Wellbore cement compositions and wellbore cementing methods

• US 9,359,254 B2
• Filed: 11/12/2013
• Issued: 06/07/2016
• Est. Priority Date: 11/12/2013
• Status: Active Grant

• Current Assignee: Baker Hughes Holdings LLC (Baker Hughes Company)
• Original Assignee: Baker Hughes Incorporated (Baker Hughes Company)
• Inventors: Narvaez, Guido G., Cardona, Diana, Vorderbruggen, Mark A., Shen, Dong
• Primary Examiner(s): Marcantoni, Paul
• Application Number:
  US14/077,554
• Publication Number:
  US 20150129217A1
• Time in Patent Office: 938 Days
• US Class Current: 1/1
• CPC Class Codes: C04B 14/047 Zeolites
• CPC Class Codes: C04B 14/06 Quartz; Sand
• CPC Class Codes: C04B 14/08 Diatomaceous earth
• CPC Class Codes: C04B 14/14 Minerals of vulcanic origin granite C04B14/048
• CPC Class Codes: C04B 20/0016 Granular materials, e.g. microballoons
• CPC Class Codes: C04B 20/1018 with organic materials pigments or dyes C04B20/1096
• CPC Class Codes: C04B 20/1022 Non-macromolecular compounds
• CPC Class Codes: C04B 20/1037 obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
• CPC Class Codes: C04B 2103/20 Retarders
• CPC Class Codes: C04B 24/003 Phosphorus-containing compounds
• CPC Class Codes: C04B 24/08 Fats; Fatty oils; Ester type waxes; Higher fatty acids, i.e. having at least seven carbon atoms in an unbroken chain bound to a carboxyl group; Oxidised oils or fats
• CPC Class Codes: C04B 28/02 containing hydraulic cements other than calcium sulfates
• CPC Class Codes: C09K 8/467 containing additives for specific purposes
• CPC Class Codes: E21B 33/13 Methods or devices for cementing, for plugging holes, crevices or the like
• CPC Class Codes: E21B 33/14 for cementing casings into boreholes

Abstract

A wellbore cement composition includes substantially unhydrated cement powder and additive powder for cement. The additive powder is formulated from ingredients including a liquid additive for cement and solid carrier particles. The liquid additive is absorbed by the solid carrier particles. A wellbore cementing method includes using a dry cement composition, adding water to the dry cement composition, forming a cement slurry, placing the slurry in a wellbore, and setting the placed slurry. The dry cement composition contains substantially unhydrated cement powder and retarder powder for cement. The retarder powder contains a retarder absorbed by solid carrier particles.

Claims

1. A wellbore cement composition comprising:

substantially unhydrated cement powder; and

non-cementitious additive powder for cement, the additive powder being formulated from ingredients including a liquid additive for cement and solid carrier particles, the liquid additive being absorbed by the solid carrier particles and including a material selected from retarders, drilling mud surfactants, fluid loss agents, organic dispersants, antifoam agents, cement set accelerators, foamers, foam stabilizers, and combinations thereof, and the additive powder containing a mass of the liquid additive at least one-half a mass of the solid carrier particles.

2. The composition of claim 1 wherein the liquid additive comprises a material selected from retarders including modified phosphonate/gluconic acid-based polymer or acrylic acid-polyethylene glycol copolymer, dispersants including polynapthalene sulfonate formaldehyde polymer, acetone formaldehyde polymers, or acrylic acid polycarboxylate polymer, antifoam agents including polyglycol ether polymers, vegetable oils, silicone oils, or C₇ to C₁₂ alcohols, and combinations thereof.

3. The composition of claim 1 wherein the liquid additive is a liquid retarder for cement.

4. The composition of claim 3 wherein the liquid retarder comprises modified phosphonate/gluconic acid-based polymer or acrylic acid-polyethylene glycol copolymer.

5. The composition of claim 1 wherein the solid carrier particles comprise diatomaceous earth and both the solid carrier particles and the additive powder are free-flowing solids.

6. The composition of claim 1 wherein the solid carrier particles comprise a material selected from diatomaceous earth, zeolite, aerogel, pumice, porous silica, and combinations thereof.

7. The composition of claim 3 wherein an amount of the liquid retarder absorbed by the solid carrier particles exhibits the property of delaying setting of a cement slurry longer than an equal amount of retarder in liquid form added to the cement slurry.

8. The composition of claim 1 wherein the mass of the liquid additive is at least two times the mass of the solid carrier particles.

9. A wellbore cement composition comprising:

substantially unhydrated cement powder; and

non-cementitious retarder powder for cement, the retarder powder containing a retarder absorbed by solid carrier particles, an amount of the retarder absorbed by the solid carrier particles exhibiting the property of delaying setting of a cement slurry longer than an equal amount of retarder in liquid form added to the cement slurry.

10. The composition of claim 9 wherein the retarder powder exhibits the property of delaying setting of the cement slurry longer than the cement slurry without the retarder powder.

11. The composition of claim 9 wherein the retarder powder exhibits the property of delaying setting of cement for at least three hours following addition of water to form the cement slurry.

12. The composition of claim 9 wherein the retarder powder comprises a mass of the liquid retarder at least one-half a mass of the solid carrier particles.

13. The composition of claim 9 wherein the solid carrier particles comprise diatomaceous earth and both the solid carrier particles and the additive powder are free-flowing solids.

14. The composition of claim 9 wherein the solid carrier particles comprise a material selected from diatomaceous earth, zeolite, aerogel, pumice, porous silica, and combinations thereof.

15. The composition of claim 9 wherein the retarder exhibits the property of dissolving from the solid carrier particles into the cement slurry.

16. The composition of claim 9 wherein the retarder powder exhibits the property of maintaining strength of the set cement compared to the set cement without the retarder powder.

17. A wellbore cement composition formulated from ingredients comprising:

a dry cement composition containing an admixture of;

substantially unhydrated cement powder; and

non-cementitious retarder powder for cement, the retarder powder being formulated from ingredients including a liquid retarder for cement and solid carrier particles, the liquid retarder being absorbed by the solid carrier particles and having a mass at least two times a mass of the solid carrier particles; and

water sufficient to form a settable cement slurry.

18. The composition of claim 17 wherein an amount of the retarder absorbed by the solid carrier particles delays setting of the cement slurry longer than an equal amount of retarder in liquid form added to the cement slurry.

19. The composition of claim 18 wherein the liquid retarder comprises modified phosphonate/gluconic acid-based polymer or acrylic acid-polyethylene glycol copolymer.

20. The composition of claim 19 wherein the solid carrier particles comprise diatomaceous earth and both the solid carrier particles and the additive powder are free-flowing solids in the dry cement composition.