Electrolyte separator and method of making the electrolyte separator

• US 9,368,774 B2
• Filed: 03/24/2010
• Issued: 06/14/2016
• Est. Priority Date: 03/24/2010
• Status: Active Grant

• Current Assignee: General Electric Company
• Original Assignee: General Electric Company
• Inventors: Kumar, Sundeep, Rahmane, Mohamed, Nayak, Mohandas, Basak, Arunabh, Krishna, Kalaga Murali, Saha, Atanu
• Primary Examiner(s): Huff, Mark F
• Assistant Examiner(s): WILLS, MONIQUE M
• Application Number:
  US12/730,496
• Publication Number:
  US 20110236743A1
• Time in Patent Office: 2,274 Days
• Field of Search: 429/144, 264/241
• US Class Current: 1/1
• CPC Class Codes: H01M 10/39 working at high temperature
• CPC Class Codes: H01M 50/434 Ceramics
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

An electrolyte separator structure is provided. The electrolyte separator structure comprises a graded integral structure, wherein the structure comprises an ion-conducting first ceramic at a first end and an electrically insulating second ceramic at a second end, wherein the difference in the coefficient of thermal expansion of the ion-conducting first ceramic and the electrically insulating second ceramic is less than or equal to about 5 parts per million per degrees Centigrade, and wherein at least one of the first ceramic or the second ceramic comprises a strengthening agent. Method of making the ion-separator structure is provided. Electrochemical cells comprising the ion-separator structure and method of making the electrochemical cell using the ion-separator structure are also provided.

Claims

1. An electrolyte separator structure comprising:

a graded integral structure, wherein the graded integral structure comprises a monolithic structure comprising an ion-conducting first ceramic at a first end and an electrically insulating second ceramic at a second end;

wherein the electrically insulating second ceramic comprises one or more of alpha-alumina, yttria, yttria stabilized zirconia, yttrium aluminum garnet, magnesia alumina spinel, and yttrium aluminate perovskite;

wherein the difference in the coefficient of thermal expansion of the ion-conducting first ceramic and the electrically insulating second ceramic is less than or equal to about 5 parts per million per degrees Centigrade; and

wherein at least one of the first ceramic or the second ceramic comprises a strengthening agent that comprises an oxide, a nitride, or a carbide of at least one element selected from the group consisting of group IIIA elements, group IIIB elements, group IVB elements, and group IVB elements.

2. The electrolyte separator structure of claim 1, wherein the ion-conducting first ceramic comprises beta-alumina.

3. The electrolyte separator structure of claim 1, wherein about 80 percent to about 99 percent of the graded integral structure, based on the total length of the graded integral structure, comprises the ion-conducting first ceramic.

4. The electrolyte separator structure of claim 1, wherein about 1 percent to about 20 percent of the graded integral structure, based on the total length of the graded integral structure, comprises the electrically insulating second ceramic.

5. The electrolyte separator structure of claim 1, wherein the difference in the coefficient of thermal expansion of the ion-conducting first ceramic and the electrically insulating second ceramic is in a range from about 0.001 parts per million per degrees Centigrade to about 5 parts per million per degrees Centigrade.

6. The electrolyte separator structure of claim 1, wherein both the first ceramic and the second ceramic comprise a strengthening agent.

7. The electrolyte separator structure of claim 1, wherein the strengthening agent is present in the first ceramic in a range from about 1 volume percent to about 50 volume percent based on the volume of the first ceramic.

8. The electrolyte separator structure of claim 1, wherein the strengthening agent is present in the second ceramic in a range from about 1 volume percent to about 50 volume percent based on the volume of the second ceramic.

9. The electrolyte separator structure of claim 1, wherein the ratio of the amount of the strengthening agent present in the first ceramic to the amount of the strengthening agent in the second ceramic is in a range from about 1:

0.2 to about 1;

5.

10. The electrolyte separator structure of claim 1, wherein the graded integral structure comprises a composition varying in a gradual predetermined manner across a specified length of the structure which forms an interface between the ion-conducting first ceramic and the electrically insulating second ceramic.

11. The electrolyte separator structure of claim 10, wherein the interface between the ion-conducting first ceramic and the electrically insulating second ceramic is free of a sealing material.