Process for recovering sugars from a pretreatment stream of lignocellulosic biomass

• US 9,296,830 B2
• Filed: 09/29/2011
• Issued: 03/29/2016
• Est. Priority Date: 09/29/2010
• Status: Active Grant

• Current Assignee: Versalis S.P.A, (Eni Petroleum Company Incorporated)
• Original Assignee: Beta Renewables SpA
• Inventors: Ottonello, Piero, Ferrero, Simone, Torre, Paolo, Cherchi, Francesco, Defaveri, Danilo, Oriani, Luis
• Primary Examiner(s): Brunsman, David M
• Application Number:
  US13/817,869
• Publication Number:
  US 20130158253A1
• Time in Patent Office: 1,643 Days
• US Class Current: 1/1
• CPC Class Codes: C08B 37/0057 beta-D-Xylans, i.e. xylosaccharide, e.g. arabinoxylan, arabinofuronan, pentosans; (beta-1,3)(beta-1,4)-D-Xylans, e.g. rhodymenans; Hemicellulose; Derivatives thereof
• CPC Class Codes: C08H 8/00 Macromolecular compounds derived from lignocellulosic materials pretreatment thereof B27N
• CPC Class Codes: C12P 19/02 Monosaccharides 2-ketogulonic acid C12P7/60
• CPC Class Codes: C12P 2201/00 Pretreatment of cellulosic or lignocellulosic material for subsequent enzymatic treatment or hydrolysis
• CPC Class Codes: C13K 1/02 obtained by saccharification of cellulosic materials manufacture of fodder A23K10/32
• CPC Class Codes: C13K 13/002 Xylose
• CPC Class Codes: C13K 13/007 Separation of sugars provided for in subclass C13K C13K3/00 takes precedence
• CPC Class Codes: D21B 1/02 Pretreatment of the raw materials by chemical or physical means removal of bark B27L
• CPC Class Codes: D21B 1/12 by wet methods, by the use of steam beaters D21D1/00
• CPC Class Codes: D21B 1/36 Explosive disintegration by sudden pressure reduction
• CPC Class Codes: D21C 1/02 with water or steam

Abstract

This specification discloses an improved method for conducting the removal of C5 xylan based sugars from biomass. The improved method involves a series of soakings and washings of the biomass as opposed to conducting one soaking and washing step.

Claims

1. A process for the soaking of lignocellulosic biomass, comprising the steps of

A) introducing a lignocellulosic biomass feedstock into a first soaking zone,

B) soaking the lignocellulosic biomass feedstock in the presence of a liquid or vapor of the liquid for a first time and a first temperature correlating to a first severity of the soaking conditions creating a first liquid comprised of at least one compound selected from the group consisting of xylose and soluble oligomers thereof,

C) separating at least a portion of the first liquid comprised of the at least one compound selected from the group consisting of xylose and soluble oligomers thereof from the biomass of the first soaking,

D) introducing the biomass of the first soaking zone into a second soaking zone in the presence of a liquid for a second time and a second temperature correlating to a second severity of the soaking conditions creating a second liquid comprised of at least one compound selected from the group consisting of xylose and soluble oligomers thereof wherein the second severity is greater than first severity,

E) separating at least a portion of the second free liquid comprised of the at least one compound selected from the group consisting of xylose and soluble oligomers thereof from the biomass of the second soaking,

F) moving the biomass of the second soaking zone into a compressor to prepare the biomass for steam explosion, and

G) moving the biomass from the compressor to a steam explosion device.

2. The process according to claim 1, wherein the soaking of each soaking zone is conducted in a separate vessel.

3. The process according to claim 1, wherein the soaking zones are in a single vessel and the first soaking zone is positioned above the second soaking zone.

4. The process according to claim 1, wherein the soaking zones are in a single vessel and first soaking zone and second soaking zone are horizontal to each other.

5. The process according to claim 1, wherein the soaking zones are in a single vessel and the first soaking zone is located beneath the second soaking zone.

6. The process according to claim 1, comprising the further steps of, after separating at least a portion of the second free liquid and before moving the biomass of the second soaking zone into the compressor, introducing the biomass from the second soaking zone into a third soaking zone in the presence of a liquid for a third time and at a third temperature range correlating to a third severity of the soaking conditions creating a third liquid comprised of at least one compound selected from the group consisting of xylose and soluble oligomers thereof wherein the third severity is greater than second severity, and separating at least a portion of the third liquid comprised of at least one compound selected from the group consisting of xylose and soluble oligomers thereof from the biomass of the third soaking.

7. The process according to claim 2, wherein the soaking of each soaking zone is conducted in a separate vessel.

8. The process according to claim 2, wherein the soaking zones are in a single vessel and the first soaking zone is positioned above the second soaking zone.

9. The process according to claim 2, wherein the soaking zones are in a single vessel and first soaking zone and second soaking zone are horizontal to each other.

10. The process according to claim 2, wherein the soaking zones are in a single vessel and the first soaking zone is located beneath the second soaking zone.