Differential ultrasonic waveguide cure monitoring probe

• US 9,297,789 B2
• Filed: 09/20/2012
• Issued: 03/29/2016
• Est. Priority Date: 06/09/2008
• Status: Expired due to Fees

• Current Assignee: Materials And Sensors Technologies, Inc.
• Original Assignee: Materials And Sensors Technologies, Inc.
• Inventors: Djordjevic, Borislav B., Rouch, Lawrence L.
• Primary Examiner(s): Martin, Laura
• Assistant Examiner(s): MILLER, ROSE MARY
• Application Number:
  US13/623,503
• Publication Number:
  US 20130260469A1
• Time in Patent Office: 1,286 Days
• Field of Search: 73/18.2, 73/18.6, 736/17, 736/44, 736/09
• US Class Current: 1/1
• CPC Class Codes: G01N 2203/0092 Visco-elasticity, solidification, curing, cross-linking degree, vulcanisation or strength properties of semi-solid materials
• CPC Class Codes: G01N 2291/0251 Solidification, icing, curing composites, polymerisation
• CPC Class Codes: G01N 29/028 by measuring mechanical or acoustic impedance
• CPC Class Codes: G01N 29/09 by measuring mechanical or acoustic impedance
• CPC Class Codes: G01N 29/11 by measuring attenuation of acoustic waves
• CPC Class Codes: G01N 29/2462 Probes with waveguides, e.g. SAW devices
• CPC Class Codes: G01N 29/4427 with stored values, e.g. threshold values

Abstract

The present invention is seen to provide a new methodology, testing system designs and concept to enable in situ real time monitoring of the cure process. Apparatus, system, and method for the non-destructive, in situ monitoring of the time dependent curing of advanced materials using one or more differential ultrasonic waveguide cure monitoring probes. A differential ultrasonic waveguide cure monitoring probe in direct contact with the material to be cured and providing in situ monitoring of the cure process to enable assessment of the degree of cure or cure level in a non-cure related signal variances (e.g., temperature) independent calibrated response manner. A differential ultrasonic waveguide cure monitoring probe including a transducer coupled to a waveguide and incorporating correction and calibration methodology to accurately and reproducibly monitor the cure process and enable assessment of cure level via ultrasonic reflection measurements. The amplitude of the corrected interface response signal reflected from the probe-resin interface indicating changes in the modulus of the material during the cure.

Claims

1. A differential ultrasonic waveguide cure monitoring probe for in situ ultrasonic monitoring of a material undergoing a cure process, the probe comprising:

an ultrasonic transducer for generating, transmitting and receiving ultrasonic waves;

a waveguide for guiding the ultrasonic waves and having a proximal end in contact with the ultrasonic transducer and a distal end for contacting the material undergoing the cure process, the waveguide comprising;

a first portion extending from the proximal end;

a reference segment of the waveguide for reflecting a portion of the ultrasonic wave back to the ultrasonic transducer as a reference ultrasonic wave signal for use to recalibrate the probe and account for non-cure related ultrasonic wave variances during the cure process;

a second portion extending from the reference to a tip at the distal end of the waveguide;

wherein the tip further comprises a lip located on the circumference of the tip; and

wherein the lip extends intermittently about the circumference of the tip;

a waveguide for guiding the ultrasonic waves whose proximal end in contact with the ultrasonic transducer is easily separated from the ultrasonic transducer.

2. The differential ultrasonic waveguide cure monitoring probe of claim 1, wherein the lip comprises a plurality of lip segments separated by a plurality of gaps.

3. The differential ultrasonic waveguide cure monitoring probe of claim 2, wherein each lip segment occupies about 80°

of the circumference and each gap occupies about 40°

of the circumference.

4. The differential ultrasonic waveguide cure monitoring probe of claim 2, wherein the lip has a triangular cross-section.

5. The differential ultrasonic waveguide cure monitoring probe of claim 2, wherein the tip has one or more surface treatment selected from cleaning, etching, coating, solvent swipe, and controlled micro-roughness.

6. The differential ultrasonic waveguide cure monitoring probe of claim 1, wherein the waveguide defines a non-linear shape.

7. The differential ultrasonic waveguide cure monitoring probe of claim 6, wherein the non-linear waveguide has a curved body or an angled body.

8. An in situ single cure sensor or multi sensor calibration method for monitoring the cure of a material comprising:

comparatively calibrating each of one or more probe assemblies of claim 1 by concurrently measuring ultrasonic wave reflections response signal from a material having a known impedance;

coupling a calibrated differential ultrasonic waveguide cure monitoring probe to a material to be cured, the differential ultrasonic waveguide cure monitoring probe now comprising of paired or matched ultrasonic transducer and a waveguide extending from the ultrasonic transducer;

positioning the probe with a tip and front face of the waveguide in direct contact with the material to be cured;

directing a pulse of ultrasound energy through the waveguide toward the material being cured, wherein a portion of the ultrasound energy is reflected back from the reference segment of the waveguide, and a portion of the ultrasound energy is reflected back from a materials boundary interface between the probe and the material being cured;

sensing the ultrasound energy reflected from the materials boundary interface between the probe and the material being cured;

sensing the ultrasound energy reflected from the reference segment in the waveguide;

correcting the sensed ultrasound energy reflected from the materials boundary interface using the sensed ultrasound energy reflected from the reference segment;

additionally, correcting the overall paired probe response by comparative calibration normalization of the probe response signals from a material having a known impedance; and

determining via real time measurement the modulus of the material being cured at a particular point in the curing process using the calibrated and corrected values of the sensed ultrasound energy reflected from the materials boundary interface and from the reference.

9. The method of claim 8, wherein the step of sensing the ultrasound energy reflected from the materials boundary interface further comprises:

analyzing the amplitude of the reflected ultrasound energy from the materials boundary interface and the reference segment;

periodically analyzing the amplitude of the waveform of the reflected ultrasound energy from the materials boundary interface to determine whether the modulus of the composite has reached a predetermined modulus; and

terminating the cure process once the predetermined modulus is reached.

10. The method of claim 8, wherein the step of correcting the measurement further comprises continuous in situ and localized temperature effects compensation of the ultrasound energy reflected from the materials boundary interface, using the ultrasound energy reflected from the reference segment, to ensure accurate and reproducible sensing of the cure state of the material during the cure process.

11. The method of claim 8, wherein the step of correcting the measurement, further comprises continuous in situ non-cure related test probe signal variances via recalibration of the ultrasound energy reflected from the materials boundary interface, using the ultrasound energy reflected from the reference segment, to ensure accurate and reproducible sensing of the level of the cure in the material during the cure process.

12. The method of claim 8, wherein a series of pulses of ultrasound energy, and corresponding reflected reference signals and reflected interface signals, are generated and sensed over a period of time at predetermined time intervals.

13. The method of claim 8 where the differential ultrasonic waveguide cure monitoring probe comprises an ultrasonic transducer comprising, at a proximal end, a remote laser ultrasonic source and receiver coupled to a proximal end of a waveguide via mirrors, fiber optics bundles, light pipes or combination of optical components replacing the ultrasonic transducer.

14. A system for monitoring the progress of a curing process for a material to be cured, the system comprising:

a multiplexing computer; and

two or more differential ultrasonic waveguide cure monitoring probes of claim 1;

wherein said multiplexing computer is adapted for multiple channel support of the two or more differential ultrasonic waveguide cure monitoring probes.

15. The system of claim 14, wherein each differential ultrasonic waveguide cure monitoring probe of claim 1 comprises a plurality of differential ultrasonic waveguide cure monitoring probes for monitoring local cure state of the material.

16. The system of claim 15, wherein each differential ultrasonic waveguide cure monitoring probe may function independently or identically with respect to one another.

17. The system of claim 14 further comprising a computer network to facilitate sharing of data and/or process control inclusive of networking and modern computer communication features.

18. A calibrated and reproducible method for detecting material cure comprising:

performing an initial signal calibration of a probe, comprising an ultrasonic transducer and a waveguide, by measuring waveguide distal end ultrasonic wave reflection in air or from controlled impedance liquid at pre-determined temperature, for a specific probe with particular distal end cure tip geometrical features;

coupling the probe waveguide distal end to the material to be cured;

generating an ultrasonic stress wave in a waveguide using the ultrasonic transducer;

generating a response signal by reflecting a portion of the generated ultrasonic stress wave from a reference structure in the waveguide back to the ultrasonic transducer;

generating a distal end cure tip interface response signal by reflecting a portion of the generated ultrasonic stress wave from distal end interface of the waveguide and the cure material back to the ultrasonic transducer;

performing non-cure related signal variances correction/compensation of the sensed distal end interface signal using the sensed reference and calibration signals thus establishing R_RRC (Relative Reflection Coefficient value) as universal reference value;

setting numeric value of initial start up cure level to “

1”

by dividing the measured signal level by calibration signal level; and

comparing the corrected signal to a known response curve for the material to be cured to determine a quantitative degree of cure of the materials.

19. The method of the claim 18 where waveguide cure tip at distal end for contacting the material undergoing the cure process is set at critical reflection angle for a predetermined modulus value in contact with the material undergoing the cure to create a switching signal.

20. The method of the claim 18 where the waveguide cure tip at distal end for contacting the material undergoing the cure process comprises a set of multi angle facets at critical reflection angles for a predetermined modulus value in contact with the material undergoing the cure to create a switching signal.