Fuel cell assembly having feed-back sensor

• US 9,401,522 B2
• Filed: 10/20/2014
• Issued: 07/26/2016
• Est. Priority Date: 08/20/2007
• Status: Active Grant

• Current Assignee: Fuel Cell Technology Sweden AB
• Original Assignee: MyFC AB (myFC Holding AB)
• Inventors: Lundblad, Anders, Ekstrom, Henrik, Jonsson, Eric
• Primary Examiner(s): Ruddock, Ula C
• Assistant Examiner(s): AMPONSAH, OSEI K
• Application Number:
  US14/518,662
• Publication Number:
  US 20150037699A1
• Time in Patent Office: 645 Days
• US Class Current: 1/1
• CPC Class Codes: H01M 2008/1095 Fuel cells with polymeric electrolytes
• CPC Class Codes: H01M 2250/30 Fuel cells in portable systems, e.g. mobile phone, laptop
• CPC Class Codes: H01M 8/04089 of gaseous reactants
• CPC Class Codes: H01M 8/04223 during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
• CPC Class Codes: H01M 8/04225 during start-up
• CPC Class Codes: H01M 8/04302 applied during start-up
• CPC Class Codes: H01M 8/04552 of the individual fuel cell
• CPC Class Codes: H01M 8/04559 of fuel cell stacks
• CPC Class Codes: H01M 8/04567 of auxiliary devices, e.g. batteries, capacitors
• CPC Class Codes: H01M 8/04753 of fuel cell reactants
• CPC Class Codes: H01M 8/04798 of fuel cell reactants
• CPC Class Codes: H01M 8/0494 of fuel cell stacks
• CPC Class Codes: H01M 8/04955 Shut-off or shut-down of fuel cells
• CPC Class Codes: H01M 8/1097 Fuel cells applied on a support, e.g. miniature fuel cells deposited on silica supports
• CPC Class Codes: H01M 8/241 with solid or matrix-supported electrolytes
• CPC Class Codes: Y02B 90/10 Applications of fuel cells in buildings
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A sensor cell (1010) for control purposes usable in an assembly (1000) of fuel cells of the type having a membrane electrode assembly (MEA) interposed between an anode gas diffusion layer and a cathode gas diffusion layer, and first and second current collectors coupled to the anode and cathode gas diffusion layers (GDL), respectively. The sensor cell (1010) is preferably coupled so that it shares the negative current collector (1050) with last fuel cell in the in-plane fuel cell assembly (1000), and is short-circuited by a resistor (1070) to provide a voltage signal, indicative of the status of the assembly in operation.

Claims

1. A fuel cell assembly, comprising:

a gas feed;

a support plate;

a negative current collector; and

a plurality of fuel cells arranged in an in-plane configuration on the support plate, the plurality of fuel cells comprising at least one power generating fuel cell and a sensor fuel cell,

wherein the plurality of fuel cells are connected to the gas feed,

wherein a last power generating fuel cell includes a hydrogen gas outlet providing residual fuel therefrom,

wherein a portion of the negative current collector extends between the last power generating fuel cell and the hydrogen sensor,

wherein said sensor fuel cell comprises a GDL/MEA/GDL stack made up of an anode GDL, a cathode GDL, and a MEA interposed between said anode and cathode GDLs,

wherein said sensor fuel cell is located at the hydrogen gas outlet of the last power generating fuel cell so as to receive fuel from the residual fuel provided from said hydrogen gas outlet, and

wherein said sensor fuel cell is coupled to electrically share the portion of the negative current collector, that extends between the last power generating fuel cell and the sensor fuel cell, with said last power generating fuel cell; and

a resistor (R) connecting the anode and the cathode of the sensor fuel cell, wherein said sensor fuel cell has a voltage.

2. The fuel cell assembly as claimed in claim 1, wherein all elements of the sensor fuel cell are provided on the support plate and all elements of the power generating fuel cell(s) are provided on the support plate.

3. The fuel cell assembly as claimed in claim 1, wherein the sensor fuel cell is coupled in series with the power generating fuel cell(s) with respect to a supply of hydrogen.

4. The fuel cell assembly as claimed in claim 1, further comprising a hydrogen supply, wherein,

the assembly includes a plurality of the power generating fuel cells arranged in the in-plane configuration on the support plate,

all elements of the sensor fuel cell are provided on the support plate and all elements of the power generating fuel cells are provided on the support plate, and

the sensor fuel cell is coupled in series with the power generating fuel cells with respect to the supply of the hydrogen.

5. The fuel cell assembly as claimed in claim 1, wherein,

the gas feed provides a hydrogen supply,

the hydrogen supply has a max-flow limit, and

the sensor fuel cell is configured to indicate when a power draw is larger than the max-flow limit of the hydrogen supply.

6. The fuel cell assembly as claimed in claim 1, adapted to consume 1-5% of the gas feed.

7. The fuel cell assembly as claimed in claim 1, wherein the resistor is dimensioned as follows for a sensor fuel cell having a working voltage of Uwork:

R=Uwork/Ireg/

wherein

Ireg=Egas×

Inom×

N

and

Egas is excess gas supplied to the sensor fuel cell, Ireg is a current through the sensor fuel cell for an assembly of N cells having a nominal current of Inom.

