Organic electroluminescent devices

• US 9,397,309 B2
• Filed: 03/13/2015
• Issued: 07/19/2016
• Est. Priority Date: 03/13/2014
• Status: Active Grant

• Current Assignee: Universal Display Corporation
• Original Assignee: Universal Display Corporation
• Inventors: Premutico, Mauro, Xia, Chuanjun, Lin, Chun
• Primary Examiner(s): HENRY, CALEB E
• Application Number:
  US14/657,779
• Publication Number:
  US 20150263305A1
• Time in Patent Office: 494 Days
• Field of Search: 257/40, 257/E51.018, 257/E51.001, 438/46
• US Class Current: 1/1
• CPC Class Codes: H10K 2101/10 Triplet emission
• CPC Class Codes: H10K 2101/80 Composition varying spatially, e.g. having a spatial gradient
• CPC Class Codes: H10K 50/11 characterised by the electroluminescent [EL] layers
• CPC Class Codes: H10K 50/12 comprising dopants
• CPC Class Codes: H10K 85/342 comprising iridium
• CPC Class Codes: H10K 85/346 comprising platinum

Abstract

An OLED having an organic layer formed of a dopant and a host, where the organic layer is disposed between an anode and a cathode is disclosed. The dopant'"'"'s concentration level in the organic layer, along a direction perpendicular to the first and second planar surfaces of the organic layer, defines a novel concentration gradient that enhances the OLED'"'"'s efficiency.

Claims

1. A device comprising one or more organic light emitting devices, at least one of the organic light emitting devices comprising:

an anode;

a cathode that is parallel to the anode; and

a first organic layer disposed between the anode and the cathode and having a first planar surface and a second planar surface that are parallel to the anode and the cathode and defining a perpendicular distance L, representing the thickness of the first organic layer, between the first planar surface and the second planar surface, wherein the anode is closer to the first planar surface than the second planar surface;

wherein the first organic layer comprises a dopant material and a host material;

wherein the dopant material has a concentration level in the first organic layer that is between 0.1 to 90 wt. % and is generally constant throughout the first organic layer along a direction parallel to the first and second planar surfaces;

wherein the dopant material'"'"'s concentration level in the first organic layer along a direction perpendicular to the first and second planar surfaces, is not generally constant and defines a first concentration gradient along the direction perpendicular to the first and second planar surfaces;

wherein the first concentration gradient has a first concentration level C₁ within a distance of no more than 0.1 L from the first planar surface, a second concentration level C₂ within a distance of no more than 0.1 L from the second planar surface, and a third concentration level C₃ at a distance less than 0.5 L but greater than 0.1 L from the first planar surface, wherein the third concentration level C₃ is greater than the first concentration level C₁ and the second concentration level C₂.

2. The device of claim 1, wherein the first concentration level C₁ can be equal to or different from the second concentration level C₂.

3. The device of claim 1, wherein the third concentration level C₃ is a first maximum concentration level.

4. The device of claim 3, wherein the first concentration gradient has a fourth concentration level C₄ at a distance less than 0.5 L but greater than 0.1 L from the second planar surface, wherein the fourth concentration level C₄ is a second maximum concentration level.

5. The device of claim 1, wherein the first organic layer is a light emitting layer, and the dopant material is a light emitting material.

6. The device of claim 1, wherein the first organic layer is a non-light emitting layer.

7. The device of claim 1, wherein the first organic layer further comprises a second dopant material that has a concentration level in the first organic layer that is between 0.1 to 90 wt. % and is generally constant throughout the first organic layer along a direction parallel to the first and second planar surfaces;

wherein the second dopant material'"'"'s concentration level in the first organic layer along a direction perpendicular to the first and second planar surfaces, is not generally constant and defines a second concentration gradient along the direction perpendicular to the first and second planar surfaces.

