Shape memory sensor

• US 9,347,797 B2
• Filed: 12/24/2008
• Issued: 05/24/2016
• Est. Priority Date: 12/28/2007
• Status: Expired due to Fees

• Current Assignee: Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno
• Original Assignee: Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno
• Inventors: Boersma, Arjen
• Primary Examiner(s): Bedtelyon, John M
• Application Number:
  US12/810,412
• Publication Number:
  US 20110052116A1
• Time in Patent Office: 2,708 Days
• US Class Current: 1/1
• CPC Class Codes: G01D 5/02 using mechanical means
• CPC Class Codes: G01D 5/35303 using a reference fibre, e.g. interferometric devices
• CPC Class Codes: G01D 5/35316 using a Bragg gratings
• CPC Class Codes: G01K 5/483 using materials with a configuration memory, e.g. Ni-Ti alloys
• CPC Class Codes: G02B 6/02104 characterised by the coating external to the cladding, e.g. coating influences grating properties

Abstract

The invention relates to a sensor for measuring an environmental effect, comprising a sensor material having an internal stress, which sensor material is designed to at least partially relax under the influence of the environmental effect. The sensor further comprising a detection unit for indirectly or directly detecting said relaxation. The invention also relates to a waveguide, comprising a grating in at least a portion of the waveguide, which waveguide comprises a coating, the coating comprising a polymer that contains reversible crosslinks that can be broken by the environmental effect in such a way that the polymer changes shape. The invention further relates to a sensor system comprising a waveguide, a light source, and a photo-detector.

Claims

1. A sensor for measuring an environmental effect, comprising a waveguide having a core, the core having a grating in a segment of the core,

the waveguide further having a coating comprising a polymeric sensor material,

the polymeric sensor material having internal mechanical stress as a consequence of being in a deformed shape, which sensor material is configured to at least partially relax under the influence of the environmental effect by which relaxation the material changes shape from the deformed shape to a memory shape,

the sensor further comprising a detection unit for indirectly or directly detecting said relaxation,

wherein the grating is a fiber bragg grating.

2. A sensor according to claim 1, wherein the polymer comprises crosslinks, which crosslinks are adapted to be cleaved under the influence of the environmental effect.

3. A sensor according to claim 2, wherein the polymer comprises crosslinks selected from the group of amide group crosslinks, ester group crosslinks, complexed metal ion crosslinks, saccharide-based crosslinks, Diels-Alder-based crosslinks, diazidostilbene-based crosslinks and diperoxide-based crosslinks.

4. A sensor according to claim 1, wherein the detection unit is arranged to detect a change in the refractive index of the sensor material.

5. A sensor according to claim 1, wherein the detection system comprises a light source for sending light into the waveguide and a photo-detector for detecting light leaving the waveguide.

6. The sensor according to claim 1, wherein the coating has a thickness in the range of 0.1 to 200 μ

m.

7. The sensor according to claim 1, wherein the environmental effect is an analyte.

8. The sensor according to claim 7, wherein the analyte is selected from the group consisting of water, carbon monoxide, oxygen, carbon dioxide, hydrogen cyanide, ammonia, metal ions, metal-containing ions, biomolecules, DNA, RNA, a peptide, an enzyme, H⁺, and hydroxyl ions.

9. The waveguide according to claim 7, wherein the grating is present in the core regardless of the presence of the analyte.

10. The waveguide according to claim 1, wherein the grating is present in the core when the material is under internal mechanical stress and when the sensor material is at least partially relaxed.

11. A waveguide comprising a core, the core having a grating in a segment of the core, the waveguide further having a coating, the coating comprising a polymeric sensor material, the polymeric sensor material having internal stress as a consequence of being in a deformed shape, and wherein the polymeric sensor material is configured to at least partially relax under the influence of the environmental effect by which relaxation the material changes shape from the deformed shape to a memory shape, the sensor further comprising a detection unit for indirectly or directly detecting said relaxation, the waveguide comprising a fiber bragg grating.

12. The waveguide according to claim 11, wherein the coating has a thickness in the range of 0.1 to 200 urn.

13. The waveguide according to claim 11, wherein the environmental effect is an analyte.

14. The waveguide according to claim 13, wherein the analyte is selected from the group consisting of water, carbon monoxide, oxygen, carbon dioxide, hydrogen cyanide, ammonia, metal ions, metal-containing ions, biomolecules. DNA, RNA, a peptide, an enzyme, H⁺, and hydroxyl ions.

15. The waveguide according to claim 13, wherein the grating is present in the core regardless of the presence of the analyte.

16. The waveguide according to claim 11, wherein the polymer comprises crosslinks, which crosslinks are adapted to be cleaved under the influence of the environmental effect.

17. The waveguide according to claim 11, wherein the polymer comprises crosslinks selected from the group consisting of amide group crosslinks, ester group crosslinks, complexed metal ion crosslinks, saccharide-based crosslinks, Diels-Alder-based crosslinks, diazidostilbene-based crosslinks and diperoxide-based crosslinks.

18. The waveguide according to claim 11, wherein the grating is present in the core when the material is under internal mechanical stress and when the sensor material is at least partially relaxed.