Hollow fiber membrane with compatible reinforcements

• US 9,321,014 B2
• Filed: 12/16/2011
• Issued: 04/26/2016
• Est. Priority Date: 12/16/2011
• Status: Active Grant

• Current Assignee: BL Technologies Inc. (Ashland Global Holdings, Inc.)
• Original Assignee: BL Technologies Inc. (Ashland Global Holdings, Inc.)
• Inventors: Pedersen, Steven Kristian, Cote, Pierre Lucien, Bai, Jinhua
• Primary Examiner(s): FORTUNA, ANA M
• Application Number:
  US13/328,761
• Publication Number:
  US 20130153490A1
• Time in Patent Office: 1,593 Days
• Field of Search: 210/500.23, 210/500.41, 210/500.36, 264/178.R, 264/177.14, 264/171.26, 442/60, 442/269, 442/366, 118/75, 428/364
• US Class Current: 1/1
• CPC Class Codes: B01D 2323/42 Details of membrane preparation apparatus
• CPC Class Codes: B01D 2325/40 Fibre reinforced membranes
• CPC Class Codes: B01D 69/08 Hollow fibre membranes manufacture of hollow fibres D01D5/24, D01F1/08
• CPC Class Codes: B01D 69/085 Details relating to the spinneret
• CPC Class Codes: B01D 71/34 Polyvinylidene fluoride
• CPC Class Codes: B29C 48/05 Filamentary, e.g. strands
• CPC Class Codes: B29C 48/08 flexible, e.g. films
• CPC Class Codes: B29C 48/11 comprising two or more partially or fully enclosed cavities, e.g. honeycomb-shaped
• CPC Class Codes: B29C 48/919 using a bath, e.g. extruding into an open bath to coagulate or cool the material

Abstract

A process of making a reinforced hollow fiber membrane comprises flowing a membrane dope through a casting head while drawing one or more yarns or tows of filaments through the casting head. The filaments are spread apart in the casting head, for example by forcing the yarns or tows around a bend or through a narrow gap in the casting head. The filaments are adapted to bond to the membrane dope or the membrane wall. A reinforced hollow fiber membrane comprises a plurality of filaments individually surrounded by, and bonded to, the membrane wall.

Claims

1. A hollow fiber membrane comprising:

a) a membrane wall formed from a membrane dope; and

b) one or more yarns or tows of filaments embedded in the membrane wall;

wherein the filaments are made, at least in part, of a polymer that is adapted to bond to the membrane dope or the membrane wall; and

wherein the one or more yarns or tows of filaments embedded in the membrane wall have a cross-sectional shape perpendicular to the length of the membrane that is larger when measured perpendicular to a radius of the membrane that when measured parallel to the radius of the membrane, and

wherein a cylindrical bundle of the filaments has a diameter that is greater than the thickness of the membrane wall.

2. The membrane of claim 1 wherein the polymer is provided in a sheath around a core of the filament, and the core is made of a different polymer.

3. The membrane of claim 1 wherein the polymer is soluble in a solvent used in the membrane dope.

4. The membrane of claim 1 wherein the polymer is a polymer that is also present in the membrane dope.

5. The membrane of claim 1 wherein the polymer is PVDF.

6. The membrane of claim 5 wherein the filaments have a core of PET or co-PET.

7. The membrane of claim 1 wherein the polymer is PES.

8. The membrane of claim 1 wherein the polymer has a melt temperature below the temperature of a TIPS dope used to form the membrane wall.

9. The membrane of claim 1 wherein the polymer has a surface treated to promote bonding.

10. The membrane of claim 1 wherein the membrane wall surrounds and is bonded to the filaments.

11. The membrane of claim 1 wherein at least most of the filaments extend continuously from one end to the other of a segment of the membrane that is at least 1 meter long and the filaments are generally parallel to each other.

12. A process of making a reinforced hollow fiber membrane comprising the steps of,

a) flowing a membrane dope through a casting head;

b) drawing one or more yarns or tows of filaments through the casting head, the filaments initially forming a generally cylindrical bundle before they enter the casting head; and

,

c) forcing the one or more yarns or tows filaments around at least one bend in the casting head, or through at least one gap in the casting head that is narrower than the initial cylindrical bundle of the filaments, such that the one or more yarns or tows are flattened relative to the initial generally cylindrical bundle.

13. The process of claim 12 wherein the filaments comprise a core of a first polymer and a sheath of a second polymer.

14. The process of claim 13 comprising a step of heat setting the filaments before step b).

15. The process of claim 13 wherein the second polymer is a polymer also provided in the dope.

16. The process of claim 15 wherein the first polymer comprises PET.

17. The process of claim 12 wherein step a) comprises providing dope in a first zone of the casting head in which a tow travels in a trough upstream of a die, and providing dope in a second zone in communication with the die.

18. The process of claim 12 further comprising a step of providing a bore fluid to a lumen of the membrane.

19. A reinforced hollow fiber membrane comprising a membrane wall and one or more tows cast into the membrane wall, each tow comprising a plurality of generally parallel continuous filaments, wherein the filaments of the tow are spread apart such that the membrane wall extends between at least most pairs of adjacent filaments within the tow, and wherein the filaments comprise a Polymer present in the membrane wall.