Encapsulated white OLEDs having enhanced optical output

• US 9,362,530 B2
• Filed: 07/13/2015
• Issued: 06/07/2016
• Est. Priority Date: 12/22/2008
• Status: Active Grant

• Current Assignee: Samsung Display Company Limited (Samsung Electronics Co. Ltd.)
• Original Assignee: Samsung Display Company Limited (Samsung Electronics Co. Ltd.)
• Inventors: Visser, Robert Jan, Moro, Lorenza
• Primary Examiner(s): BOWMAN, MARY ELLEN
• Application Number:
  US14/797,260
• Publication Number:
  US 20160013450A1
• Time in Patent Office: 330 Days
• US Class Current: 1/1
• CPC Class Codes: H10K 2102/00 Constructional details relating to the organic devices covered by this subclass
• CPC Class Codes: H10K 2102/351 Thickness
• CPC Class Codes: H10K 50/00 Organic light-emitting devices integrated devices or assemblies of multiple devices H10K59/00, H10K65/00; organic semiconductor lasers H01S5/36
• CPC Class Codes: H10K 50/81 Anodes
• CPC Class Codes: H10K 50/828 Transparent cathodes, e.g. comprising thin metal layers
• CPC Class Codes: H10K 50/84 Passivation; Containers; Encapsulations
• CPC Class Codes: H10K 50/8445 multilayered coatings having a repetitive structure, e.g. having multiple organic-inorganic bilayers
• CPC Class Codes: H10K 50/85 Arrangements for extracting light from the devices
• CPC Class Codes: H10K 50/858 comprising refractive means, e.g. lenses

Abstract

Methods of making an integrated barrier stack and optical enhancement layer for protecting and improving the light out coupling of encapsulated white OLEDs are described. The method includes optimizing the thickness of various layers including one or more of the plasma protective layer, the initial organic layer, the initial inorganic barrier layer, and the inorganic barrier layer and polymeric decoupling layer for the barrier stack. The thickness is optimized for at least one of total efficiency, or intentional color point shift so that the encapsulated OLED has enhanced light outcoupling compared to the bare OLED.

Claims

1. An encapsulated white OLED having an integrated barrier and optical enhancement stack for protecting and improving the light out coupling of the encapsulated white OLED comprising;

a co-doped white OLED having a transparent electrode;

a plasma protective layer having a refractive index in a range of about 1.1 to about 1.9 and a thickness within a range of about 20 nm to about 50 nm, the plasma protective layer adjacent to the transparent electrode of the white OLED;

an initial inorganic barrier layer having a refractive index in a range of about 1.55 to about 2 and a thickness within a range of about 40 nm to about 240 nm, the initial inorganic barrier layer adjacent to the transparent electrode in the white OLED; and

a barrier stack comprising at least a pair of inorganic barrier layers and a polymeric decoupling layer between the inorganic barrier layers, the inorganic barrier layer having a refractive index in a range of about 1.55 to about 2 and a thickness within a range of about 20 nm to about 80 nm, and the polymeric decoupling layer having a refractive index in a range of about 1.4 to about 1.65 and a thickness within in a range of about 0.2 μ

m to about 4 μ

m, the barrier stack adjacent to the initial inorganic barrier layer, wherein the thickness of at least one of the plasma protective layer, initial inorganic barrier layer, the inorganic barrier layer, or the polymeric decoupling layer are optimized for at least one of total efficiency, or intentional color point shift so that the encapsulated white OLED has enhanced light outcoupling compared to a bare white OLED, wherein the initial inorganic barrier layer is different from the inorganic barrier layer of the barrier stack and further wherein the improving the light out coupling of the encapsulated OLED is achieved without either (a) a scattering layer placed adjacent the OLED, initial inorganic barrier layer or barrier stack or (b) a quarter-wave stack placed adjacent the OLED, initial inorganic barrier layer or barrier stack.

2. The encapsulated white OLED of claim 1, wherein the plasma protective layer is an inorganic layer.

3. The encapsulated white OLED of claim 1, wherein the transparent electrode is a transparent cathode.

4. The encapsulated white OLED of claim 3, wherein the co-doped white OLED includes a transparent cathode layer material, the transparent cathode layer material having a refractive index in a range of about 1.6 to about 2 and a thickness within a range of about 20 to about 300 nm, and wherein thickness of the cathode layer is optimized for at least one of total efficiency, or intentional color point shift.

5. The method of claim 1, wherein the transparent electrode in the OLED is a transparent anode.

6. An encapsulated white OLED having an integrated barrier and optical enhancement stack for protecting and improving the light out coupling of the encapsulated white OLED comprising:

a vertically stacked white OLED having a transparent electrode;

an initial organic layer having a refractive index in a range of about 1.4 to about 1.65 and a thickness within range of about 0.2 μ

m to about 1 μ

m, the initial organic layer adjacent to the transparent electrode of the white electrode;

an initial inorganic barrier layer having a refractive index in a range of about 1.55 to about 2 and a thickness within a range of about 40 nm to about 240 nm, the initial inorganic barrier layer adjacent to a transparent electrode in the white OLED; and

a barrier stack comprising at least a pair of inorganic barrier layers and a polymeric decoupling layer between the inorganic barrier layers, the inorganic barrier layer having a refractive index in a range of about 1.55 to about 2 and a thickness within a range of about 20 nm to about 80 nm, and the polymeric decoupling layer having a refractive index in a range of about 1.4 to about 1.65 and a thickness within a range of about 0.2 μ

m to about 4 μ

m, the barrier stack adjacent to the initial inorganic barrier layer, wherein the thickness of at least one of the initial organic layer, initial inorganic barrier layer, the inorganic barrier layer, or the polymeric decoupling layer are optimized for at least one of total efficiency, or intentional color point shift so that the encapsulated white OLED has enhanced light outcoupling compared to a bare white OLED, wherein the initial inorganic barrier layer is different from the inorganic barrier layer of the barrier stack and further wherein the improving the light out coupling of the encapsulated OLED is achieved without either (a) a scattering layer placed adjacent the OLED, initial inorganic barrier layer or barrier stack or (b) a quarter-wave stack placed adjacent the OLED, initial inorganic barrier layer or barrier stack.

7. The encapsulated white OLED of claim 6, further comprising a plasma protective layer having a refractive index in a range of about 1.1 to about 1.9 and a thickness within a range of about 20 nm to about 50 nm, the plasma protective layer between the transparent electrode of the white OLED and the initial organic layer, wherein the thickness of the plasma protective layer is optimized for at least one of total efficiency, or intentional color point shift so that the encapsulated white OLED has enhanced light outcoupling compared to the bare white OLED.

8. The method of claim 7, wherein the plasma protective layer is an inorganic layer.

9. The method of claim 6, wherein the transparent electrode is a transparent cathode.