Dynamic load-absorbing material and articles

• US 9,394,959 B2
• Filed: 03/08/2014
• Issued: 07/19/2016
• Est. Priority Date: 09/09/2011
• Status: Active Grant

• Current Assignee: Purdue Research Foundation (Purdue University)
• Original Assignee: Purdue Research Foundation (Purdue University)
• Inventors: Nauman, Eric Allen, Breedlove, Evan Louis, Zakrajsek, Anne Dye, Lynch, Eric S.
• Primary Examiner(s): Cain, Edward
• Application Number:
  US14/201,820
• Publication Number:
  US 20140196998A1
• Time in Patent Office: 864 Days
• Field of Search: 188/377, 264/334
• US Class Current: 1/1
• CPC Class Codes: A41D 13/015 with shock-absorbing means A41D13/05 takes precedence
• CPC Class Codes: A42B 3/12 Cushioning devices
• CPC Class Codes: C08J 2201/026 Crosslinking before of after foaming
• CPC Class Codes: C08J 2383/04 Polysiloxanes
• CPC Class Codes: C08J 9/0066 Use of inorganic compounding ingredients
• CPC Class Codes: C08K 3/04 Carbon
• CPC Class Codes: C08L 83/04 Polysiloxanes
• CPC Class Codes: F16F 7/12 using plastic deformation of members F16F9/30 takes precedence; yieldable means for mounting bumpers on vehicles B60R19/26; yieldable or collapsible steering columns B62D1/192
• CPC Class Codes: F41H 5/0492 Layered armour containing hard elements, e.g. plates, spheres, rods, separated from each other, the elements being connected to a further flexible layer or being embedded in a plastics or an elastomer matrix

Abstract

Dynamic load-absorbing materials suitable for use as cushion-type and armor-type materials, for example, of types that can be incorporated into protective gear, equipment, armor, vehicles, and various other structures, or used for the isolation and dissipation of vibratory loads, such as vibration isolators used to support avionic equipment. The impact-absorbing materials include a matrix material (22) and at least first and second sets of inclusions (which can be either included material or voids) (24) in the matrix material (22) that define a hierarchy of inclusions (24) in the matrix material (22). The inclusions (24) differ in size, quantity, shape and/or composition in a direction through the impact-absorbing material, the combination of which contributes to the ability of the material to exhibit at least one property that changes as the inclusions (24) are deformed under load.

Claims

1. A composite material for protection of an object from a load, comprising:

a matrix material including at least three sizes of stress-concentrating features, including;

a plurality of first features having a first average characteristic dimension of between about ten microns and about two hundred microns;

a plurality of second features having a second average characteristic dimension that is at least about one order of magnitude larger than said first average characteristic dimension; and

a plurality of third features having a third average characteristic dimension that is at least about one order of magnitude larger than said second average characteristic dimension;

wherein the material proximate to said first, second, and third features progressively buckles upon application of the load, such that material proximate said third features tends to deform before the deformation of material proximate to said second and first features, and material proximate said first features tends to deform after the deformation of material proximate to said second and third features.

2. The composite material of claim 1 wherein the deformation of said material proximate to said third features is substantially elastic buckling response.

3. The composite material of claim 1 wherein the deformation of said material proximate to said third features is substantially inelastic.

4. The composite material of claim 1 wherein said second features are voids in said matrix material.

5. The composite material of claim 1 wherein said first features are graphite flakes.

6. The composite material of claim 1 wherein said third features are pockets molded into the material.

7. The composite material of claim 1 wherein the ratio of the third average dimension to the second average dimension is greater than about seven.

8. The composite material of claim 1 wherein the ratio of the second average dimension to the first average dimension is greater than about seven.

9. The composite material of claim 1 wherein said matrix material is an elastomer.

10. A method of making an impact-mitigating material for a helmet, comprising:

providing a compound that is curable to form a polymer;

providing a mold cavity having an internal height adapted and configured to produce cured silicone of a thickness suitable for use in a helmet;

placing the compound in the mold cavity;

curing the compound for at least about five minutes;

exposing the mixture in the mold cavity to pressure less than ambient pressure; and

removing the substantially polymerized material from the mold and placing the material in the interior of a helmet.

11. The method of claim 10 wherein the thickness of the cured silicone is less than about three centimeters.

12. The method of claim 10 wherein the compound is a first compound, and which further comprises adding a second compound to the first compound so that the silicone polymer has a Shore A hardness of less than about 40.

13. The method of claim 10 wherein said mold cavity has surface features which are at least partially spherical.

14. An impact-absorbing material (20, 120, 220, 320) comprising:

a matrix material (22); and

at least first and second sets of inclusions (24) in the matrix material (22) that define a hierarchy of inclusions (24) in the matrix material (22) that differ in size, quantity, shape and/or composition in a direction through the impact-absorbing material (20), wherein the hierarchy of inclusions (24) yield a synergistic relationship between the inclusions (24) and the matrix material (22), the combination of which contributes to the ability of the impact-absorbing material (20, 120, 220, 320) to exhibit at least one property that changes as the inclusions (24) are deformed under load.

15. The impact-absorbing material (20, 120, 220, 320) according to claim 14, wherein the first and second sets of inclusions (24) are within first and second tier regions (26, 28), respectively, of the impact-absorbing material (20, 120, 220, 320).

16. The impact-absorbing material (20, 120, 220, 320) according to claim 15, wherein the first and second sets of inclusions (24) are uniformly dispersed in the first and second tier regions (26, 28), respectively.

17. The impact-absorbing material (20, 120, 220, 320) according to claim 15, wherein the first and second sets of inclusions (24) comprise first and second sets of voids (24), respectively, in the first and second tier regions (26, 28), respectively.

18. The impact-absorbing material (20, 120, 220, 320) according to claim 15, wherein the first and second sets of inclusions (24) comprise first and second sets of solids (24), respectively, in the first and second tier regions (26, 28), respectively.

19. The impact-absorbing material (20, 120, 220, 320) according to claim 18, wherein the first and second sets of solids (24) are formed of first and second materials, respectively, and the second material is stiffer than the first material.