Apparatus for measuring the electrical conductivity of a liquid medium

• US 9,354,193 B2
• Filed: 06/26/2012
• Issued: 05/31/2016
• Est. Priority Date: 07/20/2011
• Status: Active Grant

• Current Assignee: OPTEK-Danulat GmbH
• Original Assignee: OPTEK-Danulat GmbH
• Inventors: Pohl, Alfred, Platte, Daniel
• Primary Examiner(s): Assouad, Patrick
• Assistant Examiner(s): Curtis, Sean
• Application Number:
  US14/117,942
• Publication Number:
  US 20140152332A1
• Time in Patent Office: 1,435 Days
• Field of Search: 324/713, 324/722, 324/693, 324/694, 324/439
• US Class Current: 1/1
• CPC Class Codes: G01N 27/06 of a liquid involving electrolysis G01N27/26
• CPC Class Codes: G01N 27/07 Construction of measuring vessels; Electrodes therefor

Abstract

Device for measuring electrical conductivity of a liquid medium comprising constant voltage means, connected to a first electrode arrangement for injecting an alternating signal into the liquid medium, detection means, connected to a second electrode arrangement coupled via the liquid medium, for generating a measurement signal influenced by the electrical conductivity with a clock frequency (CLK) of the alternating signal, and evaluation means which from a current-proportional injection signal of the current injected by the first electrode arrangement into the liquid medium and from the measurement signal generate a conductivity signal of the liquid medium. The constant voltage means are made in an individual circuit branch which has commutator means for the first electrode arrangement and ohmic resistance means in a series connection, the current-proportional injection signal being tapped as a voltage drop over the resistance means.

Claims

1. A device for measuring an electrical conductivity of a liquid medium, comprising:

constant voltage means for injecting an alternating signal into the liquid medium, the constant voltage means electrically connected to a first electrode arrangement,

detection means for generating a measurement signal influenced by the electrical conductivity of the liquid medium, the measurement signal having a clock frequency of the alternating signal, wherein the detection means is electrically connected to a second electrode arrangement, which is physically separated from the first electrode arrangement and which is electrically coupled to the first electrode arrangement via the liquid medium, and

evaluation means for generating an output signal from (i) a current-proportional injection signal of current injected by the first electrode arrangement into the liquid medium and (ii) the measurement signal, said output signal provided for further electronic processing,

wherein the constant voltage means is located in a circuit branch having a first commutator for the first electrode arrangement and ohmic resistance means for providing a source of ohmic resistance, the first commutator and the ohmic resistance means connected in series with the constant voltage means, and

wherein the current-proportional injection signal is tapped as a voltage drop over a resistor of the ohmic resistance means.

2. The device as claimed in claim 1, wherein the device further comprises:

a first analog-digital converter unit for generating a digital current-proportional injection signal, wherein the first analog-digital converter unit is not integrated into the evaluation means and is assigned to the ohmic resistance means.

3. The device as claimed in claim 2, wherein the device further comprises:

a second analog-digital converter unit for generating a digital measurement signal, wherein the second analog-digital converter unit is not integrated into the evaluation means and is assigned to capacitance means which interacts with the second electrode arrangement.

4. The device as claimed in claim 2, wherein the first analog-digital converter unit generates a serial output signal that is transmitted to the evaluation means via a serial connecting line assigned to the first analog-digital converter unit.

5. The device as claimed in claim 2, wherein the first analog-digital converter unit has integrated filter means tuned to the clock frequency of the alternating signal and/or of a supply voltage signal.

6. The device as claimed in claim 2, wherein the device further comprises:

a common voltage supply unit assigned to the first analog-digital converter unit, wherein the common voltage supply unit serves as a supply voltage unit for the constant voltage means and/or the common voltage supply unit is integrated into the first analog-digital converter unit and/or the first analog-digital converter unit has a common reference voltage source for converter quantization.

7. The device as claimed in claim 1, wherein the constant voltage means includes an analog control unit and/or the constant voltage means is implemented without integrated digital circuit modules.

8. The device as claimed in claim 1, wherein the device further comprises:

temperature detection means for detecting a temperature of the liquid medium, the temperature detection means interacting with the evaluation means via a third analog-digital converter unit, wherein the temperature of the liquid medium influences the conductivity signal.

9. The device as claimed in claim 1, wherein the circuit branch is configured such that the ohmic resistance means is invariable, free of hysteresis and not able to be discretely switched over or selected, and/or there are no active and/or switching elements in the circuit branch which influence an ohmic resistance value of the ohmic resistance means.

10. The device as claimed in claim 3, wherein the detection means includes a capacitor having a capacitor voltage that determines the digital measurement signal which is generated continuously and/or independently of the clock frequency of the alternating signal.

