Cartridge for controlled production of hydrogen

• US 9,409,772 B2
• Filed: 04/22/2014
• Issued: 08/09/2016
• Est. Priority Date: 07/23/2009
• Status: Active Grant

• Current Assignee: Intelligent Energy Limited (Lb-shell Plc)
• Original Assignee: Intelligent Energy Limited (Lb-shell Plc)
• Inventors: Braithwaite, Daniel, Ryu, WonHyoung, Helland, Courtney Aline, Yamamoto, Kei E, Peterson, Andrew Philip, JONEMANN, Matthieu, Rodriguez, Adam Naegeli, Parisi-Amon, Gabriel Jose
• Primary Examiner(s): Merkling, Matthew
• Application Number:
  US14/259,048
• Publication Number:
  US 20140227170A1
• Time in Patent Office: 840 Days
• US Class Current: 1/1
• CPC Class Codes: C01B 3/02 Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
• CPC Class Codes: C01B 3/065 from a hydride
• CPC Class Codes: Y02E 60/36 Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Abstract

A reaction hydrogen production control mechanism is provided that includes, a solid sodium borohydride mixture, a liquid fuel reactant, at least one liquid delivery medium (LDM), a movable boundary interface (MBI) and a reaction zone, where the MBI is disposed to provide a constant contact between a reacting surface of the solid fuel mixture and the primary LDM to form the reaction zone. A reaction in the reaction zone includes a hydrolysis reaction. The MBI moves according to a spring, gas pressure, or an elastic membrane. Product paths are disposed to transfer reactants from the system. The product paths can include a channel on a surface of the solid fuel mixture, a channel disposed through the solid fuel mixture, a channel disposed about the solid fuel mixture, a contained region disposed about the solid fuel mixture, or a conduit abutting the solid fuel mixture.

Claims

1. A method of producing hydrogen gas comprising:

(a) delivering a primary liquid delivery medium (LDM) comprising a liquid fuel reactant to contact a solid fuel mixture in a reaction zone under conditions sufficient to cause a reaction between the liquid fuel reactant and the solid fuel mixture;

the delivery of the primary liquid delivery medium being controlled by a movable boundary interface (MBI) that biases the primary liquid delivery medium against the solid fuel mixture;

the reaction zone comprising a reaction product path, said reaction product path being disposed to remove reaction products from said reaction zone during the course of the reaction; and

,

(b) independently contacting the reaction products with a second liquid delivery medium outside of the reaction zone.

2. The method of claim 1, said method being conducted in a reaction control mechanism comprising:

a. the solid fuel mixture;

b. the liquid fuel reactant;

c. the primary liquid delivery medium (LDM) fluidly connected to and configured to deliver the liquid fuel reactant to the solid fuel mixture;

d. the movable boundary interface (MBI) coupled to a primary liquid delivery medium distal the solid fuel mixture that biases the primary liquid delivery medium against the solid fuel mixture;

e. the reaction zone defined between the solid fuel mixture and the primary liquid delivery mechanism; and

,

f. the second liquid delivery medium located in a reaction product path exiting the reaction zone.

3. The method of claim 1, wherein the reaction product path is comprises at least one channel defined in a surface of said solid fuel mixture, at least one channel disposed through said solid fuel mixture, at least one helix channel disposed about said solid fuel mixture, at least one conduit abutting said solid fuel mixture, or a combination thereof.

4. The method of claim 1, wherein the reaction product path comprises guides disposed in said reaction product path, wherein said guides are disposed to provide said liquid fuel reactant to said reaction zone, wherein the secondary LDM is disposed to provide said liquid fuel reactant independently from said primary LDM.

5. The method of claim 1, wherein the solid fuel mixture and the liquid fuel reactant react through a hydrolysis reaction.

6. The method of claim 1, wherein the solid fuel mixture comprises at least solid sodium borohydride (SBH).

7. The method of claim 1, wherein the MBI moves according to a physical moving element providing a force by an elastic membrane.

8. The method of claim 7, wherein the elastic membrane envelopes said solid fuel mixture.

9. The method of claim 7, wherein the elastic membrane comprises an elastic polymer of fabric, a heat shrinkable fabric, a spring sheet, or a combination thereof.

10. The method of claim 1, wherein the primary LDM is a stationary LDM.

11. The method of claim 1, wherein the primary LDM receives a compression force from said MBI.

12. The method of claim 1, wherein the primary LDM provides liquid to the reaction product path, said reaction production path being disposed between a surface of the solid fuel mixture and the MBI, wherein the reaction product path fluidly passes the reaction products away from the reaction zone.

13. The method of claim 12, wherein the reaction product path comprises at least one channel disposed on a surface of said solid fuel mixture, at least one channel disposed through said solid fuel mixture, at least one helix channel disposed about said solid fuel mixture, a contained region disposed about said solid fuel mixture, at least one conduit abutting said solid fuel mixture, or a combination thereof.

14. The method of claim 1, wherein the MBI is an elastic membrane disposed to envelope said solid fuel mixture, such that when the reactants are present in said reaction product path the elastic membrane is disposed to apply a pressure on the reactants to propagate said reactant along the reaction product path.

15. The method of claim 1, wherein the elastic membrane pressure applied to the reactants is a variable pressure.

16. The method of claim 2, further comprising a pump fluidly connected to the primary LDM.

17. The method of claim 1, wherein the reaction product(s) exiting said reaction zone comprises a combination of a partially reacted liquid fuel reactant and solid fuel mixture.

18. The method of claim 1, wherein the delivery of the primary liquid delivery medium comprising a liquid fuel reactant so as to contact a solid fuel mixture controls the rate and amount of the hydrogen gas produced.

19. The method of claim 1, said method being conducted in a reaction control mechanism comprising:

a. the solid fuel mixture;

b. the liquid fuel reactant contained within a reservoir;

c. the primary liquid delivery medium (LDM) fluidly connecting the reservoir to the solid fuel mixture;

d. the movable boundary interface (MBI) that biases a primary liquid delivery medium against the solid fuel mixture;

e. the reaction zone defined between the solid fuel mixture and the primary liquid delivery mechanism; and

f. the secondary LDM fluidly connecting the reservoir to the reaction product path to control an overall reaction stoichiometry, the secondary LDM being located in the reaction product path exiting the reaction zone.

20. The method of claim 1, said method being conducted in a reaction control mechanism comprising:

the solid fuel mixture;

the liquid fuel reactant that reacts with the solid fuel mixture to produce reaction products;

the primary liquid delivery medium fluidly connecting the liquid fuel reactant to the solid fuel mixture;

the movable boundary interface coupled to the primary liquid delivery medium distal the solid fuel mixture that biases the primary liquid delivery medium against the solid reagent;

the reaction product path, defined in the solid fuel mixture, that fluidly connects the reaction zone defined between the solid fuel mixture and the primary liquid delivery medium with area external the reaction control mechanism; and

the secondary liquid delivery medium fluidly connecting the liquid fuel reactant to the reaction product path.