Method for degumming triglyceride oils

• US 9,340,749 B1
• Filed: 05/06/2015
• Issued: 05/17/2016
• Est. Priority Date: 05/06/2015
• Status: Active Grant

• Current Assignee: Archer Daniels Midland Company
• Original Assignee: Arisdyne Systems Incorporated
• Inventors: Kozyuk, Oleg, Reimers, Peter, Reinking, Paul A.
• Primary Examiner(s): Carr, Deborah D
• Application Number:
  US14/705,221
• Time in Patent Office: 377 Days
• Field of Search: 554/190
• US Class Current: 1/1
• CPC Class Codes: C11B 3/04 with acids
• CPC Class Codes: C11B 3/06 with bases
• CPC Class Codes: C11B 3/16 by mechanical means

Abstract

A multi-stage homogenization method for degumming triglyceride oil is used to increase oil yield and reduce impurities. Two high-pressure homogenizers are used in series. The homogenizers have multiple flow constrictions to finely disperse reagents in the oil while simultaneously suppressing cavitation in the fluid. A separation step can be used to remove the phosphatides and other impurities from the treated oil to form a purified oil product.

Claims

1. A method for degumming a triglyceride oil comprising:

a. mixing an aqueous base solution with an acid-treated oil to form a pre-treated oil mixture comprising an oil phase and a water phase;

b. passing the pre-treated oil mixture at a pre-determined inlet pressure through a first homogenization apparatus and a second homogenization apparatus to form a treated oil mixture, the first homogenization apparatus and the second homogenization apparatus positioned in series with one another and the first homogenization apparatus and the second homogenization apparatus each having at least three flow constrictions in series, wherein the pressure drop in the pre-treated oil mixture across each flow constriction in the first homogenization apparatus and the second homogenization apparatus is in the range of 25 to 50% of the upstream pressure of the pre-treated oil mixture before each flow constriction such that hydrodynamic cavitation in the pre-treated oil mixture is suppressed in the first homogenization apparatus and the second homogenization apparatus;

c. separating the water phase from the oil phase to form a purified oil.

2. The method of claim 1, further comprising mixing a triglyceride oil with an aqueous acid solution to form the acid-treated oil.

3. The method of claim 2, further comprising mixing the triglyceride oil with the aqueous acid solution in a tank prior to mixing the aqueous base solution with the acid-treated oil.

4. The method of claim 1, the pre-determined inlet pressure of the pre-treated oil mixture to the first homogenization apparatus being in the range of 800 to 2,000 psi.

5. The method of claim 4, the pressure drop in the pre-treated oil mixture across the first homogenization apparatus being in the range of 60 to 80% of the pre-determined inlet pressure.

6. The method of claim 4, the pressure drop in the pre-treated oil mixture across each flow constriction in the first homogenization apparatus being at least 100 psi.

7. The method of claim 1, the pre-treated oil mixture enters the second homogenization apparatus at a second inlet pressure, the pressure drop in the pre-treated oil mixture across the second homogenization apparatus being in the range of 60 to 80% of the second inlet pressure.

8. The method of claim 1, the treated oil mixture exiting the second homogenization apparatus at a pressure less than 10% of the pre-determined inlet pressure.

9. The method of claim 1, the pre-treated oil mixture in the first homogenization apparatus and the second homogenization apparatus having a cavitation number greater than 2 when calculated using the equation C_v=(P−

P_v)/0.5ρ

V², where C_v is the cavitation number, P is the pre-treated oil mixture pressure downstream of a flow constriction, P_v is the vapor pressure of the water, ρ

is the density of the oil, and V is the velocity of the pre-treated oil mixture at a flow constriction.

10. The method of claim 9, the pre-treated oil mixture in the first homogenization apparatus and the second homogenization apparatus having a cavitation number in the range of greater than 2 and less than 5.

11. The method of claim 1, the flow constrictions in the first homogenization apparatus and the second homogenization apparatus being valves.

12. The method of claim 11, the valves having a knife edge.

13. The method of claim 1, the flow constrictions in the first homogenization apparatus or the second homogenization apparatus being positioned radially in series.

14. The method of claim 1, the flow constrictions in the first homogenization apparatus or the second homogenization apparatus being positioned axially in series.

15. The method of claim 1, the purified oil having a phosphorus content of less than 10 ppm.

16. The method of claim 1, the pre-treated oil mixture further comprising an enzyme.

17. The method of claim 1, the pre-treated oil mixture comprising crude vegetable oil or water-degummed vegetable oil.

18. The method of claim 17, the crude vegetable oil or water-degummed vegetable oil being selected from the group consisting of acai oil, almond oil, babassu oil, blackcurrent seed oil, borage seed oil, canola oil, cashew oil, castor oil, coconut oil, coriander oil, corn oil, cottonseed oil, crambe oil, flax seed oil, grape seed oil, hazelnut oil, hempseed oil, jatropha oil, jojoba oil, linseed oil, macadamia nut oil, mango kernel oil, meadowfoam oil, mustard oil, neat'"'"'s foot oil, olive oil, palm oil, palm kernel oil, palm olein, peanut oil, pecan oil, pine nut oil, pistachio oil, poppy seed oil, rapeseed oil, rice bran oil, safflower oil, sasanqua oil, sesame oil, shea butter, soybean oil, sunflower seed oil, tall oil, tsubaki oil walnut oil or a mixture thereof.

19. The method of claim 1, the acid-treated oil comprising an acid selected from the group consisting phosphoric acid, hydrochloric acid, sulfuric acid, ascorbic acid, acetic acid, citric acid, fumaric acid, maleic acid, tartaric acid, succinic acid, glycolic acid or a mixture thereof.

20. The method of claim 1, the aqueous base solution comprises a base selected from the group consisting of sodium hydroxide, potassium hydroxide, sodium silicate, sodium carbonate, calcium carbonate or a mixture thereof.