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Integration of reforming/water splitting and electrochemical systems for power generation with integrated carbon capture

  • US 9,371,227 B2
  • Filed: 09/08/2010
  • Issued: 06/21/2016
  • Est. Priority Date: 09/08/2009
  • Status: Active Grant
First Claim
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1. A method for producing electricity and a separate CO2 rich stream from a carbonaceous fuel and steam comprising:

  • reducing Fe2O3 containing particles to lower oxidation state metallic iron containing particles by reacting the Fe2O3 containing particles with a carbonaceous fuel in a first reaction zone, the first reaction zone having a top and a bottom;

    oxidizing a first portion of the metallic iron containing particles with a steam or CO2 rich gas from a fuel cell anode in a second reaction zone to provide iron oxide containing particles while generating a fuel rich gas stream comprising H2 or CO;

    returning the fuel rich gas stream from the second reaction zone to the anode of the fuel cell via a closed loop between the second reactor zone and the fuel cell, wherein the closed loop comprises a working fluid stream of (1 ) fuel and (2 ) steam or CO2;

    directly sending a second portion of the metallic iron containing particles from the first reaction zone to a third reaction zone, and oxidizing the second portion of the metallic iron containing particles and iron oxide containing particles obtained from the oxidation reaction in the second reaction zone with an oxygen containing gas to produce Fe2O3 containing particles in a third reaction zone; and

    returning the Fe2O3 containing particles to the first reaction zone;

    wherein at least a portion of the oxygen containing gas used in the third reaction zone is the oxygen containing gas produced from the outlet of a fuel cell cathode.

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