11. The device as claimed in claim 1, wherein the measurement signal is present parallel and synchronously on a first and a second input of the detection means with signal levels which have been amplified to different degrees from one another.

12. The device as claimed in claim 2, wherein a repetition frequency and/or a cycle frequency of the generation of the digital current-proportional injection signal is set up to the clock frequency of the alternating signal in a ratio of less than 1:

100.

13. The device as claimed in claim 1, wherein the device further comprises:

decoupling means located between respective electrodes of the second electrode arrangement and a second commutator downstream of the respective electrodes of the second electrode arrangement.

15. A device as claimed in claim 1, wherein the liquid medium is an aqueous medium.

16. A device as claimed in claim 1, wherein the second electrode arrangement is an electrode pair.

17. A device as claimed in claim 1, wherein the detection means is coupled via the liquid medium in the manner of a four-pole configuration.

18. A device as claimed in claim 1, wherein the output signal is a conductivity signal of the liquid medium.

19. A device as claimed in claim 1, wherein the current-proportional injection signal is tapped as a voltage drop over a partial resistor of the ohmic resistance means.

20. The device as claimed in claim 3, wherein the second analog-digital converter unit generates a serial output signal for the evaluation means and interacts with the evaluation means via a serial connecting line, which is assigned individually to the second analog-digital converter unit.

21. The device as claimed in claim 3, wherein the second analog-digital converter unit has integrated filter means tuned to the clock frequency of the alternating signal and/or of a supply voltage signal.

22. The device as claimed in claim 3, wherein the device further comprises:

a common voltage supply unit assigned to the second analog-digital converter unit, wherein the common voltage supply unit serves as a supply voltage unit for the constant voltage means and/or the common voltage supply unit is integrated into the second analog-digital converter unit and/or the second analog-digital converter unit has a common reference voltage source for converter quantization.

23. The device as claimed in claim 1, wherein the device further comprises:

a second analog-digital converter unit for generating a digital measurement signals, wherein the second analog-digital converter unit is not integrated into the evaluation means and is assigned to capacitance means which interacts with the second electrode arrangement.

24. The device as claimed in claim 23, wherein the second analog-digital converter unit generates a serial output signal that is transmitted to the evaluation means via a serial connecting line assigned individually to each of the first and second analog-digital converter units.

25. The device as claimed in claim 23, wherein the second analog-digital converter unit has integrated filter means tuned to the clock frequency of the alternating signal and/or of a supply voltage signal.

26. The device as claimed in claim 23, wherein the device further comprises:

a common voltage supply unit assigned to the second analog-digital converter unit, wherein the common voltage supply unit serves as a supply voltage unit for the constant voltage means and/or the common voltage supply unit is integrated into the second analog-digital converter unit and/or the second analog-digital converter unit has a common reference voltage source for converter quantization.

27. The device as claimed in claim 9, wherein the ohmic resistance means has a constant ohmic resistance value.

28. The device as claimed in claim 12, wherein the ratio is less than 1:

500.

29. The device as claimed in claim 13, wherein the decoupling means is ohmic resistance means.

32. The device as claimed in claim 3, wherein a repetition frequency and/or a cycle frequency of the generation of the digital measurement signal is set up to the clock frequency of the alternating signal in a ratio of less than 1:

100.

14. A method for measuring an electrical conductivity of a liquid medium, comprising:

injecting an alternating signal into the liquid medium, wherein the alternating signal is injected by constant voltage means electrically connected to a first electrode arrangement,

generating a measurement signal influenced by the electrical conductivity of the liquid medium, wherein the measurement signal has a clock frequency of the alternating signal, the measurement signal generated by a detection means electrically connected to a second electrode arrangement, said detection means physically separated from the first electrode arrangement and electrically coupled to the first electrode arrangement via the liquid medium, and

generating a conductivity signal of the liquid medium, wherein the conductivity signal is generated by evaluation means from (i) a current-proportional injection signal of current infected by the first electrode arrangement into the liquid medium and (ii) the measurement signal, and

providing the conductivity signal for further electronic processing,

wherein the constant voltage means is located in a circuit branch having a commutator for the first electrode arrangement and ohmic resistance means in a series connection,

wherein the current-proportional injection signal is tapped as a voltage drop over the ohmic resistance means, and

wherein the conductivity signal of the liquid medium has an uninterrupted range of conductivity between 0.001 mS/em and 1000 mS/cm.

30. The method as claimed in claim 14, wherein the liquid medium is water.

31. The method as claimed in claim 14, wherein the uninterrupted range of conductivity is between 0.001 mS/cm and 850 mS/cm.