Cavity enhanced laser based gas analyzer systems and methods

• US 9,304,080 B2
• Filed: 10/21/2014
• Issued: 04/05/2016
• Est. Priority Date: 11/02/2012
• Status: Active Grant

• Current Assignee: Li & S Company Limited (Yesco Holdings Co., Ltd.)
• Original Assignee: Li & S Company Limited (Yesco Holdings Co., Ltd.)
• Inventors: Kachanov, Alexander, Koulikov, Serguei
• Primary Examiner(s): PHAM, HOA Q
• Application Number:
  US14/520,203
• Publication Number:
  US 20150138558A1
• Time in Patent Office: 532 Days
• Field of Search: 356432-440, 356/409, 250/573, 250/576
• US Class Current: 1/1
• CPC Class Codes: G01N 21/17 Systems in which incident light is modified in accordance with the properties of the material investigated where the material investigated is optically excited causing a change in wavelength of the incident light G01N21/63
• CPC Class Codes: G01N 21/39 using tunable lasers
• CPC Class Codes: G01N 2201/06113 Coherent sources; lasers
• CPC Class Codes: G01N 33/0062 concerning the measuring method, e.g. intermittent, or the display, e.g. digital
• CPC Class Codes: H01S 5/0028 Laser diodes used as detectors
• CPC Class Codes: H01S 5/0085 for modulating the output, i.e. the laser beam is modulated outside the laser cavity
• CPC Class Codes: H01S 5/0656 Seeding, i.e. an additional light input is provided for controlling the laser modes, for example by back-reflecting light from an external optical component H01S5/14, H01S5/4062 and H01S5/4006 take precedence

Abstract

Cavity enhanced absorption spectroscopy systems and methods for detecting trace gases using a resonance optical cavity, which contains a gas mixture to be analyzed, and a laser coupled to the cavity by optical feedback. The cavity has any of a variety of configurations with two or more mirrors, including for example a linear cavity, a v-shaped cavity and a ring optical cavity. The cavity will have multiple cavity resonant modes, or a comb of frequencies spaced apart, as determined by the parameters of the cavity, including the length of the cavity, as is well known. Systems and methods herein also allow for optimization of the cavity modes excited during a scan and/or the repetition rate.

Claims

1. A method of measuring cavity loss of a resonant optical cavity over a range of frequencies by exciting one or a plurality of cavity modes of the cavity in a controlled manner, the cavity having at least two cavity mirrors, one of which is a cavity coupling mirror, using a laser that emits continuous wave laser light, wherein the laser is responsive to optical feedback light emerging from the cavity, and wherein a mean optical frequency of the laser is adjustable over a range of frequencies, the method comprising:

coupling the laser light to the cavity via the cavity coupling mirror using mode matching optics, the cavity having a plurality of optical resonance cavity modes that have frequencies within said range of frequencies of the laser;

applying to the laser a drive current comprising a series of current pulses, each having a predetermined current profile, so as to adjust the mean optical frequency of the laser and to excite desired cavity modes in an order during an excitation cycle as determined based on the shape of the applied current pulses; and

detecting dynamics of the intra cavity optical power of light circulating in the cavity after a cavity mode has been excited, including measuring a free decay rate cavity ring down event and measuring a direct absorption event during said excitation cycle,

wherein an end portion of one current pulse sets the laser drive current below a laser threshold value,

wherein the current profile of the next current pulse applied to the laser includes a compensation pulse portion that drives the laser at a current level and for a duration sufficient to compensate for some or all of the laser heat lost while the laser drive current was below the laser threshold value and to excite the next mode in said order.

2. The method of claim 1, wherein said order is a non-sequential order.

3. The method of claim 1, wherein said order is a sequential order with at least one mode skipped.

4. The method of claim 3, wherein detecting dynamics includes measuring a free decay rate cavity ring down event and measuring a direct absorption event for a single excited cavity mode.

5. The method of claim 3, wherein the cavity has a configuration selected from the group consisting of a ring cavity having three or more cavity mirrors and a linear cavity having two or more cavity mirrors.

