Synergistic pesticidal compositions and related methods

• US 9,295,258 B2
• Filed: 10/17/2014
• Issued: 03/29/2016
• Est. Priority Date: 10/22/2013
• Status: Expired due to Fees

• Current Assignee: Dow Agrosciences LLC (Corteva, Inc.)
• Original Assignee: Dow Agrosciences LLC (Corteva, Inc.)
• Inventors: Gomez, Luis E., Hunter, Ricky, Shaw, Mike, Trullinger, Tony K., Kubiszak, Mary E.
• Primary Examiner(s): HENLEY III, RAYMOND J
• Application Number:
  US14/517,235
• Publication Number:
  US 20150111926A1
• Time in Patent Office: 529 Days
• Field of Search: 514/341
• US Class Current: 1/1
• CPC Class Codes: A01N 37/28 containing the group; Thio analogues thereof
• CPC Class Codes: A01N 37/40 having at least one carboxylic group or a thio analogue, or a derivative thereof, and one oxygen or sulfur atom attached to the same aromatic ring system
• CPC Class Codes: A01N 43/12 condensed with a carbocyclic ring
• CPC Class Codes: A01N 43/16 with oxygen as the ring hetero atom
• CPC Class Codes: A01N 43/56 1,2-Diazoles; Hydrogenated 1,2-diazoles

Abstract

A pesticidal composition comprises a synergistically effective amount of an ecdysone receptor agonist compound and a pesticide selected from N-(3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl)-N-ethyl-3-((3,3,3-trifluoropropyl)thio)propanamide (I), N-(3-chloro-1-(pyridine-3-yl)-1H-pyrazol-4-yl)-N-ethyl-3-((3,3,3-trifluoropropyl)sulfinyl)propanamide (II), or any agriculturally acceptable salt thereof. A method of controlling pests comprises applying the pesticidal composition near a population of pests. A method of protecting a plant from infestation and attack by insects comprises contacting the plant with the synergistic pesticidal composition.

Claims

1. A pesticidal composition comprising a synergistically effective amount of:

an ecdysone receptor agonist compound; and

a pesticide selected from N-(3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl)-N-ethyl-3-((3,3,3-trifluoropropyl)thio)propanamide (I), N-(3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl)-N-ethyl-3-((3,3,3-trifluoropropyl)sulfinyl)propanamide (II), or any agriculturally acceptable salt thereof

2. The composition of claim 1, wherein the ecdysone receptor agonist compound comprises a diacylhydrazine-based compound.

3. The composition of claim 1, wherein the ecdysone receptor agonist compound comprises at least one of chromafenozide, halofenozide, tebufenozide, and fufenozide.

4. The composition of claim 1, wherein the ecdysone receptor agonist compound comprises methoxyfenozide.

5. The composition of claim 1, further comprising a phytologically-acceptable inert carrier.

6. The composition of claim 1, further comprising an additive selected from a surfactant, a stabilizer, an emetic agent, a disintegrating agent, an antifoaming agent, a wetting agent, a dispersing agent, a binding agent, dye, filler, or combinations thereof.

7. The composition of claim 1, further comprising one or more compounds having acaricidal, algicidal, avicidal, bactericidal, fungicidal, herbicidal, insecticidal, molluscicidal, nematicidal, rodenticidal, virucidal or combinations thereof properties.

8. The composition of claim 1, further comprising one or more compounds that are antifeedants, bird repellents, chemosterilants, herbicide safeners, insect attractants, insect repellents, mammal repellents, mating disrupters, plant activators, plant growth regulators, synergists, or combinations thereof.

9. The composition of claim 1, wherein a weight ratio of the pesticide selected from (I), (II) or any agriculturally acceptable salt thereof to the ecdysone receptor agonist compound is no more than about 1:

2.5.

10. The composition of claim 1, wherein a weight ratio of the pesticide selected from (I), (II) or any agriculturally acceptable salt thereof to the ecdysone receptor agonist compound is no more than about 1:

4.

11. The composition of claim 1, wherein a weight ratio of the pesticide selected from (I), (II) or any agriculturally acceptable salt thereof to the ecdysone receptor agonist compound is no more than about 1:

32.

12. The composition of claim 1, wherein the weight ratio of the pesticide (I), (II), or any agriculturally acceptable salt thereof and the ecdysone receptor agonist compound is X:

Y;

wherein,

X is the parts by weight of the pesticide (I), (II), or any agriculturally acceptable salt thereof, and the numerical range is 0<

X≦

20;

Y is the parts by weight of the ecdysone receptor agonist compound, and the numerical range is 0<

Y≦

20.

13. The composition of claim 10, wherein the ranges of weight ratios of the pesticide (I), (II), or any agriculturally acceptable salt thereof and the ecdysone receptor agonist compound are X₁:

Y₁ to X₂;

Y₂, wherein one of the following conditions is satisfied;

(a) X₁>

Y₁ and X₂<

Y₂;

or

(b) X₁>

Y₁ and X₂>

Y₂;

or

(c) X₁<

Y₁ and X₂<

Y₂.

14. A method of controlling pests comprising applying a pesticidal composition near a population of pests, wherein the pesticidal composition comprises a synergistically effective amount of:

an ecdysone receptor agonist compound; and

a pesticide selected from N-(3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl)-N-ethyl-3-((3,3,3-trifluoropropyl)thio)propanamide (I), N-(3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl)-N-ethyl-3-((3,3,3-trifluoropropyl)sulfinyl)propanamide (II), or any agriculturally acceptable salt thereof

15. The method of claim 14, wherein the ecdysone receptor agonist compound comprises a diacylhydrazine-based compound.

16. The method of claim 14, wherein the ecdysone receptor agonist compound comprises at least one of chromafenozide, halofenozide, tebufenozide, and fufenozide.

17. The method of claim 14, wherein the ecdysone receptor agonist compound comprises methoxyfenozide.

18. The method of claim 14, wherein the pests include cotton aphid, Aphis gossypii (Glover).

19. The method of claim 14, wherein the pests include diamondback moth, Plutella xylostella.

20. A method for protecting a plant from infestation and attack by pests, the method comprising:

contacting the plant with a pesticidal composition comprising a synergistically effective amount of an ecdysone receptor agonist compound in combination with a pesticide selected from N-(3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl)-N-ethyl-3-((3,3,3-trifluoropropyl)thio) propanamide (I), N-(3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl)-N-ethyl-3-((3,3,3-trifluoropropyl) sulfinyl)propanamide (II), or any agriculturally acceptable salt thereof

21. The method of claim 20, wherein the ecdysone receptor agonist compound comprises a diacylhydrazine-based compound.

22. The method of claim 20, wherein the ecdysone receptor agonist compound comprises at least one of chromafenozide, halofenozide, tebufenozide, and fufenozide.

23. The method of claim 20, wherein the ecdysone receptor agonist compound comprises methoxyfenozide.