Low pressure electron beam welding of Li-ion battery connections

• US 9,375,804 B2
• Filed: 07/27/2011
• Issued: 06/28/2016
• Est. Priority Date: 07/27/2011
• Status: Active Grant

• Current Assignee: GM Global Technology Operations LLC (General Motors Company)
• Original Assignee: GM Global Technology Operations LLC (General Motors Company)
• Inventors: Lev, Leonid C.
• Primary Examiner(s): Gilliam, Barbara
• Assistant Examiner(s): Arciero, Adam A
• Application Number:
  US13/191,505
• Publication Number:
  US 20130029206A1
• Time in Patent Office: 1,798 Days
• Field of Search: None
• US Class Current: 1/1
• CPC Class Codes: B23K 15/0006 specially adapted for particular articles
• CPC Class Codes: B23K 15/10 Non-vacuum electron beam-welding or cutting
• CPC Class Codes: H01M 10/0525 Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
• CPC Class Codes: H01M 2220/20 Batteries in motive systems, e.g. vehicle, ship, plane
• CPC Class Codes: H01M 50/516 by welding, soldering or brazing
• CPC Class Codes: H01M 50/522 Inorganic material
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product
• CPC Class Codes: Y02T 10/70 Energy storage systems for electromobility, e.g. batteries
• CPC Class Codes: Y10T 29/49108 Electric battery cell making

Abstract

A method for connecting individual lithium ion cells into a battery suited for powering an electric or hybrid vehicle is disclosed. The cell current collectors are electron beam welded to one another and to a connector tab in an substantially oxygen-free atmosphere. The cell current collectors and the connector tab are temporarily secured with a clamp, one portion of which has an opening. The electron beam size may be controlled, by magnetic coils and by the extent of electron scattering by the gas atmosphere, to minimally fill the clamp opening to minimize any irradiation of the clamp. The beam or the workpieces may be displaced, if required, fuse the entire opening area. A similar procedure may be followed to weld a plurality of connector tabs to a busbar.

Claims

1. A method of fusion welding a plurality of current collectors, each having an intended joining portion and each being electrically connected to an electrode of a lithium ion battery, to a tab connector with an intended joining portion, in a weld region, the method comprising:

aligning the plurality of current collectors, each ranging in thickness from 10 to 20 micrometers, and the connector tab, to form a workpiece stack with the current collectors being grouped together and positioned on top of the connector tab;

positioning the stack in a generally horizontal orientation so that the intended joining portions of all of the current collectors are vertically aligned with the intended joining portion of the tab connector;

clamping and compacting the stack between opposing surfaces of only two clamp members, each being of one-piece construction and each with generally flat stack-contacting surfaces;

a first clamp member being in contact with the uppermost current collector in the stack and a second clamp member with a continuous, flat supporting surface in contact with and supporting the connector tab at the bottom of the stack, the first clamp member having at least one through opening for exposing the joining portion of the surface of the uppermost current collector in the stack, the stack-contacting surface of the second clamp being free of surface cavities infiltrateable by liquid metal;

locating the clamp members and stack in a protective, overlying, substantially oxygen-free atmosphere to avoid oxide formation, and irradiating, from above, through the opening in the first clamp member and the protective overlying atmosphere, at least the exposed, joining portion of the surface of the uppermost current collector in the stack with an electron beam to heat and melt the joining portion of the uppermost current collector of the stack; and

then,

continuing to irradiate the stack for a time predetermined to progressively melt the joining portions of each of the remaining current collectors and, at least a portion of the joining portion of the tab connector thickness in that portion of the stack located in the first clamp member opening, to form, from the joining portions, a molten pool against the remaining solid tab thickness portion or the second clamp member surface, the molten pool extending through the joining location portions of each of the current collectors and being confined within the first clamp member opening, before ceasing electron irradiation and cooling the stack to thereby fuse together those portions of the current collectors and the tab located in the first clamp member opening to form a low resistance fusion welded electrical interconnection between all the stack members at their respective joining portions.

2. The method recited in claim 1, further comprising displacing the first clamp member opening relative to the electron beam or by steering the electron beam until all of the clamp member opening is exposed to the electron beam.

3. The method recited in claim 1 in which the current collectors comprise copper.

4. The method recited in claim 1 in which the current collectors comprise aluminum.

5. The method recited in claim 1 in which the atmosphere comprises argon and helium.

6. The method recited in claim 1 in which the first clamp member opening is rectangular.

7. The method recited in claim 1 in which the first clamp member opening is circular.

8. The method recited in claim 1 in which the clamp members are fabricated of one or more of the group consisting of steel, cemented carbide, graphite, molybdenum, nickel and nickel based alloys, aluminum oxide, and zirconium oxide.

9. A method of fusion welding a plurality of tab connectors, each electrically connected to a plurality of current collectors of a plurality of lithium ion cell electrodes, to a 500 to 1000 micrometer thick busbar, the method comprising:

aligning the plurality of tab collectors and the 500 to 1000 micrometer thick busbar to form a work piece stack;

clamping and compacting the stack between opposing, generally planar surfaces of only two clamp members, each being of one-piece construction, one member having at least one through opening with an extent for access to a portion of the stack surface and a second clamp member having a generally flat supporting surface free of surface cavities infiltrateable by liquid metal for supporting the stack;

positioning the stack in a generally horizontal orientation with the clamp member with the through opening being uppermost;

locating the clamp members and stack in a protective, overlying, substantially oxygen-free atmosphere to avoid oxide formation, and exposing at least a portion of the accessible portion of the stack surface to an electron beam, the electron beam being positioned above the stack and of suitable power density to heat and melt the stack, for a time sufficient to heat and melt the stack and fuse together the tab connectors and the busbar; and

,

optionally, traversing the beam across the entire clamp member through opening to melt and fuse together the tab connectors and the busbar located in the accessible portion of the stack to form, a low resistance fusion welded electrical interconnection between the tab connectors and the busbar, the fusion welded electrical interconnection having an extent equal to, or less than, the extent of the clamp opening.

10. The method recited in claim 9 in which the current collectors comprise copper.

11. The method recited in claim 9 in which the current collectors comprise aluminum.

12. The method recited in claim 9 in which the atmosphere comprises argon and helium.

13. The method recited in claim 9 in which the clamp member through opening is rectangular.

14. The method recited in claim 9 in which the clamp member through opening is circular.

15. The method recited in claim 9 in which the clamp members are fabricated of one or more of the group consisting of steel, cemented carbide, graphite, molybdenum, nickel and nickel based alloys, aluminum oxide and zirconium oxide.

16. The method recited in claim 9 in which the clamp comprises the one member comprising an opening and the second member comprising a stack-contacting surface and a flow-through conduit in thermal communication with the stack-contacting surface and the second clamp member is cooled by flowing coolant through the conduit.