Optical sensor, especially for determining substance concentrations in aqueous solutions by means of a fluorescence measurement

• US 9,383,317 B2
• Filed: 08/21/2012
• Issued: 07/05/2016
• Est. Priority Date: 08/22/2011
• Status: Active Grant

• Current Assignee: Endress+Hauser Conducta GmbH+Company KG (Endress+Hauser AG)
• Original Assignee: Endress+Hauser Conducta GmbH+Company KG (Endress+Hauser AG)
• Inventors: Zeun, Hendrik, Michael, Ronny
• Primary Examiner(s): Warden, Jill
• Assistant Examiner(s): Krcha, Matthew
• Application Number:
  US13/590,420
• Publication Number:
  US 20130214175A1
• Time in Patent Office: 1,414 Days
• US Class Current: 1/1
• CPC Class Codes: G01D 5/34 the beams of light being detected by photocells
• CPC Class Codes: G01N 21/64 Fluorescence; Phosphorescence
• CPC Class Codes: G01N 21/6428 Measuring fluorescence of fluorescent products of reactions or of fluorochrome labelled reactive substances, e.g. measuring quenching effects, using measuring "optrodes" in vivo A61B5/00; immunoassay G01N33/53
• CPC Class Codes: G01N 21/8422 Investigating thin films, e.g. matrix isolation method

Abstract

An optical sensor, comprising a sensor head, which contains a sensitive element and which is adjoined by a housing, which contains sensor electronics, wherein the sensitive element is irradiated with light from an optical transmitter and a light characteristic radiated back by the sensitive element is detected by an optical receiver and evaluated by the sensor electronics. The sensor head and the housing are embodied to be separable, wherein different sensor heads having different sensitive elements are connectable to the housing containing the sensor electronics and the sensor electronics evaluates the light characteristics generated by the different sensitive elements.

Claims

1. A method for determining substance concentrations in aqueous solutions by means of a fluorescence measurement with an optical sensor, the sensor comprising:

a housing;

sensor electronics;

an optical transmitter;

an optical receiver; and

a sensor head, which contains a sensitive element and which is adjoined by said housing, said housing containing said sensor electronics; and

wherein said sensor head and said housing are separable, wherein different sensor heads having different sensitive elements are connectable to said housing containing said sensor electronics;

the method comprising the steps of;

irradiating said sensitive element with light from said optical transmitter, wherein said sensor electronics excites said optical transmitter;

radiating back a light characteristic by said sensitive element;

detecting said back-radiated light characteristic by said optical receiver;

forwarding said back-radiated light characteristic from said optical receiver to said sensor electronics;

evaluating said back-radiated light characteristic by said sensor electronics, wherein said light characteristics are generated by said different sensitive elements; and

recognizing said sensitive element in said sensor head automatically by said sensor electronics by comparing said back-radiated light characteristic with stored measurement data and/or characteristic lines for recognizing said sensitive element.

2. The method as claimed in claim 1, wherein:

the stored measurement data comprise light intensities and/or light frequencies and the characteristic lines comprise the decay curves of the light intensity of the back-radiated light characteristic.

3. The method as claimed in claim 1, wherein:

said sensor electronics has an electrical current source.

4. The method as claimed in claim 1, wherein:

said sensor head and said housing are optically and mechanically connected to one another via a standard interface.

5. The method as claimed in claim 1, wherein:

said sensor head is cap-like.

6. The method as claimed in claim 5, wherein:

said cap-like sensor head or said housing has a sealing element, which seals off said standard interface from the environment.

7. The method as claimed in claim 1, wherein:

said sensitive element is a sensitive layer.

8. The method as claimed in claim 1, wherein:

said housing contains an optical transmitter and an optical receiver, which are connected to said sensor electronics; and

said sensor electronics has a memory containing said measurement data and/or characteristic lines of the light characteristics of the different sensitive elements.

9. The method as claimed in claim 2, wherein:

said light characteristics stored in the memory serve as reference patterns.

10. The method as claimed in claim 1, further comprising the step:

calibrating or initializing by activating the optical transmitter by said sensor electronics, wherein said optical transmitter radiates light on the sensitive element.

11. The method as claimed in claim 1, further comprising the step:

feeding the back-radiated light characteristic to the sensor electronics, which automatically detects the measurement parameter to be determined, and

selecting by said sensor electronics an evaluating method which corresponds to a determined measurement parameter and with which following concentration measurement methods are executed.

12. The method as claimed in claim 7, wherein:

said sensitive layer detects oxygen, hydrogen, chlorine, or pH value.