Electrolytic gas generating devices, actuators, and methods

• US 9,297,083 B2
• Filed: 12/16/2013
• Issued: 03/29/2016
• Est. Priority Date: 12/16/2013
• Status: Expired due to Fees

• Current Assignee: Palo Alto Research Center, Inc. (Xerox Holdings Corp.)
• Original Assignee: Palo Alto Research Center, Inc. (Xerox Holdings Corp.)
• Inventors: Abhishek, Ramkumar, Endicott, Frederick Joseph
• Primary Examiner(s): Mendez, Zulmariam
• Application Number:
  US14/107,367
• Publication Number:
  US 20150167184A1
• Time in Patent Office: 834 Days
• Field of Search: 204/244, 204/253, 204/256, 204/267, 204/283, 204/284
• US Class Current: 1/1
• CPC Class Codes: C25B 1/04 by electrolysis of water
• CPC Class Codes: C25B 11/036 Bipolar electrodes
• CPC Class Codes: C25B 9/17 Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
• CPC Class Codes: F03G 7/005 Electro-chemical actuators; Actuators having a material for absorbing or desorbing gas, e.g. a metal hydride; Actuators using the difference in osmotic pressure between fluids; Actuators with elements stretchable when contacted with liquid rich in ions, with UV light, with a salt solution
• CPC Class Codes: Y02E 60/36 Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Abstract

Devices and methods are provided for generating gas(es). A device includes a first layer having a conductive region and an electrode, a sealing layer adjacent the first layer and having a conductive region and a multi-electrode assembly including an ionic layer with a cathode side and an opposed anode side, and a second layer adjacent the sealing layer and having a conductive region and an electrode operably associated with an isolated electrical connector, wherein the device is configured to generate the gas(es) upon application of a voltage to the electrical connector and to the conductive regions of the layers.

Claims

1. An electrochemical actuator, comprising:

a first electrode layer comprising a first electrically conductive region and a plurality of isolated first electrodes configured to allow a first generated gas to be released therethrough;

a sealing layer adjacent the first electrode layer and comprising a second electrically conductive region and a plurality of isolated multi-electrode assemblies, each multi-electrode assembly comprising an ionic material layer having a first side comprising a cathode material and a second side comprising an anode material; and

a second electrode layer adjacent the sealing layer on a side opposite the first electrode layer and comprising a third electrically conductive region and a plurality of isolated second electrodes, each second electrode being configured to allow a second generated gas to be released therethrough and being operably associated with an isolated electrical connector,

wherein each of the first electrodes is aligned with one of the multi-electrode assemblies and one of the second electrodes, to form a plurality of isolated stacks in which the isolated electrical connector and the first electrically conductive region are in electrical communication with opposing sides of the multi-electrode assembly,

wherein the first, second, and third electrically conductive regions are in electrical communication,

wherein the actuator is configured to independently generate the first and second gases from each of the stacks via electrolysis upon application of a voltage to the isolated electrical connector associated with the stack and to the third electrically conductive region.

2. The actuator of claim 1, wherein the ionic material layer comprises a hygroscopic material.

3. The actuator of claim 2, wherein the hygroscopic material comprises nafion.

4. The actuator of claim 1, wherein each isolated electrical connector comprises at least one via.

5. The actuator of claim 1, wherein the first and/or second electrodes comprise perforated electrodes.

6. The actuator of claim 1, wherein the sealing layer comprises a conductive epoxy.

7. The actuator of claim 6, wherein the sealing layer comprises silver epoxy.

8. The actuator of claim 1, wherein the sealing layer comprises solder or a pressure sensitive adhesive.

9. The actuator of claim 1, wherein the first electrode layer comprises a conductive metal shim.

10. The actuator of claim 9, wherein the shim comprises copper.

11. The actuator of claim 1, wherein the cathode material comprises platinum black and the anode material comprises iridium-ruthenium oxide.

12. The actuator of claim 1, wherein the first and second electrodes comprise gold coated copper.

13. The actuator of claim 1, wherein the sealing layer is configured such that the first side of each multi-electrode assembly faces the first electrode layer and the second side of each multi-electrode assembly faces the second electrode layer.

14. The actuator of claim 1, wherein the sealing layer is configured such that the second side of each multi-electrode assembly faces the first electrode layer and the first side of each multi-electrode assembly faces the second electrode layer.

15. The actuator of claim 1, wherein the second electrode layer comprises a printed circuit board and the second electrodes are patterned on the printed circuit board.

16. A drug delivery device comprising the electrochemical actuator of claim 1, wherein the actuator is configured to drive at least one drug from one or more drug-containing reservoirs.

17. The actuator of claim 16, wherein each drug-containing reservoir is in operable communication with one of the plurality of isolated stacks, such that each stack is configured to generate the first generated gas to drive the at least one drug from the drug-containing reservoir in communication therewith.

18. The actuator of claim 17, wherein the first generated gas is hydrogen.

19. A gas generating device, comprising:

a first electrode layer comprising a first electrically conductive region and at least one first perforated electrode configured to allow a first generated gas to be released therethrough;

a sealing layer adjacent the first electrode layer and comprising a second electrically conductive region and at least one multi-electrode assembly, each multi-electrode assembly comprising an ionic material layer having a first side comprising a cathode material and an opposed second side comprising an anode material; and

a printed circuit board adjacent the sealing layer on a side opposite the first electrode layer and comprising a third electrically conductive region and at least one second perforated electrode patterned on the printed circuit board, each second perforated electrode being configured to allow a second generated gas to be released therethrough and being operably associated with an isolated electrical connector,

wherein the first electrically conductive region is in electrical communication with one side of each multi-electrode assembly and each isolated electrical connector is in electrical communication with an opposing side of one of the at least one multi-electrode assemblies,

wherein the first, second, and third electrically conductive regions are in electrical communication,

wherein the device is configured to generate the first and second gases upon application of a voltage to the isolated electrical connector and to the third electrically conductive region.

20. The device of claim 19, wherein the ionic material comprises nafion or another hygroscopic material.

21. An actuator comprising:

the gas generating device of claim 19; and

a displacement system operable via a force produced by a gas from the generating device.

22. A method of generating hydrogen and oxygen, comprising:

providing a device which comprises;

a first electrode layer comprising a first electrically conductive region and a plurality of isolated first electrodes;

a sealing layer adjacent the first electrode layer and comprising a second electrically conductive region and a plurality of isolated multi-electrode assemblies, each multi-electrode assembly comprising an ionic material layer having a first side comprising a cathode material and a second side comprising an anode material; and

a second electrode layer adjacent the sealing layer on a side opposite the first electrode layer and comprising a third electrically conductive region and a plurality of isolated second electrodes, each second electrode being associated with an isolated electrical connector,

wherein the first electrically conductive region is in electrical communication with one side of each multi-electrode assembly and each isolated electrical connector is in electrical communication with an opposing side of one of the multi-electrode assemblies,

wherein the first, second, and third electrically conductive regions are in electrical communication,

wherein each of the first electrodes is aligned with one of the multi-electrode assemblies and one of the second electrodes, to form a plurality of isolated stacks in contact with water; and

applying a voltage to the isolated electrical connector operably associated with one of the stacks and to the third electrically conductive region to selectively hydrolyze the water and thereby generate hydrogen and oxygen which are respectively released through the isolated first and second electrodes of said stack.

23. The method of claim 22, wherein the hydrogen or oxygen create a driving force in an actuator.