8. The fuel cell assembly as claimed in claim 1, wherein the resistor has a resistance of 0.5-2 Ohms.

9. The fuel cell assembly as claimed in claim 1, wherein the resistor has a resistance of 0.75-1.25 Ohms.

10. The fuel cell assembly as claimed claim 1, wherein the sensor fuel cell is smaller than the power generating fuel cell(s).

11. The fuel cell assembly as claimed claim 1, wherein the negative current collector extends from the last power generating fuel cell further on the support plate to the sensor fuel cell, and both the last fuel cell and the sensor fuel cell are located on said negative current collector with both the anode GDL of the sensor fuel cell and an anode GDL of the last fuel cell in contact with the negative current collector.

12. The fuel cell assembly as claimed in claim 1, further comprising a control unit operatively connected to the plurality of fuel cells and adapted to regulate the supply of hydrogen to the assembly in response to the voltage of the sensor fuel cell.

13. The fuel cell assembly as claimed in claim 1, further comprising a control unit operatively connected to the plurality of fuel cells and adapted to regulate a power draw from the assembly in response to the voltage of the sensor fuel cell.

14. The fuel cell assembly as claimed in claim 1, further comprising a spacer frame that clamps the MEA to the support plate and seals off the GDL/MEA/GDL stack.

15. The fuel cell assembly as claimed in claim 1 connected to an electrical device.

16. The fuel cell assembly as claimed in claim 1 connected to an electronic apparatus, wherein the fuel cell assembly is a power source for the electronic apparatus.

17. A fuel cell assembly, comprising:

a hydrogen feed with a max-flow limit;

a support plate;

a negative current collector; and

a plurality of fuel cells arranged in an in-plane configuration on the support plate and connected to the hydrogen feed, the plurality of fuel cells comprising plural series-connected power generating fuel cells and a sensor

fuel cell,

wherein a last of the power generating fuel cells includes a hydrogen outlet providing residual fuel therefrom,

wherein a portion of the negative current collector extends between the last power generating fuel cell and the hydrogen sensor,

wherein said sensor fuel cell comprises a GDL/MEA/GDL stack made up of an anode GDL, a cathode GDL, and a MEA interposed between said anode and cathode GDLs,

wherein said sensor fuel cell is located at the hydrogen outlet of the last power generating fuel cell and receives fuel from the residual fuel provided from said hydrogen outlet, and

wherein said sensor fuel cell is coupled to electrically share the portion of the negative current collector, that extends between the last power generating fuel cell and the sensor fuel cell, with said last power generating fuel cell; and

a resistor (R) having a resistance of 0.5-2 Ohms and connecting the anode and the cathode of the sensor fuel cell, wherein said sensor fuel cell has a voltage,

wherein the sensor fuel cell is configured to indicate when a power draw is larger than the max-flow limit of the hydrogen source; and

a control unit operatively connected to the plurality of fuel cells and adapted to regulate at least one of the group consisting of i) the supply of hydrogen to the assembly in response to the voltage of the sensor fuel cell, and ii) a power draw from the assembly in response to the voltage of the sensor fuel cell,

wherein the plurality of fuel cells are connected to an electronic apparatus as a power source for the electronic apparatus.

18. The fuel cell assembly as claimed claim 17, wherein the sensor fuel cell is smaller than the power generating fuel cell(s).

19. A fuel cell assembly, comprising:

a hydrogen feed with a max-flow limit;

a support plate;

a negative current collector; and

a plurality of fuel cells arranged in an in-plane configuration on the support plate and connected to the hydrogen feed, the plurality of fuel cells comprising plural power generating fuel cells and a sensor fuel cell;

wherein a last of the power generating fuel cells includes a hydrogen outlet providing residual fuel therefrom,

wherein a portion of the negative current collector extends between the last power generating fuel cell and the hydrogen sensor,

wherein said sensor fuel cell receives fuel from the residual fuel provided from said hydrogen outlet,

wherein said sensor fuel cell comprises a GDL/MEA/GDL stack made up of an anode GDL, a cathode GDL, and a MEA interposed between said anode and cathode GDLs;

a negative current collector that extends from the last power generating fuel cell further on the support plate with the anode GDL of the sensor fuel cell in contact with the negative current collector, said sensor fuel cell being coupled to electrically share the portion of the negative current collector, that extends between the last power generating fuel cell and the sensor fuel cell, with said last power generating fuel cell; and

a resistor (R) having a resistance of 0.5-2 Ohms and connecting the anode and the cathode of the sensor fuel cell, wherein said sensor fuel cell has a voltage,

wherein the sensor fuel cell is configured to indicate when a power draw is larger than the max-flow limit of the hydrogen source; and

a control unit operatively connected to the plurality of fuel cells and adapted to regulate at least one of the group consisting of i) the supply of hydrogen to the assembly in response to the voltage of the sensor fuel cell, and ii) a power draw from the assembly in response to the voltage of the sensor fuel cell,

wherein the plurality of fuel cells are connected to an electronic apparatus as a power source for the electronic apparatus.

20. The fuel cell assembly as claimed claim 19, wherein the sensor fuel cell is smaller than the power generating fuel cell(s).