Separation of biocomponents from manure

• US 9,371,356 B2
• Filed: 06/27/2013
• Issued: 06/21/2016
• Est. Priority Date: 06/27/2013
• Status: Active Grant

• Current Assignee: Aicardo Roa-Espinosa
• Original Assignee: Aicardo Roa-Espinosa
• Inventors: Roa-Espinosa, Aicardo
• Primary Examiner(s): DRODGE, JOSEPH W
• Application Number:
  US13/929,618
• Publication Number:
  US 20150005482A1
• Time in Patent Office: 1,090 Days
• Field of Search: 71/15, 71/21, 209162-167, 210/631, 210/632, 210703-705, 210732-736, 210/770, 210/800, 210/804
• US Class Current: 1/1
• CPC Class Codes: B03D 3/06 Flocculation
• CPC Class Codes: C02F 1/24 by flotation C02F1/465 takes precedence
• CPC Class Codes: C02F 1/56 Macromolecular compounds
• CPC Class Codes: C02F 11/121 by mechanical de-watering
• CPC Class Codes: C02F 11/147 using organic substances C02F11/148 takes precedence
• CPC Class Codes: C02F 11/16 using drying or composting beds
• CPC Class Codes: C02F 2103/20 from animal husbandry
• CPC Class Codes: C02F 2303/24 Separation of coarse particles, e.g. by using sieves or screens
• CPC Class Codes: C07K 1/32 as complexes

Abstract

A process for separating amino acids and peptides from raw and digested farm manure is disclosed. The raw manure may be recovered from sand bedding used in the cow stalls of some farms. The process involves the steps of precipitating out struvite and separating a stream rich in amino acids and peptides from a mineral rich stream in a dissolved air floatation machine. Struvite precipitation is accomplished by the addition of polydicyandiamide and an acrylate based polymer, while the separation of the stream rich in fibers, amino acids and peptides from a mineral rich streams is accomplished by the addition of an acrylamide chloride copolymer.

Claims

1. A substantially continuous process for separating a stream rich in fibers, amino acids and peptides and a stream rich in minerals from raw farm manure, said process comprising the steps of:

providing a raw manure stream for treatment, said raw manure stream containing magnesium ammonium phosphate, calcium phosphate, amino acids, peptides, fibers and minerals, said minerals containing nitrogen, phosphorus, potassium and sulfur, said manure stream containing pathogen levels exceeding 6×

10⁵ MPN/mL;

mechanically removing particles having a predetermined size by a screening step;

reducing pathogen levels in the raw manure stream by between a factor of 3.3 to about a factor of 5, said reducing pathogen levels in the raw manure stream being accomplished by treating the raw manure stream in a clarifier at about 7 percent solids with between about 10 parts per million and about 25 parts per million on a dry weight basis of acrylamide/Ethanaminium, N,N,N-trimethyl-2-((1-oxo-2-propenyl)oxo)-, chloride copolymer, said acrylamide/Ethanaminium, N,N,N-trimethyl-2-((1-oxo-2-propenyl)oxo)-, chloride copolymer having a weight average molecular weight of between about 3 million and about 10 million;

precipitating magnesium ammonium phosphate and calcium phosphate, said precipitating being accomplished by the addition of between about 5 parts per million and about 75 parts per million on a dry weight basis of polydicyandiamide polymer, said polydicyandiamide polymer having a weight average molecular weight of between about 3000 and about 150,000; and

separating the stream rich in amino acids, peptides and fibers from the stream rich in minerals, said separating being accomplished in a dissolved air flotation device, said separating being accomplished by adding micronized air of a size between about 10 micrometers and about 20 micrometers at a rate between 5 to 10 cubic feet per hour to the dissolved air flotation device and by the addition of between about 10 parts per million and about 75 parts per million on a dry weight basis of acrylamide/Ethanaminium, N,N,N-trimethyl-2-((1-oxo-2-propenyl)oxo)-, chloride copolymer, said acrylamide/Ethanaminium, N,N,N-trimethyl-2-((1-oxo-2-propenyl)oxo)-, chloride copolymer having a weight average molecular weight of between about 3 million and about 10 million.

2. The process of claim 1, wherein the mineral rich stream contains at least 50 percent by weight of the nitrogen content in the raw manure stream, at least 75% of the phosphorus content by weight in the raw manure stream, at least 10 percent of the potassium content by weight in the raw manure stream, and at least 75% of the sulfur content by weight in the raw manure stream.

3. The process of claim 1, further comprising a volute press configured to remove water from the stream rich in amino acids, peptides and fibers to achieve a solids level of between about 40% to about 70%.

4. The process of claim 1, further comprising passing the raw manure stream through a sand bedding prior to mechanically removing the particles having a predetermined size by the screening step.

5. A substantially continuous process for producing a stream rich in amino acids and peptides from digested farm manure comprising the steps of:

providing a digested manure stream for treatment, said manure stream containing amino acids, peptides, fibers and minerals, said minerals containing nitrogen, phosphorus, potassium and sulfur;

precipitating magnesium ammonium phosphate and calcium phosphate, said precipitating being accomplished by the addition of a polydicyandiamide said polydicyandiamide polymer being added at between about 5 parts per million and about 75 parts per million on a dry weight basis of polydicyandiamide polymer, said polydicyandiamide polymer having a weight average molecular weight of between about 3000 and about 150,000;

passing the digested manure stream through a rotating drum and a screw press for mechanically removing particles having a predetermined size; and

separating a stream rich in amino acids, peptides and fibers, said separating being accomplished in a dissolved air flotation device by adding micronized air of a size between about 10 micrometers and about 20 micrometers at a rate between 5 to 10 cubic feet per hour to the dissolved air flotation device and by the addition of between about 10 parts per million and about 75 parts per million on a dry weight basis of acrylamide/Ethanaminium, N,N,N-trimethyl-2-((1-oxo-2-propenyl)oxo)-, chloride copolymer, said acrylamide/Ethanaminium, N,N,N-trimethyl-2-((1-oxo-2-propenyl)oxo)-, chloride copolymer having a weight average molecular weight of between about 3 million and about 10 million.

6. The process of claim 5, wherein the mineral rich stream contains at least 50 percent by weight of the nitrogen content in the raw manure stream, at least 75% of the phosphorus content by weight in the raw manure stream, at least 10 percent of the potassium content by weight in the raw manure stream, and at least 75% of the sulfur content by weight in the raw manure stream.

7. The process of claim 5, further comprising adding between about 5 parts per million and about 20 parts per million on a dry weight basis of a cationic polyamine having a weight average molecular weight of between about 10,000 and about 1 million, said cationic polyamine being added after the screw press.

8. The process of claim 5, further comprising a volute press configured to remove water from the stream rich in amino acids, peptides and fibers to achieve a solids level of between about 40% to about 70%.