Organic electroluminescent element

• US 9,373,818 B2
• Filed: 05/20/2013
• Issued: 06/21/2016
• Est. Priority Date: 05/30/2012
• Status: Active Grant

• Current Assignee: UDC Ireland Limited (Universal Display Corporation)
• Original Assignee: UDC Ireland Limited (Universal Display Corporation)
• Inventors: Itai, Yuichiro, Tobise, Manabu, Morohashi, Kana, Sonoda, Shin'ichiro, Li, Jingbo
• Primary Examiner(s): MOORE, WHITNEY
• Application Number:
  US13/897,652
• Publication Number:
  US 20130334506A1
• Time in Patent Office: 1,128 Days
• US Class Current: 1/1
• CPC Class Codes: H10K 2102/331 Nanoparticles used in non-emissive layers, e.g. in packaging layer
• CPC Class Codes: H10K 50/81 Anodes
• CPC Class Codes: H10K 50/814 combined with auxiliary electrodes, e.g. ITO layer combined with metal lines
• CPC Class Codes: H10K 50/816 Multilayers, e.g. transparent multilayers
• CPC Class Codes: H10K 50/828 Transparent cathodes, e.g. comprising thin metal layers
• CPC Class Codes: H10K 50/854 comprising scattering means
• CPC Class Codes: H10K 50/858 comprising refractive means, e.g. lenses

Abstract

It is an object of the present invention to provide an organic electroluminescent element with which no light extraction layer needs to be produced separately, which has a transparent electrode that is advantageous in terms of cost and can be formed by a simple film formation process, and which is excellent from the standpoint of light extraction efficiency. The present invention provides an organic electroluminescent element in which a substrate, a first electrode adjacent to this substrate, an organic layer including at least one organic light-emitting layer, and a second electrode adjacent to this organic layer are formed in this order, with this organic electroluminescent element being such that at least one of the aforementioned electrodes is a transparent electrode which is transparent, which contains at least one type of light scattering particles that are transparent and that have a primary particle size of at least 0.5 μm, and which is composed of the aforementioned light scattering particles and a component having a refractive index equal to or higher than the refractive index of the aforementioned organic light-emitting layer.

Claims

1. An organic electroluminescent element in which a substrate, a first electrode adjacent to this substrate, an organic layer including at least one organic light-emitting layer, and a second electrode adjacent to this organic layer are formed in this order, wherein

at least one of said electrodes is a transparent electrode, which contains at least one type of light scattering particles that are transparent and have a primary particle size of at least 0.5 μ

m, and which is composed of said light scattering particles and a component having a refractive index equal to or higher than the refractive index of said organic light-emitting layer.

2. The organic electroluminescent element according to claim 1, wherein the component having a refractive index equal to or higher than the refractive index of said organic light-emitting layer contains particles with a primary particle size of 100 nm or less.

3. The organic electroluminescent element according to claim 2, wherein the refractive index of said particles whose primary particle size is 100 nm or less is at least 2.0 and no more than 3.0.

4. The organic electroluminescent element according to claim 1, wherein the component having a refractive index equal to or higher than the refractive index of said organic light-emitting layer contains a conductive matrix.

5. The organic electroluminescent element according to claim 4, wherein the component having a refractive index equal to or higher than the refractive index of said organic light-emitting layer contains a conductive matrix and particles whose primary particle size is 100 nm or less, and the refractive index of said particles whose primary particle size is 100 nm or less is higher than the refractive index of the conductive matrix.

6. The organic electroluminescent element according to claim 1, wherein the refractive index of the component having a refractive index equal to or higher than the refractive index of said organic light-emitting layer is at least 1.7 and no more than 2.2.

7. The organic electroluminescent element according to claim 1, wherein the primary particle size of said light scattering particles is at least 0.5 μ

m and no more than 10 μ

m.

8. The organic electroluminescent element according to claim 1, wherein the refractive index of said light scattering particles is lower than the refractive index of the component having a refractive index equal to or higher than the refractive index of said organic light-emitting layer.

11. The organic electroluminescent element according to claim 1, wherein either said first electrode or second electrode is a transparent electrode, and the other electrode is a metal electrode.

12. The organic electroluminescent element according to claim 1, wherein said first electrode is a transparent electrode.

13. The organic electroluminescent element according to claim 1, wherein wiring whose resistance is lower than that of said first electrode is provided between said first electrode and substrate, and said first electrode covers said wiring.

9. An organic electroluminescent element in which a substrate, a first electrode adjacent to this substrate, an organic layer including at least one organic light-emitting layer, and a second electrode in direct contact with this organic layer are formed in this order, wherein

at least one of said electrodes is a transparent electrode configured from two layers, these two layers both contain a conductive matrix,

one of said two layers contains at least one type of light scattering particles that are transparent and have a primary particle size of at least 0.5 μ

m and is composed of said light scattering particles and a component having a refractive index equal to or higher than the refractive index of said organic light-emitting layer, and the other layer does not contain light scattering particles and has a refractive index that is equal to or higher than the refractive index of the organic light-emitting layer.

10. The organic electroluminescent element according to claim 9, wherein of said two layers, the layer that does not contain light scattering particles is adjacent to the organic layer.