8. A device comprising one or more organic light emitting devices, at least one of the organic light emitting devices comprising:

an anode;

a cathode that is parallel to the anode; and

a first organic layer disposed between the anode and the cathode and having a first planar surface and a second planar surface that are parallel to the anode and the cathode and having a perpendicular distance L between the first planar surface and the second planar surface, wherein the anode is closer to the first planar surface than the second planar surface;

wherein the first organic layer comprises a dopant material and a host material;

wherein the dopant material has a concentration level in the first organic layer that is between 0.1 to 90 wt. % and is generally constant throughout the first organic layer along a direction parallel to the first and second planar surfaces;

wherein the dopant material'"'"'s concentration level in the first organic layer along a direction perpendicular to the first and second planar surfaces, is not generally constant and defines a first concentration gradient along the direction perpendicular to the first and second planar surfaces;

wherein the first concentration gradient has a first concentration level C₁ within a distance no more than 0.1 L from the first planar surface, a second concentration level C₂ within a distance 0.1 L from the second planar surface; and

a third concentration level at a distance less than 0.5 L but greater than 0.1 L from the first planar surface, wherein the third concentration level C₃ is lower than the first concentration level C₁ and the second concentration level C₂.

9. The device of claim 8, wherein the first concentration level C₁ can be equal to or different from the second concentration level C₂.

10. The device of claim 8, wherein the third concentration level C₃ is a first minimum concentration level.

11. The device of claim 8, wherein the first concentration gradient has a fourth concentration level C₄ that is a second minimum concentration level.

12. The device of claim 8, wherein the first concentration gradient has a fourth concentration level C₄ that is greater than the first concentration level C₁ and the second concentration level C₂.

13. The device of claim 8, wherein the first organic layer is a non-light emitting layer or a light emitting layer wherein the dopant material is a light emitting material.

14. The device of claim 8, wherein the first organic layer further comprises a second dopant material that has a concentration level in the first organic layer that is between 0.1 to 90 wt. % and is generally constant throughout the first organic layer along a direction parallel to the first and second planar surfaces;

wherein the second dopant material has a concentration level in the first organic layer along a direction perpendicular to the first and second planar surfaces, that is not generally constant and defines a second concentration gradient along the direction perpendicular to the first and second planar surfaces.

15. A device comprising one or more organic light emitting devices, at least one of the organic light emitting devices comprising:

an anode;

a cathode that is parallel to the anode; and

a first organic layer disposed between the anode and the cathode and having a first planar surface and a second planar surface that are parallel to the anode and the cathode and having a perpendicular distance L between the first planar surface and the second planar surface, wherein the anode is closer to the first planar surface than the second planar surface;

wherein the first organic layer comprises a dopant material and a host material;

wherein the dopant material has a concentration level in the first organic layer that is between 0.1 to 90 wt. % and is generally constant throughout the first organic layer along a direction parallel to the first and second planar surfaces;

wherein the dopant material'"'"'s concentration level in the first organic layer, along a direction perpendicular to the first and second planar surfaces, is not generally constant and defines a first concentration gradient along the direction perpendicular to the first and second planar surfaces;

wherein the first concentration gradient has a first concentration level C₁ within a distance of no more than 0.1 L from the first planar surface, a second concentration level C₂ within a distance of no more than 0.1 L from the second planar surface, and a third concentration level C₃ that is greater than the first concentration level C₁ and the second concentration level C₂;

wherein the first concentration level C₁ is greater than or equal to the second concentration level C₂.

16. The device of claim 15, wherein the third concentration level C₃ is at a distance greater than 0.5 L from the first surface.

17. The device of claim 15, wherein the third concentration level C₃ is a first maximum concentration.

18. The device of claim 15, wherein the first material has a fourth concentration level C₄ wherein the fourth concentration level C₄ is a second maximum concentration.

19. The device of claim 15, wherein the organic layer is either a non-light emitting layer or a light emitting layer wherein the first material is a light emitting material.

20. The device of claim 15, wherein the first organic layer further comprises a second dopant material that has a concentration level in the first organic layer that is between 0.1 to 90 wt. % and is generally constant throughout the first organic layer along a direction parallel to the first and second planar surfaces;

wherein the second dopant material'"'"'s concentration level in the first organic layer along a direction perpendicular to the first and second planar surfaces, is not generally constant and defines a second concentration gradient along the direction perpendicular to the first and second planar surfaces.