Process for separating off acid gases from a water-comprising fluid stream

• US 9,295,942 B2
• Filed: 09/05/2013
• Issued: 03/29/2016
• Est. Priority Date: 09/05/2012
• Status: Active Grant

• Current Assignee: BASF SE
• Original Assignee: BASF SE
• Inventors: Katz, Torsten, Bartling, Karsten
• Primary Examiner(s): VANOY, TIMOTHY C
• Application Number:
  US14/018,520
• Publication Number:
  US 20140065040A1
• Time in Patent Office: 936 Days
• US Class Current: 1/1
• CPC Class Codes: B01D 2252/204 Amines
• CPC Class Codes: B01D 2257/30 Sulfur compounds
• CPC Class Codes: B01D 2257/40 Nitrogen compounds
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 2258/0283 Flue gases
• CPC Class Codes: B01D 2258/05 Biogas
• CPC Class Codes: B01D 53/1418 Recovery of products
• CPC Class Codes: B01D 53/1425 Regeneration of liquid absorbents
• CPC Class Codes: B01D 53/1456 Removing acid components
• CPC Class Codes: B01D 53/1493 Selection of liquid materials for use as absorbents
• CPC Class Codes: B01D 53/40 Acidic components B01D53/44 takes precedence
• CPC Class Codes: C10L 3/102 of acid contaminants
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

A process for separating off acid gases from a water-comprising fluid stream wherein the water-comprising fluid stream is contacted in an absorption zone with an absorbent, producing a deacidified fluid stream and an acid gas-loaded absorbent; the deacidified fluid stream is contacted in a scrubbing zone with an aqueous scrubbing liquid, producing a deaminated, deacidified fluid stream and an amine-loaded scrubbing liquid which is cooled, producing an absorber top condensate; the loaded absorbent is passed into a desorption zone producing a regenerated absorbent and desorbed acid gases; the regenerated absorbent is returned to the absorption zone in order to form an absorbent circuit, to which the amine-loaded scrubbing liquid and the absorber top condensate are introduced; and the desorbed acid gases are conducted through an enrichment zone and the acid gases exiting at the top of the enrichment zone are cooled, producing a desorber top condensate.

Claims

1. A process for separating off acid gases from a water-comprising fluid stream, said process comprising

a) contacting the water-comprising fluid stream in an absorption zone with an absorbent that comprises at least one amine, wherein a deacidified fluid stream and an acid gas-loaded absorbent is obtained,

b) contacting the deacidified fluid stream in a scrubbing zone with a single pass of an aqueous scrubbing liquid to transfer at least in part entrained amine in the deacidified fluid stream to the scrubbing liquid, the scrubbing liquid flowing out of the scrubbing zone without recirculating to the scrubbing zone, and a deaminated, deacidified fluid stream and an amine-loaded scrubbing liquid are obtained,

c) cooling the deaminated, deacidified fluid stream in an indirect cooler downstream of the scrubbing zone, wherein an absorber top condensate is condensed out of the deaminated, deacidified fluid stream,

d) passing the loaded absorbent into a desorption zone in which acid gases are at least in part released, wherein a regenerated absorbent and desorbed acid gases are obtained,

e) returning the regenerated absorbent to the absorption zone in order to form an absorbent circuit,

f) introducing the amine-loaded scrubbing liquid and the absorber top condensate into the absorbent circuit, and

g) conducting the desorbed acid gases through an enrichment zone and cooling the acid gases exiting at the top of the enrichment zone, in order to condense out of the acid gases a desorber top condensate which in part is returned to the enrichment zone and in part is passed out of the process.

2. The process of claim 1, wherein the desorber top condensate comprises less than 500 ppm by weight of amines and amine decomposition products.

3. The process of claim 1, wherein the scrubbing liquid comprises absorber top condensate, desorber top condensate and/or fresh water.

4. The process of claim 1, wherein the amine-loaded scrubbing liquid is passed into the absorption zone.

5. The process of claim 1, wherein the deaminated, deacidified fluid stream is cooled to a temperature which is lower than the temperature of the water-comprising fluid stream.

6. The process of claim 1, wherein the enrichment zone comprises a structured packing, a random packing, or a plurality of trays.

7. The process of claim 6, wherein the structured packing or the random packing comprises a height of at least 1.5 meters.

8. The process of claim 6, wherein the number of the trays is at least 4.

9. The process of claim 1, wherein the loaded absorbent is regenerated in the desorption zone by at least one measure selected from expansion, stripping with an inert gas, or heating.

10. The process of claim 9, wherein the absorbent loaded with acid gases is preheated by indirect heat exchange with the regenerated absorbent prior to entry into the desorption zone.

11. The process of claim 1, wherein the loaded absorbent is expanded into an expansion vessel, wherein a gas phase and an expanded absorbent are obtained, and the expanded absorbent is passed into the desorption zone.

12. The process of claim 11, wherein at least a part of the absorber top condensate is introduced into the expansion vessel.

13. The process of claim 1, wherein the water-comprising fluid stream has a water content which is at least 20% of the saturation concentration of water.

14. The process of claim 1, wherein the water-comprising fluid stream is introduced into the absorption zone at a pressure of 50 to 70 bar.

15. The process of claim 1, wherein the water-comprising fluid stream has an acid gas partial pressure of less than 2.5 bar.

16. The process of claim 1, wherein the water-comprising fluid stream is selected from

a) natural gas,

b) synthesis gas,

c) off-gases of various refinery processes,

d) combustion gases, or

e) gas that is obtained from a Claus process.

17. The process of claim 1, wherein the water-comprising fluid stream has a water content which is at least 20% of the saturation concentration of water, an acid gas partial pressure of less than 2.5 bar, and is introduced into the absorption zone at a pressure of 50 to 70 bar.