Hydrogen generator and product conditioning method

• US 9,403,679 B2
• Filed: 07/11/2014
• Issued: 08/02/2016
• Est. Priority Date: 07/23/2009
• Status: Expired due to Fees

• Current Assignee: Intelligent Energy Limited (Lb-shell Plc)
• Original Assignee: Intelligent Energy Limited (Lb-shell Plc)
• Inventors: Braithwaite, Daniel, JONEMANN, Matthieu, Fabian, Tibor
• Primary Examiner(s): Merkling, Matthew
• Application Number:
  US14/329,454
• Publication Number:
  US 20140369923A1
• Time in Patent Office: 753 Days
• Field of Search: 48/61
• US Class Current: 1/1
• CPC Class Codes: C01B 2203/0272 containing a non-catalytic decomposition step
• CPC Class Codes: C01B 2203/0405 Purification by membrane separation
• CPC Class Codes: C01B 2203/12 Feeding the process for making hydrogen or synthesis gas
• CPC Class Codes: C01B 3/065 from a hydride
• CPC Class Codes: Y02E 60/36 Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Abstract

A hydrogen generator that includes a solid fuel mixture, a liquid reactant, a liquid delivery medium (LDM), a movable boundary interface (MBI), a reaction zone, wherein the MBI provides constant contact between a reacting surface of the solid fuel mixture and the liquid reactant delivered by the LDM to form the reaction zone, and a product separation media, fluidly coupled to the reaction zone by a fluid junction, that degasses a product. The hydrogen generator may further include auxiliary LDMs disposed throughout the hydrogen generator, wherein said auxiliary LDMs may be operated based on a ratio of the liquid reactant flow rate to the hydrogen generation rate.

Claims

1. A method for conditioning hydrogen generated using a hydrogen generator, said hydrogen generator comprising a solid fuel mixture, a liquid reactant, a first liquid delivery mechanism (LDM), a reaction zone wherein the solid fuel mixture reacts with the liquid reactant that is delivered by the LDM, and a product separation media fluidly coupled to the reaction zone by a fluid junction that degasses a product stream;

wherein the product separation media comprises of porous foam and the pore size of the product separation media decreases with increasing distance from the fluid junction the method comprising the steps of;

determining a liquid reactant flow rate;

determining a product generation rate;

adjusting the liquid reactant flow rate electrically based on a ratio of the liquid reactant flow rate to the product generation rate; and

passing the product stream through the product separation media.

2. The method of claim 1, wherein adjusting the liquid reactant flow rate comprises initiating liquid reactant delivery to the fluid junction.

3. The method of claim 2, wherein the liquid reactant is delivered with a second LDM.

4. The method of claim 1, wherein the hydrogen generator further includes a pumping mechanism that pumps the liquid reactant to the LDM at a pump rate, wherein determining the liquid reactant flow rate comprises determining the pump rate.

5. The method of claim 4, wherein determining the product generation rate comprises determining a current output.

6. The method of claim 5, wherein adjusting the liquid reactant flow rate comprises signaling for liquid reactant delivery to the hydrogen generator through a second LDM.

7. The method of claim 6, wherein the liquid reactant is delivered to the fluid junction.

8. The method of claim 1, wherein the product generation rate is the hydrogen generation rate.

9. The method of claim 1, wherein the product generation rate is determined before the liquid reactant flow rate is determined.

10. The method of claim 3 wherein the liquid reactant flow rate to the first LDM is determined from the overall product generation rate, and the liquid reactant flow rate to the second LDM is determined from the ratio of the overall liquid reactant flow rate to the product generation rate.

11. The method of claim 1, wherein the product separation media further comprises a hydrogen separator.

12. The method of claim 11, wherein the hydrogen separator comprises of ePTFE.

13. The method of claim 11, wherein the porous foam is disposed between the fluid junction and the hydrogen separator.

14. The method of claim 1, wherein the product separation media further comprises a fibrous filter.

15. The method of claim 14, wherein the fibrous filter is disposed between the porous foam and the hydrogen separator.

16. The method of claim 15, wherein the fibrous filter and the porous foam are disposed around the hydrogen separator such that the hydrogen separator is substantially enclosed by the fibrous filter and the porous foam.

17. The method of claim 1, wherein the porous foam is hydrophobic and the fibrous filter is hydrophilic.

18. The method of claim 14, wherein the porous foam comprises of nylon foam, the fibrous filter comprises of acrylic yarn, and the hydrogen separator comprises of ePTFE.

19. The method of claim 1, wherein the solid fuel mixture comprises of solid sodium borohydride.

20. The method of claim 1, wherein the liquid fuel reactant comprises of water.

21. A method for conditioning hydrogen generated using a hydrogen generator, said hydrogen generator comprising a solid fuel mixture, a liquid reactant, a liquid delivery mechanism (LDM), a movable boundary interface (MBI), wherein the MBI provides constant contact between a reacting surface of the solid fuel mixture and the liquid reactant delivered by the LDM to form the reaction zone wherein the solid fuel mixture reacts with the liquid reactant, and a product separation media fluidly coupled to the reaction zone by a fluid junction that degasses a product stream, wherein the MBI comprises of an elastic membrane disposed about the solid fuel mixture;

the method comprising the steps of;

determining a liquid reactant flow rate;

determining a product generation rate;

adjusting the liquid reactant flow rate electrically based on a ratio of the liquid reactant flow rate to the product generation rate; and

passing the product stream through the product separation media.