Method of forming urea by integration of an ammonia production process in a urea production process and a system therefor

• US 9,428,449 B2
• Filed: 06/23/2014
• Issued: 08/30/2016
• Est. Priority Date: 01/16/2013
• Status: Active Grant

• Current Assignee: General Electric Technology GmbH (GE Aerospace)
• Original Assignee: Alstom Technology Ltd. (Alstom SA)
• Inventors: Ennenbach, Frank, Koss, Ulrich
• Primary Examiner(s): Nazario Gonzalez, Profirio
• Assistant Examiner(s): Adzamli, Kofi
• Application Number:
  US14/311,477
• Publication Number:
  US 20150368191A1
• Time in Patent Office: 799 Days
• Field of Search: 544/69
• US Class Current: 1/1
• CPC Class Codes: C01C 1/04 Preparation of ammonia by synthesis in the gas phasepreparation or purification of gas mixtures for ammonia synthesis C01B3/025
• CPC Class Codes: C01C 1/0488 Processes integrated with preparations of other compounds, e.g. methanol, urea or with processes for power generation
• CPC Class Codes: C01C 1/12 Separation of ammonia from gases and vapours as part of the ammonia synthesis process C01C1/04
• CPC Class Codes: C07C 273/04 from carbon dioxide and ammonia
• CPC Class Codes: C07C 273/10 combined with the synthesis of ammonia
• CPC Class Codes: Y02P 20/52 using catalysts, e.g. selective catalysts

Abstract

A method of forming urea by integration of an ammonia production process with that of a urea production process, as well as a system for the method is disclosed. Also, an alternative method of forming urea by integration of a part of an ammonia production process with that of a urea production process, as well as a system for the alternative method.

Claims

1. A method of forming urea by integration of an ammonia production process in a urea production process comprising:

obtaining ammonia and carbon dioxide and a flue gas for a first ammonia stream, a carbon dioxide stream, and a flue gas stream containing carbon dioxide;

separating the first ammonia stream into a second ammonia stream and a third ammonia stream, wherein the second ammonia stream is transported to an absorber and the third ammonia stream is transported to a urea synthesis section of the urea production process for the production of urea;

transporting the carbon dioxide stream to the urea synthesis section;

transporting the flue gas stream to the absorber;

combining the second ammonia stream and a lean solvent stream provided from the urea production process to form a mixed stream;

contacting the mixed stream with the flue gas stream in the absorber to absorb carbon dioxide from the flue gas stream to form a rich solvent stream and a treated gas stream;

transporting the rich solvent stream emitted from the absorber to the urea synthesis section;

contacting the carbon dioxide stream, the third ammonia stream and the rich solvent stream in the urea synthesis section to form urea and the lean solvent stream; and

transporting the lean solvent stream from the urea production process to the absorber.

2. The method according to claim 1, wherein the flue gas stream is obtained during combustion in an ammonia production plant.

3. The method according to claim 2, wherein the combustion in the ammonia production plant is performed in a steam reformer.

4. The method according to claim 1, wherein the flue gas stream is cooled to a temperature of 0-25 deg C. before entering the absorber.

5. The method according to claim 1, wherein the absorber is a Chilled Ammonia Process (CAP) absorber.

6. The method according to claim 1, wherein at least a portion of the treated gas stream leaving the absorber is transported to the ammonia production process.

7. The method according to claim 1, wherein the concentration of ammonia in the mixed stream and in the rich solvent stream is 2-12 moles per liter solution, the concentration of carbon dioxide in the lean solvent stream is 0.2-4.0 moles per liter solution, and the concentration of carbon dioxide in the rich solvent stream is 1.0-10.0 moles per liter solution.

8. The method according to claim 1, wherein the ratio between the concentration of ammonia and the concentration of carbon dioxide in the rich solvent stream is 1:

1 to 3;

1, preferably 3;

2 to 5;

2.

9. A method of forming urea by integration of a part of an ammonia production process in a urea production process, comprising:

obtaining a hydrogen/carbon dioxide stream from the ammonia production process, and a flue gas stream containing carbon dioxide and nitrogen;

transporting the flue gas stream to a low pressure absorber;

contacting the flue gas stream with a lean solvent stream provided from the urea production process in the low pressure absorber to produce a semi-rich solvent stream and a cleaned gas stream containing nitrogen;

transporting the hydrogen/carbon dioxide stream to a high pressure absorber;

transporting the semi-rich solvent stream from the low pressure absorber to the high pressure absorber;

contacting the hydrogen/carbon dioxide stream with the semi-rich solvent stream in the high pressure absorber to form a rich solvent stream and a hydrogen stream;

transporting the rich solvent stream from the high pressure absorber to the urea production process to form urea and the lean solvent stream comprising a solution of carbamate, ammonia, carbon dioxide and water;

transporting the lean solvent stream to the low pressure absorber, and

transporting a stream from an ammonia production unit to the urea production process.

10. The method according to claim 9, wherein the flue gas stream is obtained during combustion in a steam reformer in the ammonia production process.

11. The method according to claim 9, wherein a syngas stream containing hydrogen and carbon monoxide, and formed during a steam reforming reaction of the ammonia production process, is transported to a carbon monoxide shift unit in which the carbon monoxide is converted into carbon dioxide to form the hydrogen/carbon dioxide stream.

12. The method according to claim 9, further comprising transporting the cleaned gas stream containing nitrogen and the hydrogen stream to the ammonia production process and reacting both for the production of ammonia.

13. The method according to claim 9, wherein an ammonia stream is added to the lean solvent stream before entering the low pressure absorber.

14. The method according to claim 9, wherein at least a portion of the rich solvent stream emitted from the high pressure absorber is transported to the low pressure absorber.

15. The method according to claim 9, wherein at least a portion of the lean solvent stream is added to the high pressure absorber.

16. The method according to claim 9, wherein a partial stream of the semi rich solvent stream exiting the low pressure absorber is transported to the urea production plant.

17. The method according to claim 9, wherein the pressure in the low pressure absorber is 0.08-0.15 MPa, and the pressure in the high pressure absorber is 0.3-4.0 MPa.

18. The method according to claim 17, wherein the pressure in the low pressure absorber is 0.095-0.11 MPa, and the pressure in the high pressure absorber is 1-2.5 MPa.

19. The method according to claim 9, wherein the concentration of carbon dioxide in the lean solvent stream is 0.2-4.0 moles per liter solution, the concentration of carbon dioxide in the semi rich solvent stream is 1.0-5.5 moles per liter of solution, and the concentration of carbon dioxide in the rich solvent stream is 1.0-10.0 moles per liter solution.

20. The method according to claim 9, wherein the ratio between the concentration of ammonia and the concentration of carbon dioxide in the rich solvent stream is 1:

1 to 3;

1, preferably 3;

2 to 5;

2.