, molybdenum, and tantalum.

4. A proton exchange membrane fuel cell as claimed in claim 1, and wherein the at least one gas diffusion layer fabricated from the inorganic material has a permeability that lies in a range of greater than about 5 Gurley-seconds to less than about 2000 Gurley-seconds.

5. A proton exchange membrane fuel cell as claimed in claim 1, and further comprising a catalyst layer positioned between the at least one gas diffusion layer and the copolymer proton exchange membrane.

6. A proton exchange membrane fuel cell as claimed in claim 5, and wherein the catalyst layer is deposited on the copolymer proton exchange membrane.

7. A proton exchange membrane fuel cell as claimed in claim 5, and further comprising a micro-gas diffusion layer positioned between the catalyst layer and the at least one gas diffusion layer, and wherein the micro-gas diffusion layer has a porosity that differs from the porosity of the at least one gas diffusion layer.

8. A proton exchange membrane fuel cell as claimed in claim 5, and further comprising a micro-gas diffusion layer positioned between the catalyst layer and the at least one gas diffusion layer, and wherein the micro-gas diffusion layer has a hydrophobicity and/or a chemical composition that differs from the hydrophobicity and/or a chemical composition of the at least one gas diffusion layer.

9. A proton exchange membrane fuel cell as claimed in claim 1, and wherein the copolymer proton exchange membrane and the at least one gas diffusion layer are affixed to each other.

10. A proton exchange membrane fuel cell as claimed in claim 1, and wherein the porous, electrically conductive, inorganic material forming the at least one gas diffusion layer has a pore size of about 0.5 to about 200 microns.

11. A proton exchange membrane fuel cell as claimed in claim 1, and wherein the porous, electrically conductive, inorganic material forming the gas diffusion layer is selected from the group of inorganic materials consisting essentially of zirconium diboride, zirconium nitride, titanium nitride, titanium diboride, molybdenum disilicide, titanium disilicide, vanadium carbide and tungsten carbide.

12. A proton exchange membrane fuel cell as claimed in claim 1, and wherein the copolymer proton exchange membrane has an anode and a cathode side, and wherein individual gas diffusion layers are juxtaposed relative to each of the anode and cathode sides, and wherein the copolymer proton exchange membrane is affixed to each of the individual gas diffusion layers to form a unitary assembly.

13. A proton exchange membrane fuel cell, comprising:

a copolymer proton exchange membrane having at least one gas diffusion layer which is juxtaposed relative thereto, the at least one gas diffusion layer fabricated solely of a porous, electrically conductive, inorganic material which is selected from the group comprising metal diborides, metal disilicides, metal nitrides, metal carbides, and composites, laminates and solid solutions thereof,

wherein the proton exchange membrane fuel cell generates water as a byproduct during operation,

wherein the at least one gas diffusion layer is configured to receive an ambient air intake with a temperature range of about 42 to about 58 degrees Celsius, and

wherein the porous, electrically conductive, inorganic material forming the at least one gas diffusion layer retains an operationally effective amount of liquid water during operation so as to render the proton exchange membrane fuel cell substantially self-humidifying.

14. A system, comprising:

a copolymer proton exchange membrane; and

at least one gas diffusion layer which is fabricated solely of a porous, electrically conductive, inorganic material which is selected from the group comprising metal diborides, metal disilicides, metal nitrides, metal carbides, and composites, laminates and solid solutions thereof,

wherein the at least one gas diffusion layer and the copolymer proton exchange membrane are configured to operate as a proton exchange membrane fuel cell with an intake ambient air temperature range of about 42 to about 58 degrees Celsius.

15. The system as claimed in claim 14, wherein the proton exchange membrane fuel cell is further configured to produce an output current of at least 9.5 amperes at a voltage range of approximately 600 mV to 650 mV within the intake ambient air temperature range.

16. The system as claimed in claim 14, wherein the proton exchange membrane fuel cell is configured to generate water as a byproduct during operation, and wherein the porous, electrically conductive, inorganic material forming the at least one gas diffusion layer retains an operationally effective amount of liquid water during operation so as to render the proton exchange membrane fuel cell substantially self-humidifying.