Reactive surface coating having chemical decontamination and biocidal properties

• US 9,353,269 B2
• Filed: 03/15/2013
• Issued: 05/31/2016
• Est. Priority Date: 03/15/2013
• Status: Active Grant

• Current Assignee: Emerald Kalama Chemical, LLC (Lanxess AG), American Sterilizer Company (Steris Corporation)
• Original Assignee: American Sterilizer Company (Steris Corporation)
• Inventors: Kaiser, Herbert J., Shaver, Miranda C., Giddens, Timothy Lee
• Primary Examiner(s): Boyle, Robert C
• Application Number:
  US13/836,364
• Publication Number:
  US 20140287154A1
• Time in Patent Office: 1,173 Days
• Field of Search: None
• US Class Current: 1/1
• CPC Class Codes: A01N 25/10 Macromolecular compounds
• CPC Class Codes: A01N 25/34 Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
• CPC Class Codes: A01N 59/00 Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
• CPC Class Codes: A01N 59/06 Aluminium; Calcium; Magnesium; Compounds thereof
• CPC Class Codes: A62D 5/00 Composition of materials for coverings or clothing affording protection against harmful chemical agents
• CPC Class Codes: B05D 1/02 performed by spraying
• CPC Class Codes: B05D 1/28 performed by transfer from the surfaces of elements carrying the liquid or other fluent material, e.g. brushes, pads, rollers
• CPC Class Codes: B05D 3/007 After-treatment
• CPC Class Codes: C09D 139/06 Homopolymers or copolymers of N-vinyl-pyrrolidones
• CPC Class Codes: C09D 5/14 Paints containing biocides, e.g. fungicides, insecticides or pesticides C09D5/16 takes precedence

Abstract

Reactive compositions are provided, having biocidal and chemical decontamination/neutralization properties, comprising a hygroscopic polymer and an active, which are useful in a variety of commercial, healthcare and military applications and a wide variety of contaminants, including without limitation chemical and biological warfare agents. The reactive compositions are renewable or rechargeable after use by exposure to an additional application of the active and do not require removal, disposal or replacement of the originally applied composition. Methods for preparing and applying the reactive compositions are disclosed.

Claims

1. A renewable, reactive, film-forming coating for application to a surface of an object or article or incorporation into an article during manufacture, having biocidal, and neutralization properties against biological and chemical warfare agents, consisting of:

a. non-cross-linked, water soluble polyvinylpyrrolidone, dissolved in water to form a solution, wherein the polyvinylpyrrolidone has a molecular weight of 10K, 58K, 360K or 1300K and is present in an amount ranging from about 1 to about 10 wt. %, based on the total weight of the reactive coating; and

b. an active material consisting of magnesium peroxide, calcium peroxide, hydrogen peroxide, chlorine, peracetic acid, or iodine, wherein hydrogen peroxide, when used, is present in an amount ranging from about 10 to about 20 wt. % and the other active materials, when used, are present in an amount ranging from about 1 to about 20 wt. %, based on the total weight of the reactive film-forming coating,

wherein the biocidal, decontamination and neutralization properties of a film formed by the coating are achieved in less than 60 minutes,

wherein the biocidal, decontamination and neutralization properties of the film are maintained under organic load and dilution, and

wherein the properties of the film may be renewed or recharged, upon fouling, exhaustion or decay of the active material after prolonged exposure to biological or chemical contaminants, by exposing the film to an additional dose of the active material, without the need to remove, dispose of, and replace the film formed from the coating.

2. The renewable, reactive, film-forming coating as set forth in claim 1, wherein the active material is hydrogen peroxide, calcium peroxide or magnesium peroxide.

3. The renewable, reactive, film-forming coating of claim 2, wherein the active material is hydrogen peroxide.

4. The renewable, reactive, film-forming coating of claim 1, wherein the active material is calcium or magnesium peroxide, and wherein the polyvinylpyrrolidone has a molecular weight of 58K and is present in an amount of about 10 wt. %.

5. A renewable, reactive, film-forming coating, for application to a surface of an object or article or incorporation into an article during manufacture, having biocidal, decontamination and neutralization properties against biological and chemical warfare agents, consisting of:

a. non-cross-linked, water soluble polyvinylpyrrolidone, dissolved in water and methanol to form a solution, wherein the polyyvinylpyrrolidone has a molecular weight of 10K, 58K, 360K or 1300K, and is present in an amount of from about 1 to about 10 wt. %, based upon the total weight of the reactive coating; and

b. an active that is hydrogen peroxide, wherein the hydrogen peroxide is present in an amount of from about 10 to about 20 wt. %, based upon the total weight of the reactive coating,

wherein the biocidal, decontamination and neutralization properties of a film formed by the coating are achieved in less than 60 minutes,

wherein the biocidal, decontamination and neutralization properties of the film are maintained under organic load and dilution, and

wherein the properties of the film formed by the reactive film-forming coating may be renewed or recharged, upon fouling, exhaustion or decay of the active material after prolonged exposure to biological or chemical contaminants, by exposing the film to an additional dose of the active material, without the need to remove, dispose of, and replace the film formed from the coating.

6. The renewable, reactive, film-forming coating of claim 5, wherein the polyvinyl pyrrolidone has a molecular weight of 1300 K and wherein the hydrogen peroxide is present in an amount of about 10 wt. %.

7. A renewable, reactive, film-forming composition, for application to a surface of an object or article, consisting of a blend of low density polyethylene and polyvinylpyrrolidone,

wherein the polyvinylpyrrolidone has a molecular weight of 58K, 360K or 1300K,

wherein the ratio of the low density polyethylene to the polyvinylpyrrolidone ranges from 60:

40 to 80;

20, and

wherein the film formed by extruding the composition is rendered reactive to biological and chemical warfare agents by exposure to liquid or vaporized hydrogen peroxide.

8. A renewable, reactive, film-forming composition, for application to a surface of an object or article, consisting of a blend of low density polyethylene, polyvinylpyrrolidone, and polyethylene glycol,

wherein the polyvinylpyrrolidone has a molecular weight of 58K, 360K or 1300 K,

wherein the ratio of the low density polyethylene to the polyvinylpyrrolidone ranges from 60:

40 to 80;

20, and

wherein the film formed by extruding the composition is rendered reactive to biological and chemical warfare agents by exposure to liquid or vaporized hydrogen peroxide. The following claims will replace all prior versions of claims in this application.