6. The method of claim 1, further comprising determining a concentration of a gas in the cavity responsive to detecting dynamics of the intra cavity optical power.

7. The method of claim 1, wherein said current level is at or near a maximum laser driving current.

8. A system for measuring cavity loss of a resonant optical cavity over a range of frequencies by exciting one or a plurality of cavity modes of the cavity, the system comprising:

a resonant optical cavity having at least two cavity mirrors, one of which is a cavity coupling mirror, the cavity having a plurality of optical resonance cavity modes;

a laser that emits continuous wave laser light, wherein the laser is capable of being scanned whereby a mean optical frequency of the laser is adjustable over a range of frequencies, and wherein the laser is responsive to optical feedback light emerging from the cavity, and wherein the modes of the cavity have frequencies within said range of frequencies of the laser;

mode matching optics configured to couple the laser light to the cavity via the cavity coupling mirror;

a control module coupled with the laser and adapted to apply a drive current comprising a series of current pulses, each pulse having a predetermined current profile, to the laser so as to adjust the mean optical frequency of the laser and to excite desired cavity modes in an excitation order during an excitation cycle as determined based on the shape of the applied current pulses; and

a first detector configured to measure dynamics of the intra cavity optical power of light circulating in the cavity after a cavity mode has been excited, including measuring a free decay rate cavity ring down event and measuring a direct absorption event during said excitation cycle,

wherein an end portion of one current pulse sets the laser drive current below a laser threshold value, and

wherein the current profile of the next current pulse applied to the laser includes a compensation pulse portion that drives the laser at a current level and for a duration sufficient to compensate for some or all of the laser heat lost while the laser current was below the laser threshold value and to excite the next mode in said excitation order.

9. The system of claim 8, wherein said order is a non-sequential order.

10. The system of claim 8, wherein said order is a sequential order with at least one mode skipped.

11. The system of claim 8, wherein the first detector is configured to measure a free decay rate cavity ring down event and a direct absorption event for a single excited cavity mode.

12. The system of claim 8, wherein the cavity has a configuration selected from the group consisting of a ring cavity having three or more cavity mirrors and a linear cavity having two or more cavity mirrors.

13. The system of claim 8, further including a processor adapted to determine a concentration of a gas in the cavity responsive to a signal received from the first detector.

14. The method of claim 8, wherein said current level is at or near a maximum laser driving current.

15. A gas analyzer for detecting one or more analyte species present in a gaseous or liquid medium, the gas analyzer comprising:

a resonant optical cavity having at least two cavity mirrors, one of which is a cavity coupling mirror, the cavity having a plurality of optical resonance cavity modes;

a laser that emits continuous wave laser light, wherein the laser is capable of being scanned whereby a mean optical frequency of the laser is adjustable over a range of frequencies, and wherein the laser is responsive to optical feedback light emerging from the cavity, and wherein the modes of the cavity have frequencies within said range of frequencies of the laser;

mode matching optics configured to couple the laser light to the cavity via the cavity coupling mirror;

a control module coupled with the laser and adapted to apply a drive current comprising a series of current pulses, each pulse having a predetermined current profile, to the laser so as to adjust the mean optical frequency of the laser and to excite desired cavity modes in an excitation order during an excitation cycle as determined based on the shape of the applied current pulses;

a first detector configured to measure dynamics of the intra cavity optical power of light circulating in the cavity after a cavity mode has been excited, including measuring a free decay rate cavity ring down event and measuring a direct absorption event during said excitation cycle,

wherein an end portion of one current pulse sets the laser drive current below a laser threshold value,

wherein the current profile of the next current pulse applied to the laser includes a compensation pulse portion that drives the laser at a current level and for a duration sufficient to compensate for some or all of the laser heat lost while the laser current was below the laser threshold value and to excite the next mode in said excitation order; and

a processor adapted to determine a concentration of an analyte species in the cavity responsive to a signal received from the first detector.

16. The gas analyzer of claim 15, wherein the first detector is configured to measure a free decay rate cavity ring down event and a direct absorption event for a single excited cavity mode.