Water-in-silicone oil macroemulsion cosmetic composition

• US 9,358,188 B2
• Filed: 11/12/2013
• Issued: 06/07/2016
• Est. Priority Date: 11/13/2012
• Status: Active Grant

• Current Assignee: Shin-Etsu Chemical Company Limited
• Original Assignee: Shin-Etsu Chemical Company Limited
• Inventors: Lee, Taeck-young
• Primary Examiner(s): Arnold, Ernst V
• Assistant Examiner(s): Yu, Hong
• Application Number:
  US14/077,833
• Publication Number:
  US 20140135406A1
• Time in Patent Office: 938 Days
• Field of Search: 514/772.3, 424/455
• US Class Current: 1/1
• CPC Class Codes: A61K 2800/5922 At least two compounds being classified in the same subclass of A61K8/18
• CPC Class Codes: A61K 8/064 Water-in-oil emulsions, e.g. Water-in-silicone emulsions
• CPC Class Codes: A61K 8/20 Halogens; Compounds thereof
• CPC Class Codes: A61K 8/23 Sulfur; Selenium; Tellurium; Compounds thereof
• CPC Class Codes: A61K 8/34 Alcohols
• CPC Class Codes: A61K 8/345 containing more than one hydroxy group
• CPC Class Codes: A61K 8/365 Hydroxycarboxylic acids; Ketocarboxylic acids
• CPC Class Codes: A61K 8/60 Sugars; Derivatives thereof
• CPC Class Codes: A61K 8/86 Polyethers
• CPC Class Codes: A61K 8/89 Polysiloxanes
• CPC Class Codes: A61K 8/891 saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
• CPC Class Codes: A61K 8/894 modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
• CPC Class Codes: A61K 8/895 containing silicon bound to unsaturated aliphatic groups, e.g. vinyl dimethicone
• CPC Class Codes: A61Q 19/00 Preparations for care of the skin
• CPC Class Codes: A61Q 19/007 Preparations for dry skin

Abstract

A water-in-silicone oil (W/S) macroemulsion cosmetic composition of waterdrop quick break type is provided. The silicone oil phase part (S) contains a partly crosslinked emulsifiable silicone elastomer, a partly crosslinked non-emulsifiable silicone elastomer, and silicone oil, and the aqueous phase part (W) contains 1,3-butylene glycol and a lower alcohol, and also, at least one member selected from the group consisting of organic acid salts, inorganic salts, and polyhydric alcohols excluding glycerin and 1,3-butylene glycol as a freeze stabilizer at a predetermined composition. The cosmetic composition instantaneously releases water upon application on the skin. The cosmetic composition is stable at the extremely low temperature of −20° C., and it retains its dispersion stability even after repeated freezing and thawing, and accordingly, it can be used in a variety of cosmetic product.

Claims

1. A water-in-silicone oil macroemulsion cosmetic composition comprising a silicone oil phase part and aqueous phase, wherein

the silicone oil phase part (S) comprises a partly crosslinked emulsifiable silicone elastomer, a partly crosslinked non-emulsifiable silicone elastomer, a non-crosslinked silicone emulsifier, and a silicone oil, and

the aqueous phase part is substantially free from glycerin, and the aqueous phase part (W) contains 1,3-butylene glycol and a lower alcohol at a total amount of 13 to 18% by weight of the entire composition, and at least one member selected from the group consisting of organic acid salts, inorganic salts, and polyhydric alcohols other than glycerin and 1,3-butylene glycol at a total amount of 0.4 to 3.0% by weight of the entire composition as a freeze stabilizer,

wherein the weight ratio of the silicone oil phase part (S):

the aqueous phase part being 7;

93 to 13.1;

86.9 and water content being 67.7 to 73.6% by weight in the composition, and

wherein the water-in-silicone oil macroemulsion is in the form of an emulsion having an average particle size of 5 to 20 μ

m.

2. A water-in-silicone oil macroemulsion cosmetic composition of claim 1 wherein the 1,3-butylene glycol and the lower alcohol is 4:

1 to 1;

2 in the weight ratio.

3. A water-in-silicone oil macroemulsion cosmetic composition of claim 1 wherein the content of the organic acid salt is present in an amount of 0.05 to 0.5% by weight of the entire composition.

4. A water-in-silicone oil macroemulsion cosmetic composition according to claim 1 wherein the lower alcohol is at least one member selected from methanol, ethanol, isopropanol, butanol, and pentanol.

5. A water-in-silicone oil macroemulsion cosmetic composition according to claim 1 wherein the organic acid salt is at least one member selected from the group consisting of sodium citrate, sodium formate, sodium acetate, and potassium acetate.

6. A water-in-silicone oil macroemulsion cosmetic composition according to claim 1 wherein the inorganic salt is at least one member selected from sodium chloride, potassium chloride, calcium chloride, magnesium chloride, and magnesium sulfate.

7. A water-in-silicone oil macroemulsion cosmetic composition according to claim 6 wherein the inorganic salt is at least one member selected from sodium chloride and potassium chloride.

8. A water-in-silicone oil macroemulsion cosmetic composition according to claim 1 wherein the polyhydric alcohol is least one member selected from ethylene glycol, propylene glycol, dipropylene glycol, tripropylene glycol, diethylene glycol, sorbitol, mannitol, maltitol, lactitol, glucose, polyethylene glycol, and polypropylene glycol.

9. A water-in-silicone oil macroemulsion cosmetic composition according to claim 1, wherein the non-crosslinked silicone emulsifier is incorporated at an amount of from 0.03% by weight in relation to the total weight of silicone oil phase to 0.2% by weight in relation to the weight of the entire composition, the aqueous phase part is free from glycerin, and the aqueous phase part (W) contains 1,3-butylene glycol and a lower alcohol selected from methanol, ethanol, isopropanol, butanol, and pentanol at a total amount of 13 to 18% by weight of the entire composition, and at least one member selected from the group consisting of organic acid salts, inorganic salts, and polyhydric alcohols other than glycerin and 1,3-butylene glycol at a total amount of 0.4 to 3.0% by weight of the entire composition as a freeze stabilizer part.