Gradual oxidation below flameout temperature

• US 9,371,993 B2
• Filed: 03/09/2012
• Issued: 06/21/2016
• Est. Priority Date: 03/09/2012
• Status: Active Grant

• Current Assignee: ReductoNox Corp.
• Original Assignee: Ener-Core Power, Inc. (Ener-Core, Inc.)
• Inventors: Armstrong, Jeffrey
• Primary Examiner(s): Sutherland, Steven
• Application Number:
  US13/417,167
• Publication Number:
  US 20130232940A1
• Time in Patent Office: 1,565 Days
• Field of Search: 60/391.82, 607/74, 607/22, 607/237.33, 607/77, 60/395, 60/392.81, 607/91, 431/7, 431/268, 431/5, 431/2, 422/168, 422/173
• US Class Current: 1/1
• CPC Class Codes: B01J 2208/00203 Coils
• CPC Class Codes: B01J 2208/00831 Stationary elements
• CPC Class Codes: B01J 2208/00849 outside the bed, e.g. baffles
• CPC Class Codes: B01J 2208/00902 Nozzle-type feeding elements
• CPC Class Codes: B01J 2208/00911 Sparger-type feeding elements
• CPC Class Codes: B01J 8/062 being installed in a furnace
• CPC Class Codes: F23C 2202/10 Premixing fluegas with fuel and combustion air
• CPC Class Codes: F23C 9/00 Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber fluidised bed combustion apparatus with means for recirculation of particles entrained from the bed F23C10/02; fluidised bed combustion apparatus with devices for removal and partial reintroduction of material from the bed F23C10/26
• CPC Class Codes: F23G 2206/202 with an internal combustion engine
• CPC Class Codes: F23G 5/46 Recuperation of heat
• CPC Class Codes: F23G 7/066 preheating the waste gas by the heat of the combustion, e.g. recuperation type incinerator
• CPC Class Codes: F23R 2900/00002 Gas turbine combustors adapted for fuels having low heating value [LHV]
• CPC Class Codes: F23R 3/005 Combined with pressure or heat exchangers
• CPC Class Codes: Y02E 20/12 Heat utilisation in combustion or incineration of waste

Abstract

Described herein are embodiments of systems and methods for oxidizing gases. In some embodiments, a reaction chamber is configured to receive a fuel gas and maintain the gas at a temperature within the reaction chamber that is above an autoignition temperature of the gas. The reaction chamber may also be configured to maintain a reaction temperature within the reaction chamber below a flameout temperature. In some embodiments, heat and product gases from the oxidation process can be used, for example, to drive a turbine, reciprocating engine, and injected back into the reaction chamber.

Claims

1. An oxidizer for oxidizing fuel, comprising:

a reaction chamber having (i) one or more inlets that are configured to direct at least one gas of a fuel, oxidant, or diluent, into the reaction chamber and (ii) one or more outlets that are configured to direct reaction products from the reaction chamber;

a heater that is configured to maintain a temperature of the at least one gas, the at least one gas being at or before the one or more inlets, to be above an autoignition temperature of a resulting mixture, comprising the at least one gas, within the reaction chamber, wherein the reaction chamber is configured to oxidize the resulting mixture; and

a controller configured to output instructions to the reaction chamber to maintain a maximum reaction temperature in the reaction chamber below a flameout temperature of the resulting mixture while a calculated adiabatic temperature is above the flameout temperature by controlling at least one of (i) removal of heat from the reaction chamber or (ii) an inlet temperature of the reaction chamber.

2. The oxidizer of claim 1, wherein the reaction chamber comprises a single inlet.

3. The oxidizer of claim 2, wherein the oxidizer is configured to change a flow rate that the resulting mixture is introduced into the reaction chamber through the single inlet.

4. The oxidizer of claim 2, further comprising a regulator that is configured to change at least one of a flow of the resulting mixture or a pressure of the resulting mixture at or near the single inlet.

5. The oxidizer of claim 1, wherein the heater comprises a heat exchanger that transfers heat from the reaction products to the resulting mixture at or before the one or more inlets.

6. The oxidizer of claim 1, wherein the heater is configured to mix at least one of oxidants or diluents with fuel at or before the one or more inlets.

7. The oxidizer of claim 1, wherein the oxidizer is configured to use heat from the reaction products to generate steam.

8. The oxidizer of claim 1, wherein the oxidizer is configured to use heat from the reaction products to drive a generator for power generation.

9. The oxidizer of claim 8, wherein the oxidizer is configured to drive a generator by a turbine or a piston engine that is configured to expand the reaction products from the reaction chamber.

10. The oxidizer of claim 1, wherein the oxidizer is configured to use heat from the reaction products to heat material that is not passed through the oxidizer.

11. The oxidizer of claim 1, wherein the oxidizer is configured to change a flow rate of the at least one gas of a fuel, oxidant, or diluent introduced into the reaction chamber through the one or more inlets.

12. The oxidizer of claim 1, wherein the oxidizer is configured to change a flow rate of the reaction products directed from the reaction chamber through the outlets.

13. The oxidizer of claim 1, further comprising a regulator that is configured to change at least one of a temperature, a flow rate, or a pressure of at least one of a fuel, oxidant, or diluent at or near one or more inlets.

14. An oxidizer for oxidizing fuel, comprising:

a reaction chamber having (i) an inlet that is configured to direct at least one gas of a fuel, oxidant, or diluent, into the reaction chamber and (ii) an outlet that is configured to direct reaction products from the reaction chamber;

means for maintaining a temperature of an incoming gas, the incoming gas being at or before the inlet, to be above an autoignition temperature of a resulting mixture, comprising the at least one gas, within the reaction chamber, wherein the reaction chamber is configured to oxidize the resulting mixture; and

a controller configured to output instructions to the reaction chamber to maintain a maximum reaction temperature in the reaction chamber below a flameout temperature of the resulting mixture while a calculated adiabatic temperature is above the flameout temperature by controlling at least one of (i) removal of heat from the reaction chamber or (ii) an inlet temperature of the reaction chamber.

15. The oxidizer of claim 14, wherein the reaction chamber comprises a plurality of inlets.

16. The oxidizer of claim 14, wherein the reaction chamber comprises a plurality of outlets.

17. The oxidizer of claim 14, wherein the means for maintaining a temperature comprises a heat exchanger that transfers heat from the reaction products to the resulting mixture at or before the inlet.

18. The oxidizer of claim 14, wherein the means for maintaining a temperature is configured to mix diluents with fuel at or before the inlet.

19. The oxidizer of claim 14, wherein the oxidizer is configured to use heat from the reaction products to generate steam.

20. The oxidizer of claim 14, wherein the oxidizer is configured to use heat from the reaction products to drive a generator for power generation.

21. The oxidizer of claim 20, wherein the oxidizer is configured to drive a generator by a turbine or a piston engine that is configured to expand the reaction products from the reaction chamber.

22. The oxidizer of claim 14, wherein the oxidizer is configured to use heat from the reaction products to heat material that is not passed through the oxidizer.

23. The oxidizer of claim 14, wherein the oxidizer is configured to change a flow rate of the resulting mixture introduced into the reaction chamber through the inlet.

24. The oxidizer of claim 14, wherein the oxidizer is configured to change a flow rate of the reaction products directed from the reaction chamber through the outlet.

25. The oxidizer of claim 14, further comprising a regulator that is configured to change at least one of a flow of the resulting mixture or a pressure of the resulting mixture at or near the inlet.

26. The oxidizer of claim 14, wherein the oxidizer is configured to change a flow rate of the at least one gas of fuel, oxidants, or diluents introduced into the reaction chamber through one or more inlets.