Display element and method for producing the same

• US 9,379,351 B2
• Filed: 09/29/2006
• Issued: 06/28/2016
• Est. Priority Date: 09/24/2002
• Status: Expired due to Fees

• Current Assignee: Dai Nippon Printing Company Limited, Junji Kido
• Original Assignee: Dai Nippon Printing Company Limited, Junji Kido
• Inventors: Mori, Toshitaka, Oyagi, Yasuyuki, Kido, Junji
• Primary Examiner(s): VETERE, ROBERT A
• Application Number:
  US11/541,507
• Publication Number:
  US 20070048437A1
• Time in Patent Office: 3,560 Days
• Field of Search: 427/64, 427 66- 67
• US Class Current: 1/1
• CPC Class Codes: H10K 50/818 Reflective anodes, e.g. ITO combined with thick metallic layers
• CPC Class Codes: H10K 71/60 Forming conductive regions or layers, e.g. electrodes
• CPC Class Codes: H10K 85/10 Organic polymers or oligomers
• CPC Class Codes: H10K 85/111 comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
• CPC Class Codes: H10K 85/1135 Polyethylene dioxythiophene [PEDOT]; Derivatives thereof
• CPC Class Codes: H10K 85/151 Copolymers
• CPC Class Codes: H10K 85/324 comprising aluminium, e.g. Alq3
• CPC Class Codes: H10K 85/615 Polycyclic condensed aromatic hydrocarbons, e.g. anthracene
• CPC Class Codes: H10K 85/631 Amine compounds having at least two aryl rest on at least one amine-nitrogen atom, e.g. triphenylamine

Abstract

Disclosed are a production process of a display device, which can prevent the oxidation of a lower electrode and can maintain luminescence efficiency, high contract, and durability, and a display element. The display element comprises a first electrode, a luminescent layer, a second electrode, and a transparent substrate. The first electrode comprises a metal layer and a corrosion-resistant charge injection accelerating layer. The corrosion-resistant charge injection accelerating layer has been formed by subjecting a surface layer in the metal layer to plasma treatment using an oxygen atom-containing gas.

Claims

1. A process for producing a display element comprising the steps of:

forming a metal layer on a substrate;

forming an alloy layer on the metal layer to form a laminate comprising at least the metal layer and the alloy layer, wherein said alloy layer comprises an alloy selected from the group consisting of Cr—

Al—

Mn—

Si, Cr—

Mn—

C—

Si, Cr—

Ni—

C—

Mn, Cr—

Ni—

Mn—

Si, Cr—

Ni—

Mo—

Mn, Cr—

Ni—

Ti—

Mn, Cr—

Ni—

Ta—

Mn and Cr—

Ni—

Cu—

C;

performing patterning on the top of the laminate;

subjecting the surface of the alloy layer of the laminate to plasma treatment using an oxygen atom-containing gas to convert the surface of the alloy layer to a corrosion-resistant charge injection accelerating layer to form a first electrode comprising the metal layer and the corrosion-resistant charge injection accelerating layer, wherein said alloy layer comprising Cr-base alloy or Ni—

Cr-base alloy, and said metal layer comprising metals selected from the group consisting of chromium (Cr), nickel (Ni), tungsten (W), manganese (Mn), indium (In), tin (Sn), zinc (Zn), molybdenum (Mo), vanadium (V), titanium (Ti), tantalum (Ta), niobium (Nb) and a mixture thereof;

forming a luminescent layer on the corrosion-resistant charge injection accelerating layer;

wherein, the first electrode is an anode, and the second electrode is a cathode.

2. The process according to claim 1, wherein, after the formation of the corrosion-resistant charge injection accelerating layer, the luminescent layer is formed on the corrosion-resistant charge injection accelerating layer without cleaning the substrate.

3. The process according to claim 1, which further comprises the step of, after the formation of the corrosion-resistant charge injection accelerating layer, applying a liquid composition comprised of an electrically conductive polymer doped with an inorganic acid or an organic acid or a liquid composition comprising said electrically conductive polymer onto the corrosion-resistant charge injection accelerating layer.

4. The process according to claim 1, wherein, in forming the corrosion-resistant charge injection accelerating layer, the plasma treatment is controlled to regulate the thickness of the corrosion-resistant charge injection accelerating layer.

5. The process according to claim 1, wherein, the corrosion-resistant charge injection accelerating layer has a lower resistivity than the luminescent layer.