Damage-resistant glass articles and method

• US 9,302,937 B2
• Filed: 04/11/2011
• Issued: 04/05/2016
• Est. Priority Date: 05/14/2010
• Status: Active Grant

• Current Assignee: Corning Incorporated
• Original Assignee: Corning Incorporated
• Inventors: Gulati, Suresh Thakordas, Suman, Balram
• Primary Examiner(s): Khan, Tahseen N
• Application Number:
  US13/083,847
• Publication Number:
  US 20110281093A1
• Time in Patent Office: 1,821 Days
• Field of Search: 428/213, 428/218
• US Class Current: 1/1
• CPC Class Codes: B32B 17/06 comprising glass as the main or only constituent of a layer, next to another layer of a specific material
• CPC Class Codes: B32B 2307/54 Yield strength; Tensile strength
• CPC Class Codes: B32B 2307/558 Impact strength, toughness
• CPC Class Codes: B32B 2315/08 Glass
• CPC Class Codes: B32B 2457/208 Touch screens
• CPC Class Codes: B32B 37/0015 to avoid warp or curl
• CPC Class Codes: B32B 37/08 characterised by the cooling method
• CPC Class Codes: B32B 37/144 using layers with different mechanical or chemical conditions or properties, e.g. layers with different thermal shrinkage, layers under tension during bonding constructional features for tensioning B32B38/1825
• CPC Class Codes: C03B 23/203 Uniting glass sheets C03B23/24 takes precedence
• CPC Class Codes: C03B 27/00 Tempering or quenching glass products
• CPC Class Codes: C03B 27/0413 Stresses, e.g. patterns, values or formulae for flat or bent glass sheets
• CPC Class Codes: C03B 27/065 Stresses, e.g. patterns, values or formulae
• CPC Class Codes: C03C 21/00 Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
• CPC Class Codes: C03C 23/007 by thermal treatment
• CPC Class Codes: Y10T 156/10 Methods of surface bonding and/or assembly therefor
• CPC Class Codes: Y10T 428/2495 Thickness [relative or absolute]
• CPC Class Codes: Y10T 428/24992 Density or compression of components

Abstract

A strengthened glass article has opposing first and second compressively stressed surface portions bound to a tensilely stressed core portion, with the first surface portion having a higher level of compressive surface stress than the second surface portion for improved resistance to surface damage, the compressively stressed surface portions being provided by lamination, ion-exchange, thermal tempering, or combinations thereof to control the stress profiles and limit the fracture energies of the articles.

Claims

1. A glass article having opposing first and second compressively stressed surface portions bound to a tensilely stressed core portion, the opposing first and second compressively stressed surface portions comprising first and second glass skin layers laminated to the tensilely stressed core portion to form a laminated article, the glass article having a stress profile resulting from subjecting the laminated article to an ion-exchange treatment,

wherein the first surface portion has a higher level of surface compression than the second surface portion,

wherein the opposing first and second compressively stressed surface portions are of differing composition and thickness, and

wherein the glass article has a bending moment M as defined by the expression M=(1+ρ

)(D₁+D₂+D₃)/ρ

of substantially zero, wherein D₁, D₂ and D₃ correspond, respectively, to bending rigidities of the first glass skin layer, the tensilely stressed core portion, and the second glass skin layer, and ρ

represents a common radius of curvature of the glass article.

2. A glass article according to claim 1 wherein the surface compression in at least the first surface portion is developed at least partially through the ion-exchange treatment of the first surface portion.

3. A glass article according to claim 1 wherein the opposing first and second glass skin layers are of different expansivity α

′

.

4. A glass article according to claim 1 having the form of a glass sheet, and wherein the tensilely stressed core portion has a tensile stress level not exceeding 20 MPa.

5. A glass article according to claim 4 wherein the level of surface compression in the second compressively stressed surface portion is at least 300 MPa.

6. A glass article comprising:

opposing first and second glass skin layers laminated to a glass core layer, each of the first and second glass skin layers comprising a lower thermal expansion than the glass core layer, and at least a portion of a stress profile of the glass article comprising an error function profile; and

a bending moment M as defined by the expression M=(1+ρ

)(D₁+D₂+D₃)/ρ

of substantially zero, wherein D₁, D₂ and D₃ correspond, respectively, to bending rigidities of the first glass skin layer, the glass core layer, and the second glass skin layer, and wherein p represents a common radius of curvature of the glass article.

7. A glass article according to claim 6, wherein the error function profile results from subjecting at least one of the first glass skin layer or the second glass skin layer to an ion-exchange treatment.

8. A glass article according to claim 6, wherein the stress profile comprises an asymmetric stress profile resulting from a combination of an ion-exchange treatment and at least one of (a) different thicknesses of the opposing first and second glass skin layers or (b) different thermal expansions of the opposing first and second glass skin layers.

9. A glass article according to claim 6 wherein the first glass skin layer comprises a different glass composition than the second glass skin layer.

10. A glass article according to claim 6 wherein each of the first glass skin layer and the second glass skin layer comprises a surface compression of at least 300 MPa.

11. A glass article according to claim 10 having the form of a glass sheet, wherein the glass core layer comprises a tensile stress level not exceeding 20 MPa.

12. A glass article comprising;

opposing first and second compressively stressed surface portions bound to a tensilely stressed core portion, the opposing first and second compressively stressed surface portions comprising first and second glass skin layers laminated to the tensilely stressed core portion to form a laminated article;

a stress profile resulting from subjecting the laminated article to an ion-exchange treatment; and

a bending moment M as defined by the expression M=(1+ρ

)(D₁+D₂+D₃)/ρ

of substantially zero, wherein D₁, D₂ and D₃ correspond, respectively, to bending rigidities of the first glass skin layer, the tensilely stressed core portion, and the second glass skin layer, and wherein ρ

represents a common radius of curvature of the glass article.

13. The glass article according to claim 12, wherein each of the first and second glass skin layers comprises a lower thermal expansion than the tensilely stressed core portion.

14. A glass article according to claim 12 wherein the first glass skin layer comprises a different glass composition than the second glass skin layer.

15. The glass article according to claim 12, wherein at least a portion of the stress profile of the glass article comprises an error function profile resulting from subjecting the laminated article to the ion-exchange treatment.

16. A glass article according to claim 15, wherein the stress profile comprises an asymmetric stress profile resulting from at least one of (a) subjecting the laminated article to the ion-exchange treatment, (b) different thicknesses of the first and second glass skin layers, or (c) different thermal expansions of the first and second glass skin layers.