Method for increasing mechanical strength of titanium alloys having α″ phase by cold working

• US 9,404,170 B2
• Filed: 12/06/2012
• Issued: 08/02/2016
• Est. Priority Date: 12/06/2011
• Status: Active Grant

• Current Assignee: National Cheng KUNG University (Government of The Republic of China)
• Original Assignee: National Cheng KUNG University (Government of The Republic of China)
• Inventors: Ju, Chien-Ping, Lin, Jiin-Huey Chern
• Primary Examiner(s): Self, Shelley
• Assistant Examiner(s): Iannuzzi, Peter
• Application Number:
  US13/706,386
• Publication Number:
  US 20130139564A1
• Time in Patent Office: 1,335 Days
• Field of Search: 72/75, 723/77, 723/78, 72199-2525, 72352-360, 72274-292
• US Class Current: 1/1
• CPC Class Codes: C22C 14/00 Alloys based on titanium
• CPC Class Codes: C22F 1/183 of titanium or alloys based thereon

Abstract

A process for making an article of a titanium alloy having α″ phase as a major phase according to the present invention includes providing a work piece of a titanium alloy consisting essentially of 7-9 wt % of molybdenum and the balance titanium and having α″ phase as a major phase; and cold working at least a portion of the work piece at room temperature to obtain a green body of the article, wherein the cold worked portion of the green body has a thickness which is 20%-80% of that of the at least a portion of the work piece, and the cold worked portion has α″ phase as a major phase.

Claims

1. A process for making an article of a titanium alloy having α

″

phase as a major phase comprising the following steps;

a) providing a work piece of a titanium-molybdenum alloy having α

″

phase as a major phase; and

b) cold working at least a portion of said work piece at room temperature once or repeatedly to obtain a green body of said article, wherein the resultant cold worked portion of said green body has an average thickness which is 10%-90% of an average thickness of before cold working said at least a portion of said work piece, and the cold worked portion has α

″

phase as a major phase,

wherein said cold working in step b) is either carried out once and the resultant cold worked portion of said green body has an average thickness which is 50%-90% of an average thickness of said at least a portion of said work piece;

or

said cold working in step b) is carried out repeatedly and each time of said repeated cold working results in a reduction of an average thickness of the cold worked portion being less than about 40% wherein the titanium-molybdenum alloy in step a) consists essentially of about 7.5 wt % of molybdenum and the balance titanium; and

wherein said cold worked portion resulted from step b) has α

″

phase as a major phase and α

′

phase as a minor phase.

2. The process of claim 1, wherein said cold working in step b) is carried out once and the resultant cold worked portion of said green body has an average thickness which is 50%-90% of an average thickness of said at least a portion of said work piece.

3. The process of claim 1, wherein said cold working in step b) is carried out repeatedly and each time of said repeated cold working results in a reduction of an average thickness of the cold worked portion being less than about 40%.

4. The process of claim 1, wherein the cold worked portion of said green body resulted from step b) has an average thickness which is 35% to 65% of an average thickness of said at least a portion of said work piece.

5. The process of claim 4, wherein the cold worked portion of said green body resulted from step b) has an average thickness which is about 50% of an average thickness of said at least a portion of said work piece.

6. The process of claim 1, wherein the cold working in step b) comprises rolling, drawing, extrusion or forging.

7. The process of claim 1, wherein the work piece in step a) is an as-cast work piece.

8. The process of claim 1, wherein the work piece in step a) is a work piece being hot-worked, solution-treated, or a hot-worked and solution-treated work piece to a temperature of 900°

C.-1200°

C., followed by water quenching.

9. The process of claim 1, wherein the article is a medical implant, and the green body in step b) is a green body of the medical implant which requires further machining.

10. The process of claim 9, wherein the medical implant is a bone plate, bone screw, bone fixation connection rod, intervertebral disc, femoral implant, hip implant, knee prosthesis implant, or a dental implant.

11. The process of claim 1 further comprising aging said green body resulted from step b), so that yield strength of said aged green body is increased by at least 10%, based on the yield strength of said green body, with elongation to failure of said aged green body being not less than about 5.0%.

12. The process of claim 11 wherein said aging is carried out at 150-250°

C. for a period of about 7.0 to 30 minutes.