Electro-chemical sensor

• US 9,377,434 B2
• Filed: 10/14/2010
• Issued: 06/28/2016
• Est. Priority Date: 12/09/2009
• Status: Active Grant

• Current Assignee: Schlumberger Technology Corporation (Schlumberger NV)
• Original Assignee: Schlumberger Technology Corporation (Schlumberger NV)
• Inventors: Lafitte, Valerie, Lawrence, Nathan S.
• Primary Examiner(s): Nguyen, Tung X
• Assistant Examiner(s): FREDERIKSEN, DAVID B
• Application Number:
  US13/502,718
• Publication Number:
  US 20120268134A1
• Time in Patent Office: 2,084 Days
• Field of Search: 324/324, 324/325, 324/353, 204/400, 204/407, 204/418, 204/431, 204/433, 204/435, 205/789, 205/788, 205/792
• US Class Current: 1/1
• CPC Class Codes: G01N 27/3335 the membrane containing at least one organic component G01N27/3271 takes precedence; aspects concerning the enzyme reagent in enzyme electrodes C12Q1/001
• CPC Class Codes: G01N 33/18 Water

Abstract

An electrochemical sensor for the presence or concentration of an analyte has at least one electrode and at least one electrochemically active species able to undergo electrochemical reaction in response to electrical potential applied to the electrode, where the said reaction is modified by the presence of the analyte. This sensor has the novel characteristic that at least one said electrochemically active species is encapsulated within polymer particles. These particles are preferably formed from an amorphous polymer with a glass transition temperature above the temperature of the fluid to which the sensor is exposed. The encapsulating polymer protects the analyte species from degradation, but a small analyte such as a hydrogen or bisulfide ion can pass through the polymer and undergo reaction at the active species.

Claims

1. A method of measuring an analyte concentration in a fluid which comprises

exposing an electrochemical sensor to the fluid, where the sensor comprises at least one electrode and at least one electrochemically active species able to undergo reversible electrochemical reduction and oxidation reaction in response to electrical potential applied to the electrode, said reaction being modified by the presence of an analyte species, and

applying varying potential to the sensor to bring about the reduction or oxidation reaction while observing current flow;

wherein the said electrochemically active species is encapsulated within separate polymer particles and analyte molecules pass through the separate polymer particles for the redox reaction to take place inside the encapsulation.

2. A method according to claim 1 wherein the encapsulating polymer has a glass transition temperature above the temperature of the fluid.

3. A method according to claim 1 wherein the sensor comprises a solid substrate to which at least one said encapsulated electrochemically active species is immobilized.

4. A method according to claim 3 wherein the substrate is electrically insulating and the encapsulated species is immobilized proximate to a said electrode.

5. A method according to claim 3 wherein a said electrode comprises an electrically conductive solid body and the encapsulated species is immobilized thereon.

6. A method according to claim 3 wherein the electrically conductive substrate comprises carbon.

7. A method according to claim 1 wherein the sensor comprises at least one further electrode which is electrically insulated from the first said electrode.

8. A method according to claim 1 wherein the polymer has a glass transition temperature above 80°

C.

9. A method according to claim 1 wherein the polymer has a glass transition temperature above 120°

C.

10. A method according to claim 1 wherein the electrochemically active species is/are one or more molecules capable of undergoing reversible oxidation and reduction reactions brought about through application of electrical potential to the electrodes.

11. A method according to claim 10 wherein an oxidation and or reduction reaction displays a potentiometric shift dependent on concentration of an analyte.

12. A method according to claim 11 wherein the analyte is hydrogen ion or bisulfide ion.

13. A method according to claim 10 comprising at least two encapsulated species capable of undergoing reversible oxidation and reduction reactions brought about through application of electrical potential to the electrodes, where a said oxidation and/or reduction reaction of one species displays a potentiometric shift dependent on concentration of an analyte and a said oxidation and/or reduction reaction of another species takes place at a potential which is independent of the concentration of that analyte.

14. A method according to claim 1 wherein the polymer particles comprise a multiplicity of islands of the electrochemically active species, distributed within a continuous matrix of the polymer.

15. A method according to claim 1 wherein the sensor comprises an insulating body, at least two electrodes supported by the body and electrically insulated from each other and at least one electrochemically active species able to undergo electrochemical reaction in response to electrical potential applied to the electrodes, said reaction being modified by the presence of an analyte species, wherein the polymer particles in which the at least one said electrochemically active species is encapsulated are immobilized relative to the insulating body.

16. A method according to claim 1 carried out at a location below ground.

17. A method according to claim 1 carried out downhole in a wellbore.

18. A method according to claim 1 wherein the polymer comprises benzene rings joined through sulfone groups.