Toner and method of producing toner

• US 9,348,247 B2
• Filed: 05/02/2013
• Issued: 05/24/2016
• Est. Priority Date: 05/10/2012
• Status: Active Grant

• Current Assignee: Canon Ayutthaya Limited (Canon Inc.)
• Original Assignee: Canon Ayutthaya Limited (Canon Inc.)
• Inventors: Ida, Hayato, Hirasa, Takashi, Natori, Ryo, Tamura, Junichi, Chimoto, Yuya, Shibata, Takaho
• Primary Examiner(s): LE, HOA VAN
• Application Number:
  US13/886,077
• Publication Number:
  US 20130302731A1
• Time in Patent Office: 1,118 Days
• Field of Search: 430/109.4
• US Class Current: 1/1
• CPC Class Codes: G03G 9/0804 whereby the components are brought together in a liquid dispersing medium
• CPC Class Codes: G03G 9/08755 Polyesters
• CPC Class Codes: G03G 9/08764 Polyureas; Polyurethanes
• CPC Class Codes: G03G 9/08795 characterised by their chemical properties, e.g. acidity, molecular weight, sensitivity to reactants
• CPC Class Codes: G03G 9/08797 characterised by their physical properties, e.g. viscosity, solubility, melting temperature, softening temperature, glass transition temperature

Abstract

An object of the present invention is to provide a toner that produces an excellent bending resistance in the output image and that also exhibits an excellent low-temperature fixability and an excellent storage stability. This toner includes a binder resin and a thermoplastic elastomer having a crystalline part, wherein the binder resin and the thermoplastic elastomer in the toner are compatible with each other and the toner has a crystalline part originating from the thermoplastic elastomer.

Claims

1. A toner comprising a binder resin and a thermoplastic elastomer, wherein,

the thermoplastic elastomer has a glass transition temperature (Tg) which does not exceed room temperature,

the thermoplastic elastomer comprises a portion which is compatible with the binder resin,

the toner comprises a crystalline part originating from the thermoplastic elastomer,

the binder resin has a glass transition temperature of at least 60°

C. and the softening point of the thermoplastic elastomer is less than or equal to the softening point of the binder resin, and

the thermoplastic elastomer is an ester-type urethane thermoplastic elastomer.

2. The toner according to claim 1, wherein the melting point of the thermoplastic elastomer is from at least 40°

C. to not more than 120°

C.

3. The toner according to claim 1, wherein the thermoplastic elastomer has an elongation at break of 100% to 2000%.

4. The toner according to claim 1, wherein the content of the thermoplastic elastomer is from at least 20 mass parts to less than 100 mass parts per 100 mass parts of the binder resin.

5. The toner according to according to claim 1, wherein the crystallinity of the thermoplastic elastomer in the toner is from at least 1% to not more than 50%.

6. The toner according to claim 1, wherein the toner is a toner produced via the steps of:

producing resin fine particles by dissolving the binder resin and the thermoplastic elastomer in an organic solvent and adding water to the resulting solution; and

aggregating the obtained resin fine particles in an aqueous medium.

7. The toner according to claim 6, wherein the organic solvent is an organic solvent that forms a homogeneous phase with water.

8. A method of producing the toner according to claim 1, comprising the steps of:

producing resin fine particles by dissolving the binder resin and the thermoplastic elastomer in an organic solvent and adding water to the resulting solution; and

aggregating the obtained resin fine particles in an aqueous medium.

9. The toner according to claim 1, wherein the content of the thermoplastic elastomer in the toner is from at least 30 mass parts to not more than 60 mass parts expressed per 100 mass parts of the binder resin.

10. The toner according to claim 1, wherein the ester-type urethane thermoplastic elastomer has the structure indicated by the following general formula (2):

(—

O—

R′

—

OCO—

NH—

R—

NHCO—

)_n 

 

(2)

wherein, in the formula (2), R denotes an aromatic hydrocarbon or aliphatic hydrocarbon, and R′

denotes a polyester.