Method of treating a lens forming surface of at least one mold half of a mold for molding ophthalmic lenses

• US 9,358,735 B2
• Filed: 11/26/2012
• Issued: 06/07/2016
• Est. Priority Date: 11/29/2011
• Status: Active Grant

• Current Assignee: Alcon Incorporated
• Original Assignee: Novartis Ag
• Inventors: Bothe, Harald, Matsuzawa, Yasuo
• Primary Examiner(s): VARGOT, MATHIEU D
• Application Number:
  US13/684,790
• Publication Number:
  US 20130147072A1
• Time in Patent Office: 1,289 Days
• US Class Current: 1/1
• CPC Class Codes: B29C 2033/725 cleaning by plasma treatment
• CPC Class Codes: B29C 33/72 Cleaning extruder parts B29C48/27; in general B08B7/00
• CPC Class Codes: B29D 11/00009 Production of simple or compound lenses
• CPC Class Codes: B29D 11/00038 Production of contact lenses
• CPC Class Codes: B29D 11/00125 Auxiliary operations, e.g. removing oxygen from the mould, conveying moulds from a storage to the production line in an inert atmosphere
• CPC Class Codes: B29D 11/0048 Moulds for lenses moulds for plastic articles in general B29C33/00

Abstract

A method of treating of a lens forming surface (2) of at least one mold half (1) of a mold for molding an ophthalmic lens, in particular of the lens forming surface of a glass mold half for molding a contact lens, especially a soft contact lens, includes the steps of:

• • providing a plasma (10) under atmospheric pressure, and
  • exposing the lens forming surface (2) to the plasma (10) under atmospheric pressure thereby hydrophilizing the lens forming surface (2) without depositing any material on the lens forming surface (2).

Claims

1. Method of molding a silicon hydrogel soft contact lens, the method comprising the steps of providing a mold comprising a male mold half and a female mold half, each of the male and female mold halves having a lens forming surface, introducing a silicon hydrogel lens forming material into the male mold half or the female mold half, assembling the male and female mold halves, exposing the lens forming material arranged between the lens forming surfaces of the male and female mold halves to polymerizing and/or crosslinking energy to form the silicon hydrogel soft contact lens, disassembling the male and female mold halves to open the mold, and removing the silicon hydrogel soft contact lens from the male mold half or from the female mold half,

wherein the lens forming surface of either both the male and female mold halves or of only one of the male and female mold halves is treated by a plasma treatment prior to introducing the lens forming material into the male mold half or the female mold half,

wherein the plasma is generated with the aid of a plasma torch comprising a plasma gun and a tubular plasma concentrator, the plasma concentrator sealingly surrounding the space between the plasma gun and the lens forming surface of the mold or mold half, wherein the plasma treatment is under atmospheric pressure thereby hydrophilizing the lens forming surface without depositing any material on the lens forming surface.

2. Method according to claim 1, wherein the mold halves are reusable and are reused to mold a plurality of silicon hydrogel soft contact lenses, and wherein the lens forming surface(s) of one of the mold halves or of both mold halves is exposed to the plasma again after molding a predetermined number of ophthalmic lenses.

3. Method according to claim 1, wherein the mold halves are reusable mold halves which are reused to mold a plurality of silicon hydrogel soft contact lenses, and wherein the lens forming surface(s) of one of the mold halves or of both mold halves is exposed to the plasma prior to molding of each silicon hydrogel soft contact lens.

4. Method according to claim 1, wherein the lens forming surfaces of both the male mold half and the female mold half are exposed to the plasma treatment.

5. Method according to claim 2, wherein the lens forming surfaces of the male mold half and of the female mold half are exposed to the plasma for different periods of time.

6. Method according to claim 1, wherein only one of the lens forming surfaces of the male mold half and the female mold half are exposed to the plasma treatment.

7. Method according to claim 6, wherein only the lens forming surfaces of the female mold half are exposed to the plasma treatment.

8. Method according to claim 1, wherein the plasma is a plasma of a gas selected from the group consisting of argon, helium, nitrogen, oxygen, tetrafluoroethane, air, or a mixture of argon and oxygen, argon and nitrogen, argon and air, argon and tetrafluoroethane, helium and oxygen, helium and nitrogen, helium and air, helium and tetrafluoroethane, nitrogen and oxygen.

9. Method according to claim 1, wherein the plasma is a plasma of argon or a plasma of a mixture of argon and oxygen.

10. Method according to claim 1, wherein the lens forming surface is exposed to the plasma such that the water contact angle of the treated lens forming surface is smaller than 40°

.

11. Method according to claim 1, wherein the lens forming surface is exposed to the plasma for a time period not exceeding 20 seconds.

12. Method according to claim 6, wherein the mold half exposed to plasma is a male mold half which is provided with an annular mask made from metal, the annular mask being arranged to surround the lens forming surface of the male mold half, and wherein the annular mask is shielded from exposure to the plasma by the plasma concentrator.

13. Method of treating of a lens forming surface of at least one mold half of a mold for molding an ophthalmic lens, the method including the steps of:

providing a plasma under atmospheric pressure, and

exposing the lens forming surface to the plasma under atmospheric pressure thereby hydrophilizing the lens forming surface without depositing any material on the lens forming surface, wherein the plasma is generated with the aid of a plasma torch comprising a plasma gun and a tubular plasma concentrator, the plasma concentrator sealingly surrounding the space between the plasma gun and the lens forming surface of the mold or mold half.

14. Method according to claim 13, wherein the mold comprises a male mold half and a female mold half, and wherein the lens forming surfaces of both the male mold half and the female mold half are exposed to the plasma.

15. Method according to claim 14, wherein the lens forming surfaces of the male mold half and of the female mold half are exposed to the plasma for different periods of time.

16. Method according to claim 13, wherein the mold comprises a male mold half and a female mold half, and wherein the lens forming surface of only one of the male and female mold halves is exposed to the plasma.

17. Method according to claim 16, wherein the lens forming surface of only the female mold half is exposed to the plasma.

18. Method according to claim 13, wherein the plasma is a plasma of a gas selected from the group consisting of argon, helium, nitrogen, oxygen, tetrafluoroethane, air, or a mixture of argon and oxygen, argon and nitrogen, argon and air, argon and tetrafluoroethane, helium and oxygen, helium and nitrogen, helium and air, helium and tetrafluoroethane, nitrogen and oxygen.

19. Method according to claim 13, wherein the plasma is a plasma of argon or a plasma of a mixture of argon and oxygen.

20. Method according to claim 13, wherein the lens forming surface is exposed to the plasma such that the water contact angle of the treated lens forming surface is smaller than 40°

.

21. Method according to claim 13, wherein the lens forming surface is exposed to the plasma for a time period not exceeding 20 seconds, preferably for a time period in the range of 5 to 20 seconds.

22. Method according to claim 13, wherein the mold half exposed to plasma is a male mold half which is provided with an annular mask made from metal, the annular mask being arranged to surround the lens forming surface of the male mold half, and wherein the annular mask is shielded from exposure to the plasma by the plasma concentrator.