Corrosion resistant metallate compositions

• US 9,347,134 B2
• Filed: 06/04/2010
• Issued: 05/24/2016
• Est. Priority Date: 06/04/2010
• Status: Active Grant

• Current Assignee: PRC-DeSoto International, Inc. (Nouryon BV)
• Original Assignee: PRC-DeSoto International, Inc. (Nouryon BV)
• Inventors: Morris, Eric L.
• Primary Examiner(s): ZHENG, LOIS L
• Application Number:
  US12/794,527
• Publication Number:
  US 20110300390A1
• Time in Patent Office: 2,181 Days
• Field of Search: 148/247
• US Class Current: 1/1
• CPC Class Codes: C23C 22/34 containing fluorides or complex fluorides
• CPC Class Codes: C23C 22/68 using aqueous solutions with pH between 6 and 8
• CPC Class Codes: C23C 22/83 Chemical after-treatment

Abstract

A composition for application to a metal substrate comprising at least one metallate compound comprising hexafluorzirconate, zirconyl nitrate, and/or yttrium nitrate is provided. The composition may further comprise additives that promote corrosion resistance of the metal substrate, or the adhesion of subsequent coatings, such as one or more rare earth element salts; allontoin, polyvinylpyrrolidone, surfactants, and other additives and co-inhibitors. A metal substrate such as an aluminum or an aluminum alloy substrate coated with a metallate composition according to the present invention is also provided. A process for preparing a coating on a metal substrate to improve the corrosion resistance of the substrate or improve the adhesion of a subsequent coating is also provided. The process comprises treating the metal substrate with an aqueous solution comprising a metallate compound. The process may further comprise one or more pre-treating the substrate, coating the metal substrate with an oxidizing agent and/or coating the metal substrate with one or more rare earth element salts. A process for preparing the metallate coatings of the invention is also provided.

Claims

1. A composition for application to a metal substrate, the composition comprising:

an aqueous carrier;

hexafluorozirconate; and

yttrium nitrate, wherein the yttrium nitrate is present in a sufficient amount so that the composition is stabilized as a suspension with no precipitate, the amount of the yttrium nitrate in the composition is greater than an amount of the hexafluorozirconate in the composition, and the composition is substantially free of Group 5 through Group 12 metals.

2. The composition according to claim 1, further comprising sodium fluoride, wherein the sodium fluoride is provided to the composition in an aqueous solution.

3. The composition according to claim 1, further comprising a surfactant.

4. The composition according to claim 1, further comprising polyvinylpyrrolidone.

5. The composition according to claim 1, wherein the hexafluorozirconate is present in the composition in an amount from 0.004 to 10 g/l.

6. The composition according to claim 1, wherein the yttrium nitrate is present in the composition in an amount from 0.1 to 15 g/l.

7. The composition according to claim 6, wherein the yttrium nitrate is present in the composition in an amount of 1 g/l.

8. The composition according to claim 1, wherein the hexafluorozirconate comprises potassium hexafluorozirconate.

9. The composition for application to a metal substrate according to claim 1 wherein:

the hexafluorozirconate is present in an amount of from 0.004 wt % to 5 wt %; and

the yttrium nitrate is present in an amount of from 0.004 wt % to 5 wt %; and

the aqueous carrier comprises water.

10. The composition for application to a metal substrate according to claim 9, wherein the yttrium nitrate is present in the composition in an amount of from 0.1 wt % to 2 wt %.

11. The composition for application to a metal substrate according to claim 9, the composition further comprising:

sodium fluoride in an amount from 0.05 wt % to 0.3 wt %.

12. The composition of claim 1, wherein the weight ratio of yttrium nitrate to hexafluorozirconate is between 1.5:

1 and 7;

1.

14. A metal substrate comprising a deoxidized or degreased aluminum or aluminum alloy substrate coated with:

(i) a composition according to claim 1.

15. The metal substrate according to claim 14, further comprising:

(ii) a coating comprising a composition consisting essentially of yttrium nitrate and an aqueous carrier.

16. The metal substrate according to claim 14, further comprising a primer coat.

17. The metal substrate according to claim 14, further comprising a topcoat.

18. A process for coating a metal substrate, comprising:

coating the metal substrate with a first composition, the first composition comprising the composition according to claim 1.

19. The process according to claim 18, further comprising pre-treating the metal substrate prior to coating the metal substrate with the first composition.

20. The process according to claim 19, wherein the pre-treating comprises pre-cleaning the metal substrate prior to coating the metal substrate with the first composition to provide a pre-cleaned metal substrate.

21. The process according to claim 20, wherein the pre-treating further comprises deoxidizing the pre-cleaned substrate prior to coating the metal substrate with the first composition.

22. The process according to claim 18, further comprising prior to coating the metal substrate with the first composition, coating the metal substrate with a composition consisting essentially of yttrium nitrate, and an aqueous carrier.

13. A composition for application to a metal substrate, the composition consisting of:

an aqueous carrier;

hexafluorozirconate; and

yttrium nitrate, wherein the yttrium nitrate is present in a sufficient amount so that the composition is stabilized as a suspension, and the amount of the yttrium nitrate in the composition is greater than an amount of the hexafluorozirconate in